Citation: JIN Ping-Ning, YAN Rui-Fang, HU Peng, WU Yan-Ni, GAO Yuan-Yuan, HUANG Ling-Zhu, ZHU Yi-Xuan, SU Yan, WANG Ying-Ling. Dinuclear Gd(Ⅲ)/Dy(Ⅲ) Complexes Based on Schiff base Ligands: Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 951-956. doi: 10.11862/CJIC.2018.126 shu

Dinuclear Gd(Ⅲ)/Dy(Ⅲ) Complexes Based on Schiff base Ligands: Structures and Magnetic Properties

JIN Ping-Ning ¹ ,
YAN Rui-Fang ¹ ,
HU Peng ^2,3,, ,
WU Yan-Ni ² ,
GAO Yuan-Yuan ^4,, ,
HUANG Ling-Zhu ² ,
ZHU Yi-Xuan ² ,
SU Yan ² ,
WANG Ying-Ling ⁵

1.
Analysis & Test Laboratory, Department of Basic Medical University, Xinxiang, Henan 453003, China
2.
Environment and Chemical Engineering College, Zhaoqing University, Zhaoqing, Guangdong 526061, China
3.
Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), Nankai University, Tianjin 300071, China
4.
Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, China
5.
School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang, Henan 453003, China

Corresponding author: HU Peng, hp8286799@163.com GAO Yuan-Yuan, wsxz1022@163.com
Received Date: 25 August 2017
Revised Date: 1 April 2018

Figures(6)

Two novel dinuclear Ln(Ⅲ) complexes[Gd₂(L)₄(HCOO)₂(CH₃OH)₂] (1) and[Dy₂(L)₄(CH₃COO)₂(CH₃OH)₂] (2) (HL=2-hydroxy-3-methoxy-5-bromobenzaldehyde oxime) have been successfully synthesized and characterized by single crystal X-ray diffraction, IR spectroscopy and elemental analyses. Single crystal X-ray crystallographic analyses reveal that these two complexes have similar structures, in which two symmetric nine-coordinate Ln(Ⅲ) ions are bridged by two phenoxide groups from two Schiff base ligands, two formate ions for 1 and two acetate ions for 2 respectively. Magnetic studies reveal that weak antiferromagnetic interaction between Gd(Ⅲ) ions existing in complex 1, while complex 2 shows slow relaxation of magnetization. CCDC: 1570377, 1; 1570378, 2.
- Schiff base,
- dinuclear,
- lanthanide,
- crystal structure,
- magnetic property
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