Citation: LIAO Hai-Shen, LI Chen, YI Xiao-Yi. tert-Butyl Hydroperoxide Oxygenation of Alcohol Catalyzed by Diruthenium Diphosphonate in Aqueous Solution[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 883-888. doi: 10.11862/CJIC.2018.128 shu

tert-Butyl Hydroperoxide Oxygenation of Alcohol Catalyzed by Diruthenium Diphosphonate in Aqueous Solution

LIAO Hai-Shen ¹ ,
LI Chen ¹ ,
YI Xiao-Yi ^1,2,,

1.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
2.
Hunan provincial Key Laboratory of Efficient and Clear Utilization of Manganese Resources, Central South University, Changsha 410083, China

Corresponding author: YI Xiao-Yi, xyyi@csu.edu.cn
Received Date: 2 October 2017
Revised Date: 24 January 2018

Figures(3)

(NH₄)₃[Ru₂(hedp)₂]·2H₂O (hedp=1-hydroxyethylidenediphosphonate) with t-BuOOH as oxidant is proved to be highly effective in the catalytic oxidation of alcohol, such as secondary alcohol and long-chain aliphatic alcohol, in aqueous solution at room temperature. The phase-transfer catalyst is not necessary. The acid or the coordinated base inhibits ketone production, while the base improves the reaction selectivity and the yield. The mechanism is proposed as a peroxometal pathway. The UV-Vis spectra prove that the key intermediates Ru₂-OO^tBu is formed.
- dinuclear ruthenium,
- metal-metal bond,
- alcohol oxidation,
- aqueous solution
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