Citation: XU Zhou-Qing, HE Ya-Ling, LI Qing-Qing, ZHANG Pei-Ling, LI Hui-Jun, WANG Yuan. Three Complexes Based on Pyridine-Pyrazine-Hydrazone Ligand:Syntheses, Photocatalysis and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 757-766. doi: 10.11862/CJIC.2018.104 shu

Three Complexes Based on Pyridine-Pyrazine-Hydrazone Ligand:Syntheses, Photocatalysis and Luminescent Properties

1.
College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China
2.
College of Physics and Electronic Information, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: ZHANG Pei-Ling, plzhang@hpu.edu.cn LI Hui-Jun, lihuijunxgy@hpu.edu.cn WANG Yuan, wangyuan08@hpu.edu.cn
Received Date: 17 September 2017
Revised Date: 24 January 2018

Figures(8)

Three novel complexes, namely {[Zn₃(L)₂(SO₄)₂(H₂O)₄]·H₂O}_n (1), {[Cd₂(L)₂(SO₄)(H₂O)]·H₂O}_n (2) and {[Cd(L)I]·CH₃OH}_n (3).(HL=N'-nicotinoylpyrazine-2-carbohydrazonamide), have been synthesized and character-ized by elemental analyses, infrared spectra and single-crystal X-ray diffraction analyze.In complex 1, Zn(Ⅱ) ions are connected by μ₃, η¹η¹η¹-SO₄^2- anions to form a inorganic layer motif in bc plane, and the L^- ligands are decorated on both sides of the layer.Adjacent layers are connected by hydrogen-bonding interactions giving rise to 3D supramolecular network.The 2D complex 2 is formed by the[(Cd2)₂(μ₂-SO₄)₂] units and Cd1 ions which are connected by the ligands.Adjacent layers of 2 are extended into 3D supramolecular network by π…π interactions.Zigzag 1D chains of complex 3 are connected by intermolecular hydrogen bonds into extended plane structure.The photocatalytic degradation of methylene blue (MB) results indicate that complexes 1~3 are excellent candidates as photocatalysts in decomposing MB with the presence of H₂O₂.In addition, the luminescent properties of these three complexes have been studied in the solid-state.
- metal-organic framework,
- luminescent property,
- photocatalytic degradation
1. [1]
  Yang H, He X W, Wang F, et al. J.Mater.Chem., 2012, 22:21849-21851 doi: 10.1039/c2jm35602c
2. [2]
  Waranusantigul P, Pokethitiyook P, Kruatrachue M, et al. Environ.Pollut., 2003, 125:385-392 doi: 10.1016/S0269-7491(03)00107-6
3. [3]
  Xu X Y, Chen Q C, Yu Y D, et al. Inorg.Chem., 2016, 55:75-82 doi: 10.1021/acs.inorgchem.5b01820
4. [4]
  Herm Z R, Wiers B M, Mason J A, et al. Science, 2013, 340:960-964 doi: 10.1126/science.1234071
5. [5]
  Lin R B, Chen D, Lin Y Y, et al. Inorg.Chem., 2012, 51:9950-9955 doi: 10.1021/ic301463z
6. [6]
  Liu J Q, Wang W J, Luo Z D, et al. Inorg.Chem., 2017, 56:10215-10219 doi: 10.1021/acs.inorgchem.7b00851
7. [7]
  Neupane G P, Tran M D, Yun S J, et al. ACS Appl.Mater.Interfaces, 2017, 9:11950-11958 doi: 10.1021/acsami.6b15239
8. [8]
  Luo L, Lin H S, Li L, et al. Inorg.Chem., 2014, 53:3464-3470 doi: 10.1021/ic402910a
9. [9]
  Yu X, Fan X, Li Z, et al. Dalton Trans., 2017, 46:11898-11904 doi: 10.1039/C7DT02824E
10. [10]
  Jiang D L, Li J, Xing C S, et al. ACS Appl.Mater.Interfaces, 2015, 34:19234-19242
11. [11]
  Lee Y Y, Moon J H, Choi Y S, et al. J.Phys.Chem.C, 2017, 121:5137-5144 doi: 10.1021/acs.jpcc.7b00038
12. [12]
  Hussain N, Bhardwaj V K. Dalton Trans., 2016, 45:7697-7707 doi: 10.1039/C6DT00612D
13. [13]
  Wang Y N, Yang Q F, Li G H, et al. Dalton Trans., 2014, 43:11646-11657 doi: 10.1039/C4DT00780H
14. [14]
  Xu J, Zhou T, Xu Z Q, et al. J.Mol.Struct., 2017, 1128:448-454 doi: 10.1016/j.molstruc.2016.09.016
15. [15]
  Xu Z, Mao X, Zhang P, et al. J.Mol.Struct., 2017, 1128:665-673 doi: 10.1016/j.molstruc.2016.09.041
16. [16]
  Sheldrick G M.SHELXL97, Program for the Crystal Structure Refinement, University of Göttingen, Germany, 1997.
17. [17]
  Sheldrick G M.SADABS, University of Göttingen, Germany, 1996.
18. [18]
  Xu C, Rangaiah G P, Zhao X S. Ind.Eng.Chem.Res., 2014, 53:14641-14649 doi: 10.1021/ie502367x
19. [19]
  Dong Y B, Wang P, Ma J P, et al. J.Am.Chem.Soc., 2007, 129:4872-4873 doi: 10.1021/ja070058e
20. [20]
  Jin J C, Wang Y Y, Liu P, et al. Cryst.Growth Des., 2010, 10:2029-2035 doi: 10.1021/cg901201s
21. [21]
  Xiao D R, Li Y G, Wang E B, et al. Inorg.Chem., 2007, 46:4158-4166 doi: 10.1021/ic070054a
22. [22]
  Shen S L, Zhao X, Zhang X F, et al. J.Mater.Chem.B, 2017, 5:289-295 doi: 10.1039/C6TB01992G
23. [23]
  McFadden P D, Frederick K, Argüello L A, et al. ACS Appl.Mater.Interfaces, 2017, 9:10061-10068 doi: 10.1021/acsami.6b13218
24. [24]
  XU Zhou-Qing, HE Ya-Ling, LI Hui-Jun, et al. Chinese J.Inorg.Chem., 2017, 33:897-904 doi: 10.11862/CJIC.2017.097
25. [25]
  LI Hui-Jun, YAN Ling-Ling, WANG Yuan, et al. Chinese J.Inorg.Chem., 2016, 32:1831-1838
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2. [2]
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沈阳化工大学材料科学与工程学院沈阳 110142