Citation: GU Chang-Sheng, HAO Xiao-Min, HOU Huan-Yao, CHEN Yi-Wen, LI Zhi-Ling, LI Yong, SONG Wen-Dong. Syntheses and Crystal Structures of Three Mg(Ⅱ), Ca(Ⅱ) and Cd(Ⅱ) Complexes with 2, 4-Dichlorophenylacetic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2278-2286. doi: 10.11862/CJIC.2017.279 shu

Syntheses and Crystal Structures of Three Mg(Ⅱ), Ca(Ⅱ) and Cd(Ⅱ) Complexes with 2, 4-Dichlorophenylacetic Acid Ligand

1.
Department of Applied Chemistry, School of Chemistry and Environment, Guangdong Ocean University, Zhanjiang, Guangdong 524088, China
2.
School of Petrochemical and Energetic Engineering, Zhejiang Ocean University, Zhoushan, Zhejiang 316022, China

Corresponding author: HAO Xiao-Min, hxmin2005@126.com SONG Wen-Dong, swd60@163.com
Received Date: 21 April 2017
Revised Date: 30 October 2017

Figures(11)

Three new coordination complexes[Mg(DCBA)₂(H₂O)₄]·3(4, 4'-bipy) (1), [Ca(DCBA)(H₂O)₄]·DCBA·H₂O (2) and[Cd(DCBA)₂(H₂O)₂]·2H₂O (3) were synthesized by evaporation methods using 2, 4-dichlorophenylacetic acid (DCBA), 4, 4'-bipyridine (4, 4'-bipy) to react with MgSO₄, CaCl₂ and Cd(NO₃)₂, respectively. The complexes were characterized by elemental analysis, FT-IR, thermogravimetrie analysis (TGA) and X-ray single-crystal structure analysis, and fluorescence properties of the complex 3 have been studied. As a result, complexes 1, 2 and 3 are zero-dimensional structure. Among others, there are O-H…O, O-H…N, C-H…O, C-H…Cl, C-H…π and O-H…O, C-H…Cl hydrogen bonds contributing 3D supramolecular structure of 1 and 2, 3, respectively.
- complex,
- 2, 4-dichlorophenylacetic acid,
- crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142