Citation: YANG Long, WANG Qin, DENG Yong-Jun, WANG Xiao-Yuan, HE Ren, YI Zhi-Yong, JIANG Long, QIU Yong. Effect of Metal Exchange on the Light-Absorbing and Band-Gap Properties of Nanoporous Zn-Cu based MOFs[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1199-1208. doi: 10.11862/CJIC.2018.117 shu

Effect of Metal Exchange on the Light-Absorbing and Band-Gap Properties of Nanoporous Zn-Cu based MOFs

YANG Long ^1,, ,
WANG Qin ² ,
DENG Yong-Jun ³ ,
WANG Xiao-Yuan ¹ ,
HE Ren ¹ ,
YI Zhi-Yong ¹ ,
JIANG Long ² ,
QIU Yong ^1,,

1.
Institute of Systems Engineering, China Academy of Engineering Physics, Mianyang, Sichuan 621999, China
2.
State Key Laboratory of Polymer Materials Engineering of China, Polymer Research Institute of Sichuan University, Chengdu 610065, China
3.
Shock and Vibration of Engineering Materials and Structures Key Laboratory of Sichuan Province, Mianyang, Sichuan 621000, China

Corresponding author: YANG Long, rjcyangl@caep.cn QIU Yong, qiuy@caep.cn
Received Date: 20 December 2017
Revised Date: 20 March 2018

Figures(8)

