Citation: XIONG Liang-Bin, LI Shuang-Ming, LI Bi-Hui, ZENG Qing-Dong, WANG Bo-Yun, NIE Chang-Jiang. Preparation by a Simplified Hydro-Thermal Method and Photoelectrochemical Properties of n-Type Cu₂O Film[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1271-1278. doi: 10.11862/CJIC.2018.138 shu

Preparation by a Simplified Hydro-Thermal Method and Photoelectrochemical Properties of n-Type Cu₂O Film

1.
School of Physics and Electronic-Information Engineering, Hubei Engineering University, Xiaogan, Hubei 432000, China
2.
School of Chemistry and Material Science, Hubei Engineering University, Xiaogan, Hubei 432000, China

Corresponding author: LI Bi-Hui, cjnie@hust.edu.cn NIE Chang-Jiang, 379799338@qq.com
Received Date: 16 January 2018
Revised Date: 7 April 2018

Figures(4)

n-Type Cu₂O films were prepared by a simplified hydro-thermal method, using only Cu plate and NaCl solution as precursors. Subsequently, the prepared samples were characterized by X-ray diffraction (XRD), laser raman spectrometer (Raman), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and photoelectrochemical methods. The technology for the preparation of n-type Cu₂O films is simpler and lower cost than others and available for the industrialization. The prepared n-type Cu₂O films are highly crystallized and have high carrier concentrations (up to 9.75×10¹⁷ cm^-3) with Cl^- doping. The photoelectrochemical and EIS measurements demonstrate that the sample prepared in 0.1 mol·L^-1 NaCl solution with 50 h reaction time at 90℃ obtains the best photoelectrochemical properties.
- simplified hydrothermal method,
- n-type Cu₂O,
- photoelectrochemical properties,
- Cl^- doping,
- carrier concentration
1. [1]
  Xiong L B, Yu H X, Yang G Y, et al. Thin Solid Films, 2010, 518(23):6738-6745 doi: 10.1016/j.tsf.2010.05.117
2. [2]
  Xiong L B, Huang S, Yang X, et al. Electrochim. Acta, 2011, 56(6):2735-2739 doi: 10.1016/j.electacta.2010.12.054
3. [3]
  Lin M Y, Lee C Y, Shiu S C, et al. Org. Electron., 2010, 11(11):1828-1834 doi: 10.1016/j.orgel.2010.08.009
4. [4]
  Zou X W, Fan H Q, Tian Y M, et al. RSC Adv., 2015, 5(30):23401-23409 doi: 10.1039/C4RA13776K
5. [5]
  McShane C M, Choi K S. J. Am. Chem. Soc., 2009, 131(7):2561-2569 doi: 10.1021/ja806370s
6. [6]
  Lee M Y, Kim S H, Park I K. Physica B, 2016, 500:4-8 doi: 10.1016/j.physb.2016.07.025
7. [7]
  Cai X M, Su X Q, Ye F, et al. Appl. Phys. Lett., 2015, 107(8):083901 doi: 10.1063/1.4928527
8. [8]
  Minami T, Miyata T, Nishi Y. Thin Solid Films, 2014, 559:105-111 doi: 10.1016/j.tsf.2013.11.026
9. [9]
  Maira A J, Yeung K L, Lee C Y, et al. J. Catal., 2000, 192(1):185-196 doi: 10.1006/jcat.2000.2838
10. [10]
  Rühle S, Anderson A Y, Barad H, et al. J. Phys. Chem. Lett., 2012, 3(24):3755-3764 doi: 10.1021/jz3017039
11. [11]
  Olsen L C, Addis F W, Miller W. Sol. Cells, 1982, 7(3):247-279 doi: 10.1016/0379-6787(82)90050-3
12. [12]
  Luo J S, Steier L, Son M K, et al. Nano Lett., 2016, 16(3):1848-1857 doi: 10.1021/acs.nanolett.5b04929
13. [13]
  Cai X M, Su X Q, Ye F, et al. J. Alloys Compd., 2017, 697:5-10 doi: 10.1016/j.jallcom.2016.12.081
14. [14]
  Yin Z X, Song S K, You D J, et al. Small, 2015, 11(35):4576-4583 doi: 10.1002/smll.v11.35
15. [15]
  SUN Du, YIN Peng-Gang, GUO Lin, et al. Acta Phys.-Chim. Sin., 2011, 27(6):1543-1550
16. [16]
  Mao Y C, He J T, Sun X F, et al. Electrochim. Acta, 2012, 62:1-7 doi: 10.1016/j.electacta.2011.10.106
