Citation: HU Bo, GAO Lin, QIAO Yu, CHE Guang-Bo. Synthesis of Fluorescent Molecularly Imprinted Polymers Based on Europium(Ⅲ) Complex for Selective Determination of Trace 2, 4, 6-Trichlorophenol[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1531-1537. doi: 10.11862/CJIC.2018.169 shu

Synthesis of Fluorescent Molecularly Imprinted Polymers Based on Europium(Ⅲ) Complex for Selective Determination of Trace 2, 4, 6-Trichlorophenol

HU Bo ^1,3 ,
GAO Lin ^1,3 ,
QIAO Yu ^1,2 ,
CHE Guang-Bo ^1,,

1.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials(Ministry of Education), Jilin Normal University, Changchun 130103, China
2.
College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China
3.
College of Environmental Science and Engineering, Jilin Normal University, Siping, Jilin 136000, China

Corresponding author: CHE Guang-Bo, cgbpapper@163.com
Received Date: 5 March 2018
Revised Date: 18 April 2018

Figures(7)

Fluorescent molecularly imprinted polymers(FMIPs) for selective determination 2, 4, 6-trichlorophenol were devised and fabricated. Here, europium(Ⅲ) complexes were used as fluorescence detection tool via the fluorescence quenching with templates. The FMIPs have a linear fluorescent response in 0~70 nmol·L^-1 concentration range, and the correlation coefficient was 0.996 28. The FMIPs exhibit excellent sensitivity with the limit of detection of 3.12 nmol·L^-1. In addition, FMIPs show good thermal stability and appreciable selectivity over several analogues. The experimental results showed that FMIPs could be used for selective fluorescence detection of low concentrations of chlorophenols.
- europium complex,
- fluorescence detection,
- molecularly imprinted polymer,
- 2, 4, 6-trichlorophenol
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