Citation: XIAO Long-Ya, CHEN Nuo, DAI Zhi-Yin, WEN Shuai, WANG Jie, DENG Jun-Yang, NIE Long-Hui. Preparation and Catalytic Performance of Pt/γ-AlOOH Nanorods Catalytic Materials[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1470-1476. doi: 10.11862/CJIC.2018.180 shu

Preparation and Catalytic Performance of Pt/γ-AlOOH Nanorods Catalytic Materials

XIAO Long-Ya ^1,2 ,
CHEN Nuo ¹ ,
DAI Zhi-Yin ¹ ,
WEN Shuai ¹ ,
WANG Jie ¹ ,
DENG Jun-Yang ¹ ,
NIE Long-Hui ^1,2,,

1.
Hubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan 430068, China
2.
Collaborative Innovation Center of Green Light-Weight Materials and Processing, Hubei University of Technology, Wuhan 430068, China

Corresponding author: NIE Long-Hui, nielonghui@mail.hbut.edu.cn
Received Date: 26 March 2018
Revised Date: 15 May 2018

Figures(9)

γ-AlOOH nanrods were firstly prepared via a hydrothermal method, and then Pt/γ-AlOOH nanrods catalysts (PA) were obtained by a combined impregnation and NaBH₄-reduction method using γ-AlOOH nanrods as supports. The obtained PA was used to catalytically oxidize formaldehyde (HCHO) at room temperature and the effect of Pt content on catalytic activity was also studied. The prepared samples were characterized by XRD, TEM, XPS and N₂ adsorption-desorption isothermal test. The results show that PA reveals higher catalytic acitivity than Pt/γ-Al₂O₃, which is mainly due to the abundance of surface hydroxyls and high dispersion of Pt nanoparticles. The catalytic activities of PA firstly increase and then almost maintain unchanged with increasing of Pt content in the range of 0.05%~0.5% (w/w). 0.2% (w/w) Pt is the optimum loading considering both catalytic activity and cost.
- heterogeneous catalysis,
- formaldehyde oxidation,
- Pt/γ-AlOOH nanrods
1. [1]
  Nie L H, Yu J G, Jaroniec M, et al. Catal. Sci. Technol., 2016, 6:3649-3669 doi: 10.1039/C6CY00062B
2. [2]
  Collins J J, Ness R, Tyl R W, et al. Regul. Toxicol. Pharmacol., 2001, 34:17-34 doi: 10.1006/rtph.2001.1486
3. [3]
  Ye J W, Zhu X F, Cheng B, et al. Environ. Sci. Technol. Lett., 2017, 4(1):20-25 doi: 10.1021/acs.estlett.6b00426
4. [4]
  Chen F, Liu S W, Yu J G. Phys. Chem. Chem. Phys., 2016, 18(27):18161-18168 doi: 10.1039/C6CP03037H
5. [5]
  Liang W J, Li J, Li J X, et al. J. Hazard. Mater., 2010, 175(12/3):1090-1095
6. [6]
  DUAN Yue-Qin, YANG Song-Po, YU Jiang -Ling, et al. Chinese J. Inorg. Chem., 2014, 30(7):1673-1677
7. [7]
  Wang H, Liang Y H, Liu L, et al. J. Hazard. Mater., 2018, 344:369-380 doi: 10.1016/j.jhazmat.2017.10.044
8. [8]
  Zhang Y, Cui W Q, An W J, et al. Appl. Catal., B, 2018, 221:36-46 doi: 10.1016/j.apcatb.2017.08.076
9. [9]
  Chen F Y, An W J, Liang Y H, et al. Appl. Catal., B, 2017, 217:65-80 doi: 10.1016/j.apcatb.2017.05.078
10. [10]
  Zhang C B, Liu F D, Zhai Y P, et al. Angew. Chem. Int. Ed., 2012, 51:9628-9632 doi: 10.1002/anie.v51.38
11. [11]
  Huang H B, Leung D Y C. ACS Catal., 2011, 1(4):348-354 doi: 10.1021/cs200023p
12. [12]
  Zhang C B, Li Y B, Wang Y F, et al. Environ. Sci. Technol., 2014, 48(10):5816-5822 doi: 10.1021/es4056627
13. [13]
  An N H, Zhang W L, Yuan X L, et al. Chem. Eng. J., 2013, 215-216:1-6 doi: 10.1016/j.cej.2012.10.096
14. [14]
  Nie L H, Meng A Y, Yu J G, et al. Sci. Rep., 2013, 3:3215(6 Pages) doi: 10.1038/srep03215
15. [15]
  Tan H Y, Wang J, Yu S Z, et al. Environ. Sci. Technol., 2015, 49:8675-8682 doi: 10.1021/acs.est.5b01264
16. [16]
  Wang Z Q, Pei J J, Zhang J S, et al. Build. Sci., 2013, 65:49-57
17. [17]
  Chen B B, Shi C, Crocker M, et al. Appl. Catal., B, 2013, 132-133:245-255
18. [18]
  Chen B B, Zhu X B, Crocker M, et al. Catal. Commun., 2013, 42:93-97 doi: 10.1016/j.catcom.2013.08.008
19. [19]
  Xu Z H, Yu J G, Jaroniec M. Appl. Catal., B, 2015, 163:306-312 doi: 10.1016/j.apcatb.2014.08.017
20. [20]
  TAN Qiao, ZHU Wei, WEI Qi, et al. Acta Phys.-Chim. Sin., 2015, 30(1):93-97
21. [21]
  Cai W Q, Yu J G, Gu S H, et al. Cryst. Growth Des., 2010, 10(9):3977-3982 doi: 10.1021/cg100544w
22. [22]
  FU Xiao-Ming. Journal of Synthetic Crystals, 2013, 42(8):1473-1476
23. [23]
  LÜ Jian-Gang, ZHANG Juan, DING Wei-Ping, et al. Chinese J. Inorg. Chem., 2007, 23(5):897-900
24. [24]
  Nie L H, Yu J G, Li X Y, et al. Environ. Sci. Technol., 2013, 47:2777-2783 doi: 10.1021/es3045949
25. [25]
  Zhang J, Wei S Y, Lin J, et al. J. Phys. Chem. B, 2006, 110:21680-21683 doi: 10.1021/jp064725m
26. [26]
  Vatanpour V, Madaeni S S, Rajabi L, et al. J. Membr. Sci., 2012, 401-402:132-143 doi: 10.1016/j.memsci.2012.01.040
27. [27]
  Nie L H, Wang J, Yu J G. RSC Adv., 2017, 7:21389-21397 doi: 10.1039/C7RA01616F
28. [28]
  Xu Q L, Lei W Y, Li X Y, et al. Environ. Sci. Technol., 2014, 48:9702-9708 doi: 10.1021/es5019477
29. [29]
  Wang J L, Li J G, Jiang C J, et al. Appl. Catal., B, 2017, 204:147-155 doi: 10.1016/j.apcatb.2016.11.036
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