Citation: LIU Guang, YAO Rui, ZHAO Yong, WANG Mu-Heng, LI Na, Li Jin-Ping. Ni/NiFe₂O₄ Nanorods Encapsulated in Onion-like N-Doped Carbon Nanolayers as Efficient Oxygen Evolution Electrocatalyst[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1494-1500. doi: 10.11862/CJIC.2018.186 shu

Ni/NiFe₂O₄ Nanorods Encapsulated in Onion-like N-Doped Carbon Nanolayers as Efficient Oxygen Evolution Electrocatalyst

Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: Li Jin-Ping, jpli211@hotmail.com
Received Date: 13 April 2018
Revised Date: 8 May 2018

Figures(6)

Ni/NiFe₂O₄ nanorods encapsulated in onion-like N-doped carbon (ONC) nanolayers was prepared by the pyrolysis of NiFe-based coordination polymer precursor under N₂ atmosphere. Compared with Ni@ONC, NiFe₂O₄, and commercial RuO₂ electrocatalysts, benefiting by the promoted electronic conductivity and enlarged electrochemical surface area (0.149 mF) from synergistic effects between the ONC nanolayers and encapsulated Ni/NiFe₂O₄ heterostructure, the as-prepared Ni/NiFe₂O₄@ONC hybrid nanorod exhibits extraordinary electrocatalytic activity towards oxygen evolution reaction (OER) with an overpotential of~299 mV at 10 mA·cm^-2 and a Tafel slope of 73 mV·dec^-1.
- water splitting,
- oxygen evolution catalysts,
- N-doped onion-like carbon,
- nickel-iron oxides,
- mesoporous heterostructure
1. [1]
  XIE Ying-Peng, WANG Guo-Sheng, ZHANG En-Lei, et al. Chinese J. Inorg. Chem., 2017, 33(2):177-209 doi: 10.11862/CJIC.2017.030
2. [2]
  ZHANG Chao-Ying, WANG Ping, LIU Yan-Yan, et al. Chinese J. Inorg. Chem., 2017, 33(7):1132-1138 doi: 10.11862/CJIC.2017.170
3. [3]
  Seh Z W, Kibsgaard J, Dickens C F, et al. Science, 2017, 355(6321):eaad4998 doi: 10.1126/science.aad4998
4. [4]
  Hunter B M, Gray H B, Müller A M. Chem. Rev., 2016, 116(22):14120-14136 doi: 10.1021/acs.chemrev.6b00398
5. [5]
  HE Yang-Hua, XU Jin-Ming, WANG Fa-Nan, et al. Chem. Ind. Eng. Prog., 2016, 35(7):2057-2062
6. [6]
  Liu G, Gao X S, Wang K F, et al. Int. J. Hydrogen Energy, 2016, 41(40):17976-17986 doi: 10.1016/j.ijhydene.2016.07.268
7. [7]
  Xiao C L, Lu X Y, Zhao C. Chem. Commun., 2014, 50(70):10122-10125 doi: 10.1039/C4CC04922E
8. [8]
  Wang Z C, Liu H L, Ge R X, et al. ACS Catal., 2018, 8(3):2236-2241 doi: 10.1021/acscatal.7b03594
9. [9]
  Liu G, Wang K F, Gao X S, et al. Electrochim. Acta, 2016, 211:871-878 doi: 10.1016/j.electacta.2016.06.113
10. [10]
  Yan K L, Shang X, Liu Z Z, et al. Int. J. Hydrogen Energy, 2017, 42(38):24150-24158 doi: 10.1016/j.ijhydene.2017.07.165
11. [11]
  Han L, Dong S J, Wang E K. Adv. Mater., 2016, 28(42):9266-9291 doi: 10.1002/adma.201602270
12. [12]
  Zhou W J, Wu X J, Cao X H, et al. Energy Environ. Sci., 2013, 6(10):2921-2924 doi: 10.1039/c3ee41572d
13. [13]
  GAO Xu-Sheng, LIU Guang, SHI Qin-Fang, et al. Chinese J. Inorg. Chem., 2017, 33(4):623-629 doi: 10.11862/CJIC.2017.080
14. [14]
  Li B Q, Xia Z J, Zhang B S, et al. Nat. Commun., 2017, 8:934 doi: 10.1038/s41467-017-01053-x
15. [15]
  Liu G, Gao X S, Wang K F, et al. Nano Res., 2017, 10(6):2096-2105 doi: 10.1007/s12274-016-1398-x
16. [16]
  CAI Xiao-Qing, JI Zhen-Yuan, SHEN Xiao-Ping, et al. Chinese J. Inorg. Chem., 2017, 33(1):26-32 doi: 10.11862/CJIC.2017.017
17. [17]
  Zhao Y, Nakamura R, Kamiya K, et al. Nat. Commun., 2013, 4:2390 doi: 10.1038/ncomms3390
18. [18]
  Li Y B, Zhao C. ACS Catal., 2017, 7(4):2535-2541 doi: 10.1021/acscatal.6b03497
19. [19]
  Liu G, He D Y, Yao R, et al. Nano Res., 2018, 11(3):1664-1675 doi: 10.1007/s12274-017-1783-0
1. [1]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
2. [2]
  Jianchun Wang , Ruyu Xie . The Fantastical Dance of Miss Electron: Contra-Thermodynamic Electrocatalytic Reactions. University Chemistry, 2025, 40(4): 331-339. doi: 10.12461/PKU.DXHX202406082
3. [3]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
4. [4]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
5. [5]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
6. [6]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
7. [7]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
8. [8]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
9. [9]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
10. [10]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
11. [11]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
12. [12]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
13. [13]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
14. [14]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
15. [15]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
16. [16]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
17. [17]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
18. [18]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
19. [19]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
20. [20]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

Get Citation

PDF

XML

Metrics

PDF Downloads(28)
Abstract views(3522)
HTML views(1253)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ni/NiFe2O4 Nanorods Encapsulated in Onion-like N-Doped Carbon Nanolayers as Efficient Oxygen Evolution Electrocatalyst

Metrics

通讯作者: 陈斌, bchen63@163.com

Ni/NiFe₂O₄ Nanorods Encapsulated in Onion-like N-Doped Carbon Nanolayers as Efficient Oxygen Evolution Electrocatalyst