Citation: TANG Sheng-Yang, MI Chang-Huan, WANG Jie. A Hybrid Aqueous Full Battery Based on LiMn₂O₄ Cathode and NaTi₂(PO₄)₃ Anode[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1279-1284. doi: 10.11862/CJIC.2018.155 shu

A Hybrid Aqueous Full Battery Based on LiMn₂O₄ Cathode and NaTi₂(PO₄)₃ Anode

Jiangsu Key Laboratory of Materials and Technology for Energy Conversion, College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

Corresponding author: MI Chang-Huan, mchmse@nuaa.edu.cn
Received Date: 17 January 2018
Revised Date: 29 April 2018

Figures(7)

A new aqueous full battery based on LiMn₂O₄ cathode and NaTi₂(PO₄)₃ anode with the hybrid ion electrolytes (1 mol·L^-1 Li₂SO₄+0.5 mol·L^-1 Na₂SO₄) was presented. The electrochemical performances of LiMn₂O₄ and NaTi₂(PO₄)₃ in the different aqueous electrolytes (1 mol·L^-1 Li₂SO₄, 0.5 mol·L^-1 Na₂SO₄ and 1 mol·L^-1 Li₂SO₄+0.5 mol·L^-1 Na₂SO₄) were characterized by the cyclic voltammetry (1 mV·s^-1) and the galvanostatic charge/discharge (265 mA·g^-1). The results show that Li⁺ ion could de-intercalation/intercalation from/into LiMn₂O₄ but Na⁺ could not because of its larger radius, and both ions (Li⁺ and Na⁺) could intercalation/de-intercalation into/from NaTi₂(PO₄)₃. The charge and discharge specific capacity was 100.1 and 74.9 mAh·g^-1, respectively, with a higher discharge voltage (1.55 V) for this aqueous full battery.
- aqueous full battery,
- hybrid ion electrolytes,
- high voltage,
- electrochemical performance,
- cyclic voltammetry
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A Hybrid Aqueous Full Battery Based on LiMn₂O₄ Cathode and NaTi₂(PO₄)₃ Anode