Citation: WANG Rui, GONG Yong, XU Hai-Juan, WEI Shi-Yong, WU De-Yong. Characteristics and Adsorption Properties of Se(Ⅳ) for MOF-Fe Prepared with Different Conditioning Agents[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 906-916. doi: 10.11862/CJIC.2018.110 shu

Characteristics and Adsorption Properties of Se(Ⅳ) for MOF-Fe Prepared with Different Conditioning Agents

WANG Rui ¹ ,
GONG Yong ² ,
XU Hai-Juan ¹ ,
WEI Shi-Yong ^1,3,, ,
WU De-Yong ^1,3

1.
Department of Chemistry and Environmental Engineering, Hubei University for Nationalities, Enshi, Hubei 445000, China
2.
Hubei Polytechnic Institute, Wuhan 432000, China
3.
Key Laboratory of Biologic Resource Protection and Utilization of Hubei Province, Enshi, Hubei 445000, China

Corresponding author: WEI Shi-Yong, weishiyong2007@126.com
Received Date: 6 December 2017
Revised Date: 28 January 2018

Figures(7)

MOF-Fe samples were prepared with HF, HCl, H₂O and NaAc as conditioning agents by hydrothermal method. The characteristics of the samples were studied by X-ray diffraction (XRD), Transmission electron microscope (TEM), N₂ adsorption/desorption, thermal analysis (TG/DTG and DTA) and proton potentiometric titration. Isothermal adsorption experiments of selenite (Se(Ⅳ)) on the samples were carried out. Crystal structure of all samples are same as MIL-100(Fe), and the morphology are octahedral, while the crystallinities and crystal orientations are different. The BET surface area are 1 683, 1 517, 1 641 and 1 734 m²·g^-1, respectively, and total pore volumes of the samples are decreased orderly. The micropore diameter are 1.27, 1.22, 1.22 and 1.17 nm for MOF-Fe(HF), MOF-Fe(HCl), MOF-Fe(H₂O) and MOF-Fe(NaAc). The temperature of decarboxylation of MOF-Fe(HF) is highest (415℃), while its carbonization temperature for benzene ring is lowest (462℃) compared with the others. A weight loss caused by redox between iron oxide and carbon appears in MOF-Fe(HCl), MOF-Fe(H₂O) and MOF-Fe(NaAc). The sequence of H⁺ consumed during the process of proton potentiometric titrations for samples is MOF-Fe(H₂O) > MOF-Fe(HCl) > MOF-Fe(HF)=MOF-Fe(NaAc), and pH value of zero point charge (pH_ZPC) are 3.1, 3.5, 3.6 and 3.5 accordingly. The sequence about the affinity of adsorption for Se(Ⅳ) on samples is MOF-Fe(NaAc) > MOF-Fe(HCl) > MOF-Fe(H₂O) > MOF-Fe(HF), and the maximum adsorption capacities (Q_m) are 77.69, 107.07, 117.40 and 87.15 mg·g^-1 correspondingly. The Q_m of Se(Ⅳ) on samples have positive correlation with density of hydroxyl for samples observably. This study reveals that the thermostability and density of active site of MOF-Fe are influenced by the conditioning agent when MOF-Fe was prepared. The HF could increase the strength of C-C between carboxyl and benzene ring, decrease carbonization temperature of benzene ring of MOF-Fe, and improve the thermostability of iron oxides after heating. While HCl and H₂O could improve the density of active site in samples, then the Q_m of Se(Ⅳ) adsorbed on MOF-Fe could be increased.
- MOF-Fe,
- conditioning agent,
- surface properties,
- adsorption,
- selenite
