Citation: LIANG Li-Li, LIU Cong-Sen, ZONG Zhi-Hui, ZHANG Man-Li, ZHANG Bing-Yuan, CAO Rui, WANG Zi-Hao, PANG Miao-Miao, LI Yu-Jie, TAO Zhao-Lin. Syntheses, Crystal Structures and Antimicrobial Activities of Two Coordination Polymers Based on Bisbenzimidazole Ligands and V-Shaped Dicarboxylates[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1365-1372. doi: 10.11862/CJIC.2018.163 shu

Syntheses, Crystal Structures and Antimicrobial Activities of Two Coordination Polymers Based on Bisbenzimidazole Ligands and V-Shaped Dicarboxylates

Bengbu Medical College, Bengbu, Anhui 233030, China

Corresponding author: TAO Zhao-Lin, tao6838@163.com
Received Date: 14 February 2018
Revised Date: 30 March 2018

Figures(9)

Two coordination polymers {[Ni(bbmb)(dcpe)(H₂O)]·2H₂O}_n (1) and {[Mn₂(bbmb)(dcpe)₂(H₂O)]·1.5H₂O}_n (2) have been synthesized utilizing a linear benzimidazole ligand 4, 4'-bis(benzimidazol-1-ylmethy1)biphenyl) (bbmb) combined with a V-shaped dicarboxylates ligand 4, 4'-dicarboxydiphenyl ether (H₂dcpe). Compound 1 possesses a 2D thick layer structure with sql topology. Compound 2 possesses a 2D thick layer network with a linear tetranuclear Mn₄ cluster within the network. The in vitro antimicrobial activities showed that both compounds have effective inhibiting effects.
- benzimidazole ligand,
- crystal structure,
- antimicrobial properties,
- coordination polymers
1. [1]
  Horton D A, Bourne G T, Smythe M L. Chem. Rev., 2003, 103:893-930 doi: 10.1021/cr020033s
2. [2]
  Shalini K, Sharma P K, Kumar N. Der Chemica Sinica, 2010, 1:36-47
3. [3]
  Kim E, Yang J, Kim H O, et al. Biomaterials, 2013, 34:4327-4338 doi: 10.1016/j.biomaterials.2013.02.006
4. [4]
  CHEN Qing, LU Li-Ping. Chinese J. Inorg. Chem., 2016, 32(6):1001-1008
5. [5]
  Fang X J, Jeyakkumar P, Avula S R, et al. Bioorg. Med. Chem. Lett., 2016, 26:2584-2588 doi: 10.1016/j.bmcl.2016.04.036
6. [6]
  Zhang J, Yao D, Jiang Y. Bioorg. Chem., 2017, 72:168-181 doi: 10.1016/j.bioorg.2017.04.005
7. [7]
  Anderson E B, Long T E. Polymer, 2010, 51:2447-2454 doi: 10.1016/j.polymer.2010.02.006
8. [8]
  Özdena S, Atabey D, Yıldız S, et al. Bioorg. Med. Chem., 2005, 13:1587-1597 doi: 10.1016/j.bmc.2004.12.025
9. [9]
  Poyraz M, Sari M, Demirci F, et al. Polyhedron, 2008, 27:2091-2096 doi: 10.1016/j.poly.2008.03.030
10. [10]
  ZHANG Qi-Long, FENG Guang-Wei, WANG Li, et al. Chinese J. Inorg. Chem., 2014, 30(5):1025-1030
11. [11]
  McCann M, Curran R, Ben-Shoshan M, et al. Dalton Trans., 2012, 41:6516-6527 doi: 10.1039/c2dt12166b
12. [12]
  Arjmand F, Mohani B, Ahmad S. Eur. J. Med. Chem., 2005, 40:1103-1110 doi: 10.1016/j.ejmech.2005.05.005
13. [13]
  ZHAO Hai-Yan, YANG Xiao-Dong, LI Na. Chinese J. Inorg. Chem., 2017, 33(4):685-691
14. [14]
  Aghatabay N M, Neshat A, Karabiyik T, et al. Eur. J. Med. Chem., 2007, 42:205-213 doi: 10.1016/j.ejmech.2006.09.023
15. [15]
  Ou Z B, Lu Y H, Lu Y M, et al. J. Coord. Chem., 2013, 66:2152-2165 doi: 10.1080/00958972.2013.800195
16. [16]
  Kalinowska-Lis U, Felczak A, Chcińska L, et al. J. Organomet. Chem., 2014, 749:394-399 doi: 10.1016/j.jorganchem.2013.10.035
17. [17]
  Feng R, Hou Y, Wu Z Z, et al. Z. Anorg. Allg. Chem., 2015, 641:1918-1925 doi: 10.1002/zaac.201400511
18. [18]
  Liang L, Xue H, Chen F, et al. J. Mol. Struct., 2017, 1148:247-253 doi: 10.1016/j.molstruc.2017.07.056
19. [19]
  Dobrzańska L, Lloyd G O, Jacobs T, et al. J. Mol. Struct., 2006, 796:107-113 doi: 10.1016/j.molstruc.2006.02.059
20. [20]
  Singh K, Barwa M S, Tyagi P. Eur. J. Med. Chem., 2007, 42:394-402 doi: 10.1016/j.ejmech.2006.10.016
21. [21]
  (a) Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.
  (b)Sheldrick G M. SHELX-97, Program for the Solution and the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
22. [22]
  Spek A L. J. Appl. Cryst., 2003, 36:7-13 doi: 10.1107/S0021889802022112
23. [23]
  Janiak C. J. Chem. Soc. Dalton Trans., 2000, 29:3885-3896
24. [24]
  Yam V V W, Lo K K W. Chem. Soc. Rev., 1999, 28:323-334 doi: 10.1039/a804249g
25. [25]
  Sarma D, Ramanujachary K V, Lofland S E, et al. Inorg. Chem., 2009, 48:11660-11676 doi: 10.1021/ic901678c
26. [26]
  Qin L, Hu J, Li Y, et al. Cryst. Growth Des., 2012, 12:403-413 doi: 10.1021/cg2012638
27. [27]
  Mahmoud W H, Mohamed G G, El-Dessouky M M I. Spectrochim. Acta Part A, 2014, 122:598-608 doi: 10.1016/j.saa.2013.11.069
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