Citation: YANG Jian, TAO Jia-Yu, XIN Guo-Xiang, MENG Ting, YUAN Xue-Mei, DU Li-Ting, LI Xu, XU Hai-Jun. Syntheses, Characterization and Crystal Structures of Metal Coordination Polymers Based on L-Malic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1312-1318. doi: 10.11862/CJIC.2018.157 shu

Syntheses, Characterization and Crystal Structures of Metal Coordination Polymers Based on L-Malic Acid

YANG Jian ¹ ,
TAO Jia-Yu ¹ ,
XIN Guo-Xiang ¹ ,
MENG Ting ¹ ,
YUAN Xue-Mei ¹ ,
DU Li-Ting ² ,
LI Xu ² ,
XU Hai-Jun ^1,,

1.
College of Chemical Engineering, Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing 210037, China
2.
College of Science, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: XU Hai-Jun, xuhaijun@njfu.edu.cn
Received Date: 2 February 2018
Revised Date: 3 May 2018

Figures(4)

Three metal-organic coordination polymers, namely[{Zn(mal)(2, 2'-bipy)]₂·5H₂O}_n (1), {[Zn(mal)(Phen)(H₂O)]₂·3H₂O}_n (2) and {[Cu(mal)(Phen)]₂·4H₂O}_n (3) (H₂mal=L-malic acid, 2, 2'-bipy=2, 2'-bipyridine, Phen=phenanthroline), have been synthesized by the reaction of Zn(CH₃CO₂)₂·2H₂O or CuCl₂ with L-malic acid and cooperative ligand (2, 2'-bipy, Phen) in solution, respectively. They were characterized by powder and single X-ray diffraction analysis, FTIR spectroscopy and elemental analysis. Single crystal X-ray analysis reveals that complexes 1, and 2 crystallize in orthorhombic system with space group P2₁2₁2₁. In complexes 1 and 2, the two adjacent metal atoms are bridged by one malate group, constructing a one-dimensional zigzag chain, and two parallel 1D chains are constituted to form a novel ladder double chain structure through π-π weak interaction between the pyridine or phenanthroline rings. However, complex 3 crystallizes in monoclinic system with space group P2₁ and copper centers are also bridged by malate group, which is linked into one dimensional chain and self-assembled to form two dimensional lamellar supramolecular architectures through weak π-π interaction between the phenanthroline rings.
- coordination polymer,
- L-malic acid,
- bipyridine,
- phenanthroline
1. [1]
  Li D S, Wang Y Y, Luan X J, et al. Eur. J. Inorg. Chem., 2005(13):2678-2684
2. [2]
  Yu X Y, Fu Y, Fu J T, et al. J. Mol. Struct., 2018, 1157:530-535 doi: 10.1016/j.molstruc.2017.12.100
3. [3]
  Xu X X, Lu Y, Wang E B, et al. Inorg. Chim. Acta, 2007, 360(2):455-460 doi: 10.1016/j.ica.2006.07.111
4. [4]
  Guo F S, Chen Y C, Liu L J, et al. Chem. Commun., 2012, 48(100):12219-12221 doi: 10.1039/c2cc37510a
5. [5]
  Chen L L, Tan H L, Xu F G, et al. Luminescence, 2018, 33(1):161-167 doi: 10.1002/bio.v33.1
6. [6]
  He X, Lu C Z, Yan Y. Inorg. Chem. Commun., 2004, 7(7):851-853 doi: 10.1016/j.inoche.2004.04.024
7. [7]
  Song Y S, Yan B, Chen Z X. J. Solid State Chem., 2006, 179(12):4037-4046 doi: 10.1016/j.jssc.2006.07.040
8. [8]
  SUN Yin-Xia, ZHAO Ya-Yuan, LI Chun-Yu, et al. Chinese J. Inorg. Chem., 2016, 32(5):913-920 doi: 10.11862/CJIC.2016.118
9. [9]
  Park M K, Lim K S, Park J H, et al. CrystEngComm, 2016, 18(23):4349-4358 doi: 10.1039/C6CE00155F
10. [10]
  Bing Y Y, Yu M H, Hu M. RSC Adv., 2015, 5(58):47216-47224 doi: 10.1039/C5RA06012E
11. [11]
  Sen S, Neogi S, Aijaz A, et al. Dalton. Trans., 2014, 43(16):6100-6107 doi: 10.1039/C3DT52977K
12. [12]
  LI Dong-Sheng, WANG Xiao-Yu, LIU Ping, et al. Acta Chim. Sinica, 2005, 63(6):550-554
13. [13]
  Xin N, Sun Y Q, Zheng Y F, et al. J. Solid State Chem., 2016, 243:267-275 doi: 10.1016/j.jssc.2016.08.025
14. [14]
  TAN Xiong-Wen, LI Chang-Hong, LI Dong-Ping, et al. Chinese J. Inorg. Chem., 2009, 25(10):1877-1881 doi: 10.3321/j.issn:1001-4861.2009.10.030
15. [15]
  XIAO Bo-An, CHEN Shui-Sheng. Chinese J. Inorg. Chem., 2017, 33(2):347-353 doi: 10.11862/CJIC.2017.014
16. [16]
  Zhou Y H, Wang Z Y. Transition Met. Chem., 2015, 40(1):89-98 doi: 10.1007/s11243-014-9893-y
17. [17]
  Chowdhury M A. J. Biomed. Mater. Res. A, 2017, 105(4):1184-1194 doi: 10.1002/jbm.v105.4
18. [18]
  SHI Juan, LI Jiang, GE Hong-Guang. Chinese J. Inorg. Chem., 2017, 33(3):463-470 doi: 10.11862/CJIC.2017.050
19. [19]
  Feng X, Liu L, Wang L Y, et al. J. Solid State Chem., 2013, 206:277-285 doi: 10.1016/j.jssc.2013.08.029
20. [20]
  Kamatchi T S, Chitrapriya N, Kumar S L A, et al. RSC Adv., 2017, 7(27):16428-16443 doi: 10.1039/C7RA00425G
21. [21]
  Sheldrick G M. Acta Crystallogr. Sect. A:Found. Crystallogr., 2008, A64:112-122
22. [22]
  Guo Y, An H, Li Y, et al. Inorg. Chim. Acta, 2004, 357:4582-4586 doi: 10.1016/j.ica.2004.07.020
23. [23]
  Zhang X D, Sun J Y, Zhao Z, et al. Acta Crystallogr. Sect. C:Cryst. Struct. Commun., 2006, C62:m4-m6
24. [24]
  Li Q, Hu H, Li C, et al. Chin. J. Struct. Chem., 2017, 36(2):273-279
25. [25]
  Elsaidi S K, Mohamed M H, Banerjee D, et al. Coord. Chem. Rev., 2018, 358:125-152 doi: 10.1016/j.ccr.2017.11.022
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沈阳化工大学材料科学与工程学院沈阳 110142