17. [17]
  YAN Li-Li, WANG Yan, XIONG Liang-Bin, et al. Chinese J. Inorg. Chem., 2009, 25(11):160-164
18. [18]
  Ghodselahi T, Vesaghi M A, Shafiekhani A, et al. Appl. Surf. Sci., 2008, 255(5):2730-2734 doi: 10.1016/j.apsusc.2008.08.110
19. [19]
  Nikesh V V, Mandale A B, Patil K R, et al. Mater. Res. Bull., 2005, 40(4):694-700 doi: 10.1016/j.materresbull.2004.12.008
20. [20]
  Xiong L B, Xiao H Q, Chen S S, et al. RSC Adv., 2014, 4(107):62115-62122 doi: 10.1039/C4RA12406E
21. [21]
  Vasquez R P. Surf. Sci. Spectra, 1993, 2(2):138-143 doi: 10.1116/1.1247732
22. [22]
  Han X F, Han K H, Tao M, et al. Thin Solid Films, 2010, 518(19):5363-5367 doi: 10.1016/j.tsf.2010.03.085
23. [23]
  Xiong L B, Ng T W, Yu Y, et al. Electrochim. Acta, 2015, 153:583-593 doi: 10.1016/j.electacta.2014.11.169
24. [24]
  Jiang T F, Xie T F, Chen L P, et al. Nanoscale, 2013, 5(7):2938-2944 doi: 10.1039/c3nr34219k
25. [25]
  Yang X Y, Wolcott A, Wang G M, et al. Nano Lett., 2009, 9(6):2331-2336 doi: 10.1021/nl900772q
26. [26]
  Yu L, Xiong L B, Yu Y. J. Phys. Chem. C, 2015, 119(40):22803-22811 doi: 10.1021/acs.jpcc.5b06736
27. [27]
  Gonzalez-Pedro V, Juarez-Perez E J, Arsyad W S, et al. Nano Lett., 2014, 14(2):888-893 doi: 10.1021/nl404252e
28. [28]
  Fabregat-Santiago F, Bisquert J, Cevey L, et al. J. Am. Chem. Soc., 2009, 131(2):558-562 doi: 10.1021/ja805850q
29. [29]
  Hong S J, Lee S, Jang J S, et al. Energy Environ. Sci., 2011, 4(5):1781-1787 doi: 10.1039/c0ee00743a
1. [1]
  Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 100014-. doi: 10.3866/PKU.WHXB202309047
2. [2]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
3. [3]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
4. [4]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
5. [5]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
6. [6]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
7. [7]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
8. [8]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
9. [9]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
10. [10]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
11. [11]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
12. [12]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
13. [13]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
14. [14]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
15. [15]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
16. [16]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
17. [17]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
18. [18]
  Caixia Lin , Ting Liu , Zhaojiang Shi , Hong Yan , Keyin Ye , Yaofeng Yuan . Innovative Experiment of Electrochemical Dearomative Spirocyclization of N-Acyl Sulfonamides. University Chemistry, 2025, 40(4): 359-366. doi: 10.12461/PKU.DXHX202406107
19. [19]
  Kaihui Huang , Boning Feng , Xinghua Wen , Lei Hao , Difa Xu , Guijie Liang , Rongchen Shen , Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204
20. [20]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1110)
HTML views(254)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation by a Simplified Hydro-Thermal Method and Photoelectrochemical Properties of n-Type Cu2O Film

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation by a Simplified Hydro-Thermal Method and Photoelectrochemical Properties of n-Type Cu₂O Film