Citation: TIAN Ju-Mei, ZHANG Jing-Ping. Penta-nuclear Mixed-Valence Co(Ⅱ/Ⅲ) and 1D Chain Cu(Ⅱ) Complexes Incorporating Schiff Base Ligand with End-On Azido Bridging: Syntheses, Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 436-444. doi: 10.11862/CJIC.2018.053 shu

Penta-nuclear Mixed-Valence Co(Ⅱ/Ⅲ) and 1D Chain Cu(Ⅱ) Complexes Incorporating Schiff Base Ligand with End-On Azido Bridging: Syntheses, Structures and Magnetic Properties

TIAN Ju-Mei ^1,, ,
ZHANG Jing-Ping ²

1.
Department of Stomatology, Xiamen Medical College, Xiamen, Fujian 361023, China
2.
Faculty of Chemistry, Northeast Normal University, Changchun 130024, China

Corresponding author: TIAN Ju-Mei, tjm@xmmc.edu.cn
Received Date: 21 August 2017
Revised Date: 30 October 2017

Figures(6)

Two novel complexes, [Co^ⅡCo₄^Ⅲ(salhn)₄(N₃)₆(CH₃OH)₂(H₂O)₂]·4CH₃OH·2H₂O (1) and[Cu₂(salhn)(N₃)₂]_n (2) (H₂salhn=N, N'-bis(salicylidene)hydrazine), were synthesized and structurally characterized by X-ray single-crystal diffraction. Complex 1 is a zigzag-like penta-nuclear[Co^ⅡCo₄^Ⅲ] cobalt cluster, while complex 2 consists of a 1D chain containing subunit[Cu₂(salhn)(N₃)₂]. Both complexes possess bridged azide with the end-on (EO, μ-1, 1) coordination fashion. The magnetic measurements indicate that 1 and 2 both show antiferromagnetic behaviors.
- Schiff base,
- azido group,
- antiferromagnetism,
- crystal structure,
- bridging ligand
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