Citation: HUANG Rong, ZENG Xue-Hua, WANG Wan-Man, ZHANG Meng-Li, CHEN Jing-Lin, LIAO Jin-Sheng, LIU Sui-Jun, WEN He-Rui. Cu(Ⅰ)Fe(Ⅱ) Heterobimetallic Complexes Based on Functionalized 6-Methoxycarbonyl-2, 2'-bipyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1719-1724. doi: 10.11862/CJIC.2018.188 shu

Cu(Ⅰ)Fe(Ⅱ) Heterobimetallic Complexes Based on Functionalized 6-Methoxycarbonyl-2, 2'-bipyridine Ligands

1.
School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China
2.
Department of Natural Science and Computer, Ganzhou Teachers College, Ganzhou, Jiangxi 341000, China

Corresponding author: CHEN Jing-Lin, gzchenjinglin@126.com
Received Date: 12 April 2018
Revised Date: 4 May 2018

Figures(3)

Two new Cu(Ⅰ)Fe(Ⅱ) heterobimetallic complexes, [Cu(mbpy)(dppf)]ClO₄·CH₂Cl₂ (1) and[Cu(mmbpy)(dppf)]ClO₄ (2), were synthesized by using[Cu(CH₃CN)₄]ClO₄, 6-methoxycarbonyl-2, 2'-bipyridine (mbpy), 6-metho-xycarbonyl-4, 4'-dimethyl-2, 2'-bipyridine (mmbpy), and 1, 1'-bis(diphenylphosphino)ferrocene (dppf) as the starting materials. As revealed by single-crystal X-ray diffraction analysis, complexes 1 and 2 are all Cu(Ⅰ)Fe(Ⅱ) heterobimetallic species and exhibit tetra-coordinated and distorted tetrahedral configuration. Complexes 1 and 2 all show a weak low-energy broad absorption in the wavelength range of 330～520 nm, which is mainly assigned to metal-to-ligand charge-transfer (MLCT) transition. No emission is detected in solution and solid states at room temperature for 1 and 2, due to the introduction of 1, 1'-bis(diphenylphosphino)ferrocene.
- copper(Ⅰ) complex,
- 1, 1'-bis(diphenylphosphino)ferrocene,
- methoxycarbonyl,
- methylation,
- crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142