Citation: Yuan YUAN, YI Jian-Jun, SHI Yu-Jian, XU Qing-Hong. Spherical α-Ti(HPO₄)₂ Supported Catalysts:Synthesis and Catalytic Properties in Olefin Polymerizations[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2329-2337. doi: 10.11862/CJIC.2017.274 shu

Spherical α-Ti(HPO₄)₂ Supported Catalysts:Synthesis and Catalytic Properties in Olefin Polymerizations

1.
State Key Laboratory of Chemical Resource Engineering, College of Science, Beijing University of Chemical Technology, Beijing 100029, China
2.
Petrochemical Research Institute, PetroChina Company Limited, Beijing 102206, China

Corresponding author: XU Qing-Hong, xuqh@mail.buct.edu.cn
Received Date: 21 July 2017
Revised Date: 6 September 2017

Figures(9)

Two metallocene catalysts and one late transition metal catalyst were immobilized respectively on the surface of spherical α-Ti(HPO₄)₂ treated with methylaluminoxane. All the supported catalysts have higher activities than those of their referenced silica supported catalysts in olefin polymerizations. The activities of α-Ti(HPO₄)₂ supported metallocene catalysts in ethylene and propylene polymerizations are up to 6.8×10⁷ g_PE·(mol_Zr·h)^-1 and 5.0×10⁷ g_PP·(mol_Zr·h)^-1. These supported catalysts can produce narrow molecular weight distribution polyolefins (M_w/M_n < 2.3) and polypropylene with high isotactic index (96.5%). The late transition metal catalyst supported on α-Ti(HPO₄)₂ has relatively less activity (8.3×10⁶ g_PE·(mol_Fe·h)^-1) in ethylene polymerization but the produced polyethylene has a very broad M_w/M_n (>19). The particles of the produced polyolefins are mainly ball-shaped which replicate the morphology of spherical α-Ti(HPO₄)₂.
- α-Ti(HPO₄)₂,
- spherical,
- metallocene,
- late transition metal catalyst,
- olefin polymerization
1. [1]
  Ziegler K, Holzkamp E, Breil H, et al. Angew. Chem., 1955, 67:541-547 doi: 10.1002/(ISSN)1521-3757
2. [2]
  Natta G. Makromol. Chem., 1955, 16:213-237 doi: 10.1002/macp.1955.020160124
3. [3]
  Busico V. Adv. Polym. Sci., 2013, 257:37-57
4. [4]
  McDaniel M P. Adv. Catal., 2010, 53:123-606
5. [5]
  Sedov I V, Makhaev V D, Matkovskii P E. Catal. Ind., 2012, 4:129-140 doi: 10.1134/S2070050412020109
6. [6]
  Johnson L K, Killian C M, Brookhart M. J. Am. Chem. Soc., 1995, 117:6414-6415 doi: 10.1021/ja00128a054
7. [7]
  Camacho D H, Salo E V, Ziller J W, et al. Angew. Chem. Int. Ed., 2004, 43:1821-1825 doi: 10.1002/(ISSN)1521-3773
8. [8]
  Britovsek G J P, Gibson V C, Kimberley B S, et al. Chem. Commun., 1998:849-850
9. [9]
  Small B L, Brookhart M, Bennett A M A. J. Am. Chem. Soc., 1998, 120:4049-4050 doi: 10.1021/ja9802100
10. [10]
  Matsui S, Tohi Y, Mitani M, et al. Chem. Lett., 1999, 28:1065-1066 doi: 10.1246/cl.1999.1065
11. [11]
  Furuyama R, Saito J, Ishii S, et al. J. Organomet. Chem., 2005, 690:4398-4413 doi: 10.1016/j.jorganchem.2005.03.060
12. [12]
  Yoshida Y, Matsui S, Takagi Y, et al. Organometallics, 2001, 20:4793-4799 doi: 10.1021/om010468q
13. [13]
  Yoshida Y, Matsui S, Fujita T. J. Organomet. Chem., 2005, 690:4382-4397 doi: 10.1016/j.jorganchem.2005.01.038
14. [14]
