Citation: LI Tian-Tian, ZHENG Sheng-Run. Structures and Properties of One Mixed-Ligand and Two Homoligand Coordination Polymers Based on 4-(Imidazol-1-yl)-benzoic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1566-1572. doi: 10.11862/CJIC.2018.191 shu

Structures and Properties of One Mixed-Ligand and Two Homoligand Coordination Polymers Based on 4-(Imidazol-1-yl)-benzoic Acid

LI Tian-Tian ¹ ,
ZHENG Sheng-Run ^2,,

1.
Guiyang College of Traditional Chinese Medicine, Guiyang 550002, China
2.
School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China

Corresponding author: ZHENG Sheng-Run, zhengsr@scnu.edu.cn
Received Date: 17 April 2018
Revised Date: 14 May 2018

Figures(4)

Reactions of Cu(Ⅱ) or Cd(Ⅱ) salts, 4-(imidazol-1-yl)-benzoic acid (HIBA) with or without 5-nitroiso-phthalic acid (H₂NPA) as co-ligand result in three coordination polymers (CPs), namely, {[Cu(IBA)₂]·DMF}_n (1), {[Cd(IBA)₂(H₂O)]·3H₂O}_n (2), and[Cd₃(IBA)₂(NPA)₂]_n (3). Compounds 1 and 2 exhibit 3D 4-and 3-fold interpene-trating diamondoid frameworks, respectively. Compound 3 displays a 3D mixed-ligand framework with 1D Cd-carboxylate secondary building blocks bridged by IBA^- and NPA^2- ligands. The phase purity and luminescent properties of selected compounds have also been explored.
- 4-(imidazol-1-yl)-benzoic acid,
- coordination polymer,
- crystal structure,
- solid-state luminescent
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