1. [1]
  Ju W, Li W, Li Z, et al. J. Trace Elem. Med. Biol., 2017, 44:8-16 doi: 10.1016/j.jtemb.2017.04.009
2. [2]
  Winkel L H, Johnson C A, Lenz M, et al. Environ. Sci. Technol., 2011, 46(2):571-579
3. [3]
  Fernández-Martínez A, Charlet L. Rev. Environ. Sci. Biote-chnol., 2009, 8(1):81-110 doi: 10.1007/s11157-009-9145-3
4. [4]
5. [5]
  ZHU Jian-Ming, QIN Hai-Bo, LI Lu, et al. Acta Scientiae Circumstantiae, 2008, 28(4):772-777
6. [6]
  Santos S, Ungureanu G, Boaventura R, et al. Sci. Total Environ., 2015, 521-522:246-260 doi: 10.1016/j.scitotenv.2015.03.107
7. [7]
  WANG Lin, SHI Yong-Sheng. Treatment of Waster Water Contain Selenium. Beijing:Chemistry Industry Press, 2005.
8. [8]
  Hu B W, Ye F, Jin C G, et al. Chemosphere, 2017, 184:408-416 doi: 10.1016/j.chemosphere.2017.05.179
9. [9]
  Xia X F, Ling L, Zhang W X. Chemosphere, 2017, 168:1597-1603 doi: 10.1016/j.chemosphere.2016.11.150
10. [10]
  Chan Y T, Kuan W H, Chen T Y, et al. Water Res., 2009, 43(17):4412-4420 doi: 10.1016/j.watres.2009.06.056
11. [11]
  Ma Z Y, Shan C, Liang J L, et al. Chemosphere, 2018, 193:134-141 doi: 10.1016/j.chemosphere.2017.11.005
12. [12]
  Rosi N L, Eckert J, Eddaoudi M, et al. Science, 2003, 300(5622):1127-1129 doi: 10.1126/science.1083440
13. [13]
  Sun J K, Xu Q. Energy Environ. Sci., 2014, 7(7):2071-2100 doi: 10.1039/c4ee00517a
14. [14]
  Alezi D, Belmabkhout Y, Suyetin M, et al. J. Am. Chem. Soc., 2015, 137(41):13308-13318 doi: 10.1021/jacs.5b07053
15. [15]
  Cao X H, Zheng B, Shi W H, et al. Adv. Mater., 2015, 27(32):4695-4701 doi: 10.1002/adma.v27.32
16. [16]
  Chen Q S, Sun J L, Li P, et al. J. Am. Chem. Soc., 2016, 138(43):14242-14245 doi: 10.1021/jacs.6b09880
17. [17]
  HUANG Gang, CHEN Yu-Zhen, JIANG Hai-Long. Acta Chim. Sinica, 2016, 74(02):113-129
18. [18]
  Guo H L, Zhu Y Z, Wang S, et al. Chem. Mater., 2012, 24(3):444-450 doi: 10.1021/cm202593h
19. [19]
  Cheng X Q, Zhang A F, Hou K K, et al. Dalton Trans., 2013, 42:13698-13705 doi: 10.1039/c3dt51322j
20. [20]
  Liu Y L, Gao P F, Huang C Z, et al. Sci. China Ser. B:Chem., 2015, 58(10):1553-1560 doi: 10.1007/s11426-015-5406-x
21. [21]
  Kumar P, Pournara A, Kim K H, et al. Prog. Mater. Sci., 2017, 86:25-74 doi: 10.1016/j.pmatsci.2017.01.002
22. [22]
  Patra S, Sene S, Mousty C, et al. ACS Appl. Mater. Interfaces, 2016, 8(31):20012-20022 doi: 10.1021/acsami.6b05289
23. [23]
  Bghadra B N, Jhung S H. ACS Appl. Mater. Interfaces, 2016, 8(10):6770-6777 doi: 10.1021/acsami.6b00608
24. [24]
  Zhu N N, Liu X H, Li T, et al. Inorg. Chem., 2017, 56(5):3414-3420
25. [25]
  Liu X C, Zhou Y Y, Zhang J C, et al. ACS Appl. Mater. Interfaces, 2017, 9(24):20255-20275 doi: 10.1021/acsami.7b02563
26. [26]
  Song G Q, Wang Z Q, Wang L, et al. Chin. J. Catal., 2014, 35(2):185-195 doi: 10.1016/S1872-2067(12)60729-3
27. [27]
  Lee Y R, Kim J, Ahn W S. Korean J. Chem. Eng., 2013, 30(9):1667-1680 doi: 10.1007/s11814-013-0140-6
28. [28]
  ZHANG Su, WANG Hai-Shui. Chinese J. Inorg. Chem., 2013, 29(1):31-35
29. [29]
  ZHAO Xin-Hua, CHEN Lin, CAO Yong-Ge, et al. Foundation of Solid-State Inorganic Chemistry and the Design Synthesis of Novel Materials. Beijing:Higher Education Press, 2012:128-131, 610-611
