Citation: CHENG Yong, SUN Fei-Fei, FENG Qi-Chun, ZHOU Ying-Hua. Synthesis of CuNPs@Cu(Ⅱ)-AMTD Metal-Organic Gel Composites with High Catalytic Activities[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 551-559. doi: 10.11862/CJIC.2018.059 shu

Synthesis of CuNPs@Cu(Ⅱ)-AMTD Metal-Organic Gel Composites with High Catalytic Activities

1.
Key Laboratory of Functional Molecular Solids, Ministry of Education, Wuhu, Anhui 241000, China
2.
College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China

Corresponding author: CHENG Yong,
Received Date: 15 September 2017
Revised Date: 19 December 2017

Figures(8)

The CuNPs@Cu(Ⅱ)-AMTD metal-organic gel composites was prepared by in situ growth of copper nanoparticles within gel matrix. The resulting material has been characterized by IR, SPR, SEM, TEM, EDX and XPS. It was found that CuNPs@Cu(Ⅱ)-AMTD composites exhibit excellent catalytic activities on the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) and other nitroarenes by NaBH₄ in aqueous solution. The mechanism of the catalytic reaction has also been discussed.
- copper nanoparticle,
- metal-organic gel,
- catalytic,
- nitroarene
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