Citation: HU Bo, GAO Lin, QIAO Yu, CHE Guang-Bo. Synthesis of Fluorescent Molecularly Imprinted Polymers Based on Europium(Ⅲ) Complex for Selective Determination of Trace 2, 4, 6-Trichlorophenol[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1531-1537. doi: 10.11862/CJIC.2018.169 shu

Synthesis of Fluorescent Molecularly Imprinted Polymers Based on Europium(Ⅲ) Complex for Selective Determination of Trace 2, 4, 6-Trichlorophenol

HU Bo ^1,3 ,
GAO Lin ^1,3 ,
QIAO Yu ^1,2 ,
CHE Guang-Bo ^1,,

1.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials(Ministry of Education), Jilin Normal University, Changchun 130103, China
2.
College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China
3.
College of Environmental Science and Engineering, Jilin Normal University, Siping, Jilin 136000, China

Corresponding author: CHE Guang-Bo, cgbpapper@163.com
Received Date: 5 March 2018
Revised Date: 18 April 2018

Figures(7)

Fluorescent molecularly imprinted polymers(FMIPs) for selective determination 2, 4, 6-trichlorophenol were devised and fabricated. Here, europium(Ⅲ) complexes were used as fluorescence detection tool via the fluorescence quenching with templates. The FMIPs have a linear fluorescent response in 0~70 nmol·L^-1 concentration range, and the correlation coefficient was 0.996 28. The FMIPs exhibit excellent sensitivity with the limit of detection of 3.12 nmol·L^-1. In addition, FMIPs show good thermal stability and appreciable selectivity over several analogues. The experimental results showed that FMIPs could be used for selective fluorescence detection of low concentrations of chlorophenols.
- europium complex,
- fluorescence detection,
- molecularly imprinted polymer,
- 2, 4, 6-trichlorophenol
1. [1]
  Czaplicka M. Sci. Total Environ., 2004, 322(1/2/3):21-39
2. [2]
  Igbinosa E O, Odjadjare E E, Chigor V N, et al. The Sci. World J., 2013, 3:75-84
3. [3]
  Guo J Q, Wu C H, Lv S L, et al. Environ. Pollut., 2016, 214:478-484 doi: 10.1016/j.envpol.2016.04.074
4. [4]
  Patterson A T, Kaffenberger B H, Keller R A, et al. J. Am. Acad. Dermatol., 2016, 74(1):143-170 doi: 10.1016/j.jaad.2015.05.006
5. [5]
  Olaniran A O, Igbinosa E O. Chemosphere, 2011, 83(10):1297-1306 doi: 10.1016/j.chemosphere.2011.04.009
6. [6]
  Arora P K, Bae H. Microb. Cell Fact., 2014, 13(1):1-17 doi: 10.1186/1475-2859-13-1
7. [7]
  Bolobajev J, Trapido M, Goi A. Appl. Catal. B, 2016, 187:75-82 doi: 10.1016/j.apcatb.2016.01.015
8. [8]
  Vandergrift G W, Krogh E T, Gill C G. Anal. Chem., 2017, 89(10):5629-5636 doi: 10.1021/acs.analchem.7b00908
9. [9]
  Olu-Owolabi B I, Alabi A H, Diagboya P N, et al. J. Environ. Manage., 2017, 192:94-99 doi: 10.1016/j.jenvman.2017.01.055
10. [10]
  Zhou Y, Zhang J F, Yoon J. Chem. Rev., 2014, 114(10):5511-5571 doi: 10.1021/cr400352m
11. [11]
  Chinen A B, Guan C M, Ferrer J R, et al. Chem. Rev., 2015, 115(19):10530-10574 doi: 10.1021/acs.chemrev.5b00321
12. [12]
  Hudson N, Baker A, Reynolds D. River Res. Appl., 2010, 23(6):631-649
13. [13]
  Liang L L, Lan F F, Ge S G, et al. Anal. Chem., 2017, 89(6):3597-3605 doi: 10.1021/acs.analchem.6b04978
14. [14]
  Nsibande S A, Forbes P B. Anal. Chim. Acta, 2016, 945:9-22 doi: 10.1016/j.aca.2016.10.002
15. [15]
  Choi M G, Lee S H, Jung Y U, et al. Sens. Actuators B, 2017, 251:713-719 doi: 10.1016/j.snb.2017.05.098
16. [16]
  Xu L, Zhou W H, Liu J W. Anal. Chim. Acta, 2017, 977:44-51 doi: 10.1016/j.aca.2017.04.046
17. [17]
  Edelmann F T. Coord. Chem. Rev., 2017, 338:27-140 doi: 10.1016/j.ccr.2017.02.001
18. [18]
  MAO Lan-Lan, ZHANG Li-Ming, DENG Yan, et al. Chinese J. Inorg. Chem., 2016, 32(12):2095-2101
19. [19]
  Campos-Gonalves I, Costa B F O, Santos R F, et al. Mater. Des., 2017, 130:263-274 doi: 10.1016/j.matdes.2017.05.064
20. [20]
  Babailov S P. Sens. Actuators B, 2017, 251:108-111 doi: 10.1016/j.snb.2017.05.033
21. [21]
  Dochai S, Vetica F, Puttreddy R, et al. Angew. Chem. Int. Ed., 2016, 55(52):16153-16155 doi: 10.1002/anie.201610196
22. [22]
  MAO Yan-Li, LUO Shi-Tian, WU Jun-Feng, et al. Chinese J. Inorg. Chem., 2017, 33(1):81-88 doi: 10.11862/CJIC.2017.007
23. [23]
  Yoshikawa M, Tharpa K, Dima S O. Chem. Rev., 2016, 116(19):11500-11528 doi: 10.1021/acs.chemrev.6b00098
24. [24]
  Medlock J, Das A A K, Madden L A, et al. Chem. Soc. Rev., 2017, 46(16):5110-5127 doi: 10.1039/C7CS00179G
25. [25]
  Ashley J, Shahbazi M A, Kant K, et al. Biosens. Bioelectron., 2017, 91:606-615 doi: 10.1016/j.bios.2017.01.018
26. [26]
  Ansari S, Karimi M. Anal. Chem., 2017, 89:146-162
27. [27]
  Zhou Z P, Li T, Xu W Z, et al. Sens. Actuators B, 2017, 240:1114-1122 doi: 10.1016/j.snb.2016.09.092
28. [28]
  Yu J L, Wang X Y, Kang Q, et al. Environ. Sci-Nano, 2016, 4(2):493-502
29. [29]
  Yang J, Lin Z Z, Zhong H P, et al. Sens. Actuators B, 2017, 252:561-567 doi: 10.1016/j.snb.2017.06.042
30. [30]
  Bortoluzzi M, Reolon A, Castro J, et al. RSC Adv., 2016, 6(39):32727-32739 doi: 10.1039/C6RA01741J
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