Citation: KUANG Xiao-Nan, WANG Yu, ZHU Ning, LIU Min, YANG Yu-Ping, LI Zhong-Feng, HAN Hong-Liang, JIN Qiong-Hua. Syntheses, Characterization and Luminescent Properties of Two Silver(Ⅰ) Complexes Based on N-donor and P-donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1733-1738. doi: 10.11862/CJIC.2018.193 shu

Syntheses, Characterization and Luminescent Properties of Two Silver(Ⅰ) Complexes Based on N-donor and P-donor Ligands

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China
2.
College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
3.
School of Science, Minzu University of China, Beijing 100081, China

Corresponding author: JIN Qiong-Hua, jinqh@cnu.edu.cn
Received Date: 22 April 2018
Revised Date: 11 May 2018

Figures(6)

Two novel silver(Ⅰ) complexes, [Ag₂(dppp)₂(phen)₂](CF₃SO₃)₂ (1) and[Ag₂(dppm)₂(dpq)₂](CF₃SO₃)₂·3CH₃OH (2) (dppp=bis(diphenylphosphino)propane, dppm=bis(diphenylphosphino)methane, phen=1, 10-phenan-throline, dpq=pyrazino[2, 3-f][1, 10]phenanthroline), have been synthesized in mixed solvent CH₃OH and CH₂Cl₂ and characterized by IR, single-crystal X-ray diffraction, ¹H NMR spectroscopy, fluorescence spectra and THz time domain spectroscopy (THz-TDS). Complex 1 is of a binuclear complex, which was generated by the reaction of AgCF₃SO₃ and dppp with phen in 1:1:1 molar ratio. In complex 1, the central Ag(Ⅰ) ion forms a ring by the bridging bisphosphine ligand (dppp) and chelating N-donor ligand (phen). Like 1, 2 is of a binuclear complex, which was obtained by the reaction of AgCF₃SO₃ and dppm with dpq in 1:1:1 molar ratio. The luminescent spectra show that all these emissions are assigned to ligand centered π-π^* transition.
- silver(Ⅰ) complex,
- fluorescence,
- terahertz spectra
1. [1]
  Mercs L, Albrecht M. Chem. Soc. Rev., 2010, 39:1903-1912 doi: 10.1039/b902238b
2. [2]
  Accorsi G, Listorti A, Yoosaf K, et al. Chem. Soc. Rev., 2009, 38:1690-1700 doi: 10.1039/b806408n
3. [3]
  Feazell R P, Carson C E, Klausmeyer K K, et al. Inorg. Chem., 2006, 45:935-944 doi: 10.1021/ic051659e
4. [4]
  Price J R, Lan Y, Jameson G B, et al. Dalton Trans., 2006:1491
5. [5]
  Constable E C, Zhang G, Housecroft C E, et al. Eur. J. Inorg. Chem., 2010:2000-2011
6. [6]
  Medici S, Peana M, Crisponi G, et al. Coord. Chem. Rev., 2016, 327-328:349-359 doi: 10.1016/j.ccr.2016.05.015
7. [7]
  Liu W K, Gust R. Coord. Chem. Rev., 2016, 329:191-213 doi: 10.1016/j.ccr.2016.09.004
8. [8]
  Mara M W, Fransted K A, Chen L X, et al. Coord. Chem. Rev., 2015, 282-283:2-18 doi: 10.1016/j.ccr.2014.06.013
9. [9]
  Czerwieniec R, Leitl M J, Homeier H H H, et al. Coord. Chem. Rev., 2016, 325:2-28 doi: 10.1016/j.ccr.2016.06.016
10. [10]
  Mjos K D, Orvig C. Chem. Rev., 2014, 114:4540-4563 doi: 10.1021/cr400460s
11. [11]
  Cuttell D G, Kuang S M, Fanwick P E, et al. J. Am. Chem. Soc., 2002, 124:6-7 doi: 10.1021/ja012247h
12. [12]
  Qiu Q M, Huang X, Zhao Y H, et al. Polyhedron, 2014, 83:16-23 doi: 10.1016/j.poly.2014.03.044
13. [13]
  Huang X, Li Z F, Jin Q H, et al. Polyhedron, 2013, 65:129-135 doi: 10.1016/j.poly.2013.08.018
14. [14]
  Zhang Y R, Cui Y Z, Jin Q H, et al. Polyhedron, 2017, 122:86-98 doi: 10.1016/j.poly.2016.10.033
15. [15]
  Cui Y Z, Yuan Y, Han H L, et al. Z. Anorg. Allg. Chem., 2016, 642(18):953-959 doi: 10.1002/zaac.201600193
16. [16]
  ZHANG Yan-Ru, WANG Meng-Qin, CUI Yang-Zhe, et al. Chinese J. Inorg. Chem., 2015, 31(10):2089-2094
17. [17]
  Xu S, Liu M, Yang, Y P, et al. Polyhedron, 2015, 87:293-301 doi: 10.1016/j.poly.2014.11.022
18. [18]
  Zhang L L, Zhong H, Deng C, et al. Appl. Phys. Lett., 2009, 94(21):211106 doi: 10.1063/1.3143613
19. [19]
  Sheldrick G M. SHELXTL Ver. 5.1, University of Göttingen, Germany, 1997.
20. [20]
  Sheldrick G M. SHELXS-97 and SHELXL-97, University of Göttingen, Germany, 1997.
21. [21]
  Lin S, Cui Y Z, Qiu Q M, et al. Polyhedron, 2017, 134:319-329 doi: 10.1016/j.poly.2017.06.036
22. [22]
  Bruce M I, Nicholson B K, Skelton B W, et al. Inorg. Chim. Acta, 2016, 453:647-653 doi: 10.1016/j.ica.2016.09.018
23. [23]
  Yuan Y, Han H J, Lin S, et al. Polyhedron, 2016, 119:184-193 doi: 10.1016/j.poly.2016.08.038
24. [24]
  Crespo O, Gimeno M C, Laguna A, et al. Dalton Trans., 2014, 43:12214-12220 doi: 10.1039/C4DT00797B
25. [25]
  Kaeser A, Delavaux-Nicot B, Duhayon C, et al. Inorg. Chem., 2013, 52:14343-14354 doi: 10.1021/ic402342y
