Citation: LIU Yuan-Yuan, ZHANG Hui-Min, WANG Xin-Rui, DING Bo, LIU Zhen-Yu, DING Bin. Hydrothermal Assembly and Photocatalytic Characterization of Polyoxometalate-Based Cu^Ⅱ and Cu^Ⅰ Hybrid Coordination Framework with 4-Amino-1, 2, 4-triazole[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 791-799. doi: 10.11862/CJIC.2018.097 shu

Hydrothermal Assembly and Photocatalytic Characterization of Polyoxometalate-Based Cu^Ⅱ and Cu^Ⅰ Hybrid Coordination Framework with 4-Amino-1, 2, 4-triazole

LIU Yuan-Yuan ^1,2,, ,
ZHANG Hui-Min ¹ ,
WANG Xin-Rui ¹ ,
DING Bo ¹ ,
LIU Zhen-Yu ¹ ,
DING Bin ^1,2

1.
Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Tianjin Normal University, Tianjin 300387, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: LIU Yuan-Yuan, hxxylyy@mail.tjnu.edu.cn
Received Date: 13 December 2017
Revised Date: 7 January 2018

Figures(5)

Under hydrothermal conditions, two novel polyoxometalate (POM)-based Cu^Ⅱ and Cu^Ⅰ hybrid materials, namely[Cu₂(4-NH₂-trz)₄(Mo₈O₂₆)(H₂O)₄]·5H₂O (1) and[Cu₄(4-NH₂-trz)₄Mo₈O₂₆] (2) (4-NH₂-trz=4-amino-1, 2, 4-triazole) have been designed and synthesized. Their crystal structures have been determined by single crystal X-ray diffraction, FT-IR infrared spectra and powder X-ray diffraction analysis. In 1, bi-dentate 4-NH₂-trz ligands bridge two neighboring Cu^Ⅱ centers forming dinuclear structural units, which are further linked by Mo₈O₂₆^4- ions and arranged into a one-dimensional (1D) hybrid coordination framework. In 2, bidentate 4-NH₂-trz ligands also link neighboring Cu^Ⅰ centers to generate unique 1D[Cu₄(4-NH₂-trz)₄]_n helical chains. Further these infinite right-hand and left-hand helical chains are linked by (β-Mo₈O₂₆)^4- anions to form a 2D hybrid framework. Photocatalytic activities for decomposition of different organic dyes (methylene blue (MB), rhodamine B (RhB) and methyl orange (MO)) have been investigated for 1 and 2, indicating that 1 and 2 are good candidates for the photocatalytic degradation of these organic dyes.
- hydrothermal,
- Cu^Ⅱ,
- Cu^Ⅰ,
- photocatalytic,
- organic dyes
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沈阳化工大学材料科学与工程学院沈阳 110142

Hydrothermal Assembly and Photocatalytic Characterization of Polyoxometalate-Based CuⅡ and CuⅠ Hybrid Coordination Framework with 4-Amino-1, 2, 4-triazole

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通讯作者: 陈斌, bchen63@163.com

Hydrothermal Assembly and Photocatalytic Characterization of Polyoxometalate-Based Cu^Ⅱ and Cu^Ⅰ Hybrid Coordination Framework with 4-Amino-1, 2, 4-triazole