Citation: LIN Jian-Jun, LIU Zhen, LÜ Ling-Zhi, FENG Yun-Long. Two Lanthanide Metal-Organic-Frameworks Based on a Tetra-carboxylate Ligand for Sensing of Small Organic Molecules[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 230-236. doi: 10.11862/CJIC.2018.037 shu

Two Lanthanide Metal-Organic-Frameworks Based on a Tetra-carboxylate Ligand for Sensing of Small Organic Molecules

Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: FENG Yun-Long, sky37@zjnu.cn
Received Date: 19 June 2017
Revised Date: 13 November 2017

Figures(5)

5, 5'-(1H-1, 2, 4-triazole-1, 4-diyl)diisophthalic acid (H₄L) was used to synthesize two microporous three-dimension metal-organic-frameworks(MOFs) with lanthanide metal salts by intermolecular self-assembly:{[Ho₃L₂(H₂O)₆]OH·2DMF}_n (1), {[Tb₃L₂(H₂O)₆]OH·2DMF}_n (2). Single-crystal X-ray diffraction revealed the Ln-MOFs are isomorphous and belong to monoclinic C2/m space group. Three Ln(Ⅲ) ions are connected through eight carboxylic groups to form a trinuclear[Ln₃(COO)₈] SBU. The SBU polyhedrons share edges with each other generating a 1D inorganic chain, and the chains are further connected by the L^4- ligands to construct a 3D framework. The luminescence intensity of 2 can be modulated by organic small molecules, and 2 exhibited the significant quenching in nitrobenzene, which indicates that 2 is potential luminescent sensing material for nitro explosives.
- 5, 5'-(1H-1, 2, 4-triazole-1, 4-diyl)diisophthalic acid,
- rare-earth metal,
- metal-organic framework,
- crystal structure,
- luminescent property
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