Citation: WU Zhong-Yu, FAN Lei, TAO You-Rong, WANG Wei, WU Xing-Cai, ZHAO Jian-Wei. Pomelo Peel Derived Hierarchical Porous Carbon as Electrode Materials for High-Performance Supercapacitor[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1249-1260. doi: 10.11862/CJIC.2018.166 shu

Pomelo Peel Derived Hierarchical Porous Carbon as Electrode Materials for High-Performance Supercapacitor

WU Zhong-Yu ¹ ,
FAN Lei ¹ ,
TAO You-Rong ¹ ,
WANG Wei ¹ ,
WU Xing-Cai ^1,, ,
ZHAO Jian-Wei ^2,,

1.
Key Laboratory of Mesoscopic Chemistry of MOE, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
2.
School of Materials and Textile Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China

Corresponding author: WU Xing-Cai, wuxingca@nju.edu.cn ZHAO Jian-Wei, 13372034523@163.com
Received Date: 12 March 2018
Revised Date: 16 April 2018

Figures(7)

We propose a novel method using cetyltrimethyl ammonium bromide (CTAB) as soft template followed by successive graphitization and activation of pomelo peel to get a new biomass-derived hierarchical porous carbon (HPC). The as-obtained HPC possesses a high specific area of 1 813 m²·g^-1 with abundant mesopores structure, which is larger than that of 1 184 m²·g^-1 for the contrast of the porous carbon (PC) prepared without CTAB. X-ray photoelectron spectroscopy (XPS) analysis presents the oxygen doped amount for HPC is larger than that for PC, which could arise a high pseudocapacitance. In addition, the HPC also shows better electrochemical performance than PC, when utilized as an electrode material in supercapacitor. At a current density of 0.5 A·g^-1, the specific capacitance of HPC is up to 285 F·g^-1 in 1 mol·L^-1 KOH solution. Further investigation based on two-electrode cell suggests good performance with high rate capability and relative stability. Such excellent performance should be attributed to the synergistic effect of large specific surface area, high O-doping content and reasonable pore-size distribution.
- supercapacitor,
- biomass,
- porous carbon,
- soft template,
- energy storage
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