30. [30]
  Cornell R M, Schwertmann U. The Iron Oxides, Structure, Properties, Reactions Occurences, Uses. Weinheim: Wiley-VCH, 2003.
31. [31]
  Zhang L. Thesis for the Doctorate of Michigan Technological University. 2011.
32. [32]
  JIANG Wu-Feng, ZHAO Shuo, HAO Su-Ju, et al. Chinese Journal of Process Engineering, 2017, 17(2):362-366 doi: 10.12034/j.issn.1009-606X.216283
33. [33]
34. [34]
  Kuang L Y, Liu Y Y, Fu D D, et al. J. Colloid Interface Sci., 2017, 490:259-269 doi: 10.1016/j.jcis.2016.11.071
35. [35]
  Hajjaji W, Ganiyu S O, Tobaldi D M, et al. Appl. Clay Sci., 2013, 83-84:91-98 doi: 10.1016/j.clay.2013.08.013
36. [36]
  Chen L, Ji T, Mu L W, et al. J. Environ. Manage., 2017, 196:168-177 doi: 10.1016/j.jenvman.2017.03.013
1. [1]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
2. [2]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
3. [3]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-0. doi: 10.1016/j.actphy.2024.100039
4. [4]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
5. [5]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
6. [6]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
7. [7]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
8. [8]
  Wei Li , Jinfan Xu , Yongjun Zhang , Ying Guan . 共价有机框架整体材料的制备及食品安全非靶向筛查应用——推荐一个仪器分析综合化学实验. University Chemistry, 2025, 40(6): 276-285. doi: 10.12461/PKU.DXHX202406013
9. [9]
  Xueqi Yang , Juntao Zhao , Jiawei Ye , Desen Zhou , Tingmin Di , Jun Zhang . 调节NNU-55(Fe)的d带中心以增强CO₂吸附和光催化活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-0. doi: 10.1016/j.actphy.2025.100074
10. [10]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
11. [11]
  Yang ZHOU , Lili YAN , Wenjuan ZHANG , Pinhua RAO . Thermal regeneration of biogas residue biochar and the ammonia nitrogen adsorption properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1574-1588. doi: 10.11862/CJIC.20250032
12. [12]
  Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068
13. [13]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
14. [14]
  Ying Liu , Jia Ji , Yinling Hou , Lilan Guo , Xuan Lv . Selenium’s Journey. University Chemistry, 2025, 40(7): 218-224. doi: 10.12461/PKU.DXHX202409046
15. [15]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
16. [16]
  Yuan Chun , Yongmei Liu , Fuping Tian , Hong Yuan , Shu'e Song , Wanchun Zhu , Yunchao Li , Zhongyun Wu , Xiaokui Wang , Yunshan Bai , Li Wang , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement of Colloidal and Surface Chemical Properties, Molecular Structure and Properties. University Chemistry, 2025, 40(5): 178-188. doi: 10.12461/PKU.DXHX202503053
17. [17]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
18. [18]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
19. [19]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
20. [20]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102

Get Citation

PDF

XML

Metrics

PDF Downloads(24)
Abstract views(4028)
HTML views(1219)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142