Cu(Ⅱ) and Zn(Ⅱ) ions were selected as the basic mixed metal nodes connected by organic ligand 1, 4-benzenedicarboxylic acid (BDC) and synthesized nanoporous Zn-Cu based mixed-metal MOFs Zn(BDC)-Cu, Cu(BDC)-Zn and Zn-Cu-BDC through different synthetic routes. Through characterization of PXRD, SEM, UV-Vis DRS, FT-IR, XPS and UPS and systematic analysis, it is found that the solar light absorbing range of Zn(BDC) is located in UV band (< 400 nm), while Cu(BDC) mainly absorbs the whole visible light (500~1 000 nm). Additionally, the Zn-Cu ions uniformly-dispersed product Zn-Cu-BDC performs better in light-absorption and exhibits lower photo band-gap and HOMO level than the other bi-metallic products Zn(BDC)-Cu and Cu(BDC)-Zn. The investigation might inspire the design of heterogeneous photocatalysts and organic-inorganic hybrids in the aspects of light-absorption and charge transfer and construction methods on metal exchange due to different routes leading to different properties despite of the same components.
- metal-organic frameworks (MOFs),
- Zn-Cu,
- metal exchange,
- light-absorption,
- band gap
1. [1]
  Allendorf M D, Stavila V. CrystEngComm, 2015, 17:229-246 doi: 10.1039/C4CE01693A
2. [2]
  Yang C, You X, Cheng J H, et al. Appl. Catal. B:Environ., 2017, 200:673-680 doi: 10.1016/j.apcatb.2016.07.057
3. [3]
  Stassen I, Burtch N, Talin A, et al. Chem. Soc. Rev., 2017, 46:3185-3241 doi: 10.1039/C7CS00122C
4. [4]
  Brozek C K, Dinca M. Chem. Soc. Rev., 2014, 43:5456-5467 doi: 10.1039/C4CS00002A
5. [5]
  Lalonde M, Bury W, Karagiaridi O, et al. J. Mater. Chem. A, 2013, 1:5453-5468 doi: 10.1039/c3ta10784a
6. [6]
  Deria P, Mondloch J E, Karagiaridi O, et al. Chem. Soc. Rev., 2014, 43:5896-5912 doi: 10.1039/C4CS00067F
7. [7]
  Yang L, Yu Y Y, Feng J, et al. J. Photochem. Photobiol. A, 2018, 350:103-110 doi: 10.1016/j.jphotochem.2017.09.069
8. [8]
  Dinca M, Long J R. J. Am. Chem. Soc., 2007, 129:11172-11176 doi: 10.1021/ja072871f
9. [9]
  Fei H H, Cahill J F, Prather K A, et al. Inorg. Chem., 2013, 52:4011-4016 doi: 10.1021/ic400048g
10. [10]
  Genna D T, Wong-Foy A G, Matzger A J, et al. J. Am. Chem. Soc., 2013, 135:10586-10589 doi: 10.1021/ja402577s
11. [11]
  Das M C, Xiang S C, Zhang Z J, et al. Angew. Chem. Int. Ed., 2011, 50:10510-10520 doi: 10.1002/anie.201101534
12. [12]
  Braglia L, Borfecchia E, Maddalena L, et al. Catal. Today, 2017, 283:89-103 doi: 10.1016/j.cattod.2016.02.039
13. [13]
  Shi D Y, He C, Sun W L, et al. Chem. Commun., 2016, 52:4714-4717 doi: 10.1039/C6CC00862C
14. [14]
  Lee Y, Kim S, Kang J K, et al. Chem. Commun., 2015, 51:5735-5738 doi: 10.1039/C5CC00686D
15. [15]
  Chambers M B, Wang X, Elgrishi N, et al. ChemSusChem, 2015, 8:603-608 doi: 10.1002/cssc.v8.4
16. [16]
  YU Qi, CHEN Yao, ZHANG Zhen-Jie, et al. Chinese J. Inorg. Chem., 2017, 33(11):1991-2004
17. [17]
  Prasad T K, Hong D H, Suh M P. Chem. Eur. J., 2010, 16:14043-14050 doi: 10.1002/chem.v16.47
18. [18]
  Procopio E Q, Linares F, Montoro C, et al. Angew. Chem. Int. Ed., 2010, 49:7308-7311 doi: 10.1002/anie.v49:40
19. [19]
  Brozek C K, Dinca M. J. Am. Chem. Soc., 2013, 135:12886-12891 doi: 10.1021/ja4064475
20. [20]
  Talin A A, Centrone A, Ford A C, et al. Science, 2014, 343:66-69 doi: 10.1126/science.1246738
21. [21]
  Shimizu G K, Taylor J M, Kim S. Science, 2013, 341:354-355 doi: 10.1126/science.1239872
22. [22]
  Biemmi E, Christian S, Stock N, et al. Microporous Mesopo-rous Mater., 2009, 117:111-117 doi: 10.1016/j.micromeso.2008.06.040
23. [23]
  Adams R, Carson C, Ward J, et al. Microporous Mesoporous Mater., 2010, 131:13-20 doi: 10.1016/j.micromeso.2009.11.035
24. [24]
  Irving H, Williams R J P. J. Chem. Soc., 1953, 637:3192-3210
25. [25]
  Song X K, Jeong S, Kim D, et al. CrystEngComm, 2012, 14:5753-5756 doi: 10.1039/c2ce26115d
26. [26]
  Li J P, Li L K, Hou H W, et al. Cryst. Growth Des., 2009, 9:4504-4513 doi: 10.1021/cg9005218
27. [27]
  Hafizovic J, Bjrgen M, Olsbye U, et al. J. Am. Chem. Soc., 2007, 129:3612-3620 doi: 10.1021/ja0675447
28. [28]
  Samuel M. Hawxwell, Brammer L. CrystEngComm, 2006, 8:473-476 doi: 10.1039/b603274e
29. [29]
  Puthiaraj P, Suresh P, Pitchumani K. Green Chem., 2014, 16:2865-2875 doi: 10.1039/c4gc00056k
30. [30]
  Song X K, Kim T K, Kim H, et al. Chem. Mater., 2012, 24:3065-3073 doi: 10.1021/cm301605w
31. [31]
  Gao L, Zhao B, Li G, et al. Inorg. Chem. Commun., 2003, 6:1249-1251 doi: 10.1016/S1387-7003(03)00242-9
32. [32]
  Kozachuk O, Khaletskaya K, Halbherr M, et al. Eur. J. Inorg. Chem., 2012:1688-1695
33. [33]
  Nguyen H L, Vu T T, Le D, et al. ACS Catal., 2016, 7:338-342
34. [34]
  Kong L M, Bjelkevig C, Gaddam S, et al. J. Phys. Chem. C, 2010, 114:21618-21624 doi: 10.1021/jp108616h
35. [35]
  Ueno N, Kera S, Sakamoto K, et al. Appl. Phys. A, 2008, 92:495-504 doi: 10.1007/s00339-008-4553-8
36. [36]
  Sueyoshi T, Kakuta H, Ono M, et al. Appl. Phys. Lett., 2010, 96:093303.1-3
37. [37]
  Liu G M, Jaegermann W, He J J, et al. J. Phys. Chem. B, 2002, 106:5814-5819 doi: 10.1021/jp014192b
38. [38]
  Rensmo H, Westermark K, Sodergren S, et al. J. Chem. Phys., 1999, 111:2744-2750 doi: 10.1063/1.479551
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