26. [26]
  Carlucci L, Ciani G, Proserpio D M, et al. CrystEngComm, 2002, 4:121-129 doi: 10.1039/b201288j
27. [27]
  Yang R N, Hou Y M, Xue B Y, et al. Transition Met. Chem., 1996, 21:28-30
28. [28]
  Cui Y Z, Yuan Y, Li Z F, et al. Polyhedron, 2016, 112:118-129 doi: 10.1016/j.poly.2016.03.060
1. [1]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
2. [2]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
3. [3]
  Jiming XI , Yukang TENG , Rui ZHANG , Zhenzhong LU . Fluorescent coordination polymers based on anthracene-and pyrene-derivative ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 847-854. doi: 10.11862/CJIC.20240367
4. [4]
  Yuanyu YANG , Jianhua XUE , Yujia BAI , Lulu CUI , Dongdong YANG , Qi MA . Design, synthesis, and detection of Al³⁺ of two zinc complexes based on Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1207-1216. doi: 10.11862/CJIC.20250005
5. [5]
  Youbo HU , Donggang LI , Changhua SUN , Zhenzhong LU , Songjun GU . Coordination polymers based on anthracene- and pyrene-derived ligands: Crystal structure, fluorescent property, and framework isomerization. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1681-1688. doi: 10.11862/CJIC.20250004
6. [6]
  Ya-Wen Zhang , Ming-Ming Gan , Li-Ying Sun , Ying-Feng Han . Supramolecular dinuclear silver(I) and gold(I) tetracarbene metallacycles and fluorescence sensing of penicillamine. Chinese Journal of Structural Chemistry, 2024, 43(9): 100356-100356. doi: 10.1016/j.cjsc.2024.100356
7. [7]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
8. [8]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
9. [9]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
10. [10]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
11. [11]
  Feihu Wu , Gengwen Chen , Kaitao Lai , Shiqing Zhang , Yingchao Liu , Ruijian Luo , Xiaocong Wang , Pinzhi Cao , Yi Ye , Jiarong Lian , Junle Qu , Zhigang Yang , Xiaojun Peng . Non-specific/specific SERS spectra concatenation for precise bacteria classifications with few samples using a residual neural network. Chinese Chemical Letters, 2025, 36(1): 109884-. doi: 10.1016/j.cclet.2024.109884
12. [12]
  Yu Mao , Yilin Liu , Xiaochen Wang , Shengyang Ni , Yi Pan , Yi Wang . Acylfluorination of enynes via phosphine and silver catalysis. Chinese Chemical Letters, 2024, 35(8): 109443-. doi: 10.1016/j.cclet.2023.109443
13. [13]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249
14. [14]
  Gongcheng Ma , Qihang Ding , Yuding Zhang , Yue Wang , Jingjing Xiang , Mingle Li , Qi Zhao , Saipeng Huang , Ping Gong , Jong Seung Kim . Palladium-free chemoselective probe for in vivo fluorescence imaging of carbon monoxide. Chinese Chemical Letters, 2024, 35(9): 109293-. doi: 10.1016/j.cclet.2023.109293
15. [15]
  Ying Xu , Chengying Shen , Hailong Yuan , Wei Wu . Mapping multiple phases in curcumin binary solid dispersions by fluorescence contrasting. Chinese Chemical Letters, 2024, 35(9): 109324-. doi: 10.1016/j.cclet.2023.109324
16. [16]
  Yuxin Li , Chengbin Liu , Qiuju Li , Shun Mao . Fluorescence analysis of antibiotics and antibiotic-resistance genes in the environment: A mini review. Chinese Chemical Letters, 2024, 35(10): 109541-. doi: 10.1016/j.cclet.2024.109541
17. [17]
  Ziyou Zhang , Te Ji , Hongliang Dong , Zhiqiang Chen , Zhi Su . Effect of coordination restriction on pressure-induced fluorescence evolution. Chinese Chemical Letters, 2024, 35(12): 109542-. doi: 10.1016/j.cclet.2024.109542
18. [18]
  Wenya Jiang , Jianyu Wei , Kuan-Guan Liu . Atomically precise superatomic silver nanoclusters stabilized by O-donor ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100371-100371. doi: 10.1016/j.cjsc.2024.100371
19. [19]
  Zhifeng CAI , Ying WU , Yanan LI , Guiyu MENG , Tianyu MIAO , Yihao ZHANG . Effective detection of malachite green by folic acid stabilized silver nanoclusters. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 983-993. doi: 10.11862/CJIC.20240394
20. [20]
  Qing Li , Fangyu Fu , Mengyun Zhao , Yeqin Feng , Manzhou Chi , Zichen Zhao , Hongjin Lv , Guo-Yu Yang . Asymmetrically anchoring silver alkynyl cluster to the cobalt-containing polyoxometalate. Chinese Chemical Letters, 2025, 36(7): 110090-. doi: 10.1016/j.cclet.2024.110090

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(936)
HTML views(99)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142