  Guan Z B, Cotts P M, McCord E F, et al. Science, 1999, 283:2059-2062 doi: 10.1126/science.283.5410.2059
15. [15]
  Guan Z B. Chem. Eur. J., 2002, 8:3086-3092 doi: 10.1002/1521-3765(20020715)8:14<3086::AID-CHEM3086>3.0.CO;2-L
16. [16]
  Terao H, Ishii S, Mitani M, et al. J. Am. Chem. Soc., 2008, 130:17636-17637 doi: 10.1021/ja8060479
17. [17]
  Mitani M, Nakano T, Fujita T. Chem. Eur. J., 2003, 9:2396-2403 doi: 10.1002/chem.200304661
18. [18]
  Eagan J M, Xu J, Di Girolamo R, et al. Science, 2017, 355:814-816 doi: 10.1126/science.aah5744
19. [19]
  Arriola D J, Carnahan E M, Hustad P D, et al. Science, 2006, 312:714-719 doi: 10.1126/science.1125268
20. [20]
  Wang H P, Chum S P, Hiltner A, et al. J. Appl. Polym. Sci., 2009, 113:3236-3244 doi: 10.1002/app.v113:5
21. [21]
  Zhang J, Wang X, Jin G X. Coord. Chem. Rev., 2006, 250:95-109 doi: 10.1016/j.ccr.2005.06.002
22. [22]
  Gibson V C, Spitzmesser S K. Chem. Rev., 2003, 103:283-316 doi: 10.1021/cr980461r
23. [23]
  Alt H G, Kppl A. Chem. Rev., 2000, 100:1205-1222 doi: 10.1021/cr9804700
24. [24]
  Gibson V C, Redshaw C, Solan G A. Chem. Rev., 2007, 107:1745-1776 doi: 10.1021/cr068437y
25. [25]
  Dos Ouros A C, De Souzab M O, Pastore H O. J. Braz. Chem. Soc., 2014, 25:2164-2185
26. [26]
  Severn J R, Chadwick J C, Duchateau R, et al. Chem. Rev., 2005, 105:4073-4147 doi: 10.1021/cr040670d
27. [27]
  Fink G, Steinmetz B, Zechlin J, et al. Chem. Rev., 2000, 100(4):1377-1390 doi: 10.1021/cr9804689
28. [28]
  Ma Z, Sun W H, Zhu N, et al. Polym. Int., 2002, 51:349-352 doi: 10.1002/(ISSN)1097-0126
29. [29]
  Conte A, Marques M F V. Eur. Polym. J., 2001, 37:1887-1893 doi: 10.1016/S0014-3057(01)00071-4
30. [30]
  Xu R W, Liu D B, Wang S B, et al. Macromol. Chem. Phys., 2006, 207:779-786 doi: 10.1002/(ISSN)1521-3935
31. [31]
  Saga K, Uozumi T, Saitoa M, et al. Macromol. Chem. Phys., 1994, 195:1503-1515 doi: 10.1002/macp.1994.021950505
32. [32]
  Kageyama K, Ng S M, Ichikawa H, et al. Macromol. Symp., 2000, 157:137-142 doi: 10.1002/(ISSN)1521-3900
33. [33]
  Guo C, Jin G X, Wang F S. J. Polym. Sci. Part A:Polym. Chem., 2004, 42:4830-4837 doi: 10.1002/(ISSN)1099-0518
34. [34]
  Weiss K, Wirth-Pfeifer C, Hofmanna M, et al. J. Mol. Catal. A:Chem., 2002, 182-183:143-149
35. [35]
  Choi Y Y, Shin S Y A, Soares J B P. Macromol. Chem. Phys., 2010, 211:1026-1034 doi: 10.1002/macp.200900643
36. [36]
  Buffet J C, Wanna N, Arnold T A Q, et al. Chem. Mater., 2015, 27:1495-1501 doi: 10.1021/cm503433q
37. [37]
  Nishida H, Uozumi T, Arai T, et al. Macromol. Rapid Commun., 1995, 16:821-830 doi: 10.1002/marc.1995.030161107
38. [38]
  Naundorf C, Matusi S, Saito J, et al. J. Polym. Sci., Part A:Polym. Chem., 2006, 44:3103-3113 doi: 10.1002/(ISSN)1099-0518
39. [39]
  Soga K, Ban H T, Arai T, et al. Macromol. Chem. Phys., 1997, 198:2779-2787 doi: 10.1002/macp.1997.021980910
40. [40]
  Belelli P G, Ferreira M L, Damiani D E. Macromol. Chem. Phys., 2000, 201:1458-1465 doi: 10.1002/(ISSN)1521-3935
41. [41]
  Belelli P G, Ferreira M L, Damiani D E. Macromol. Chem. Phys., 2000, 201:1466-1475 doi: 10.1002/(ISSN)1521-3935
42. [42]
  Shi Y S, Yuan Y, Xu Q H, et al. Appl. Surf. Sci., 2016, 383:126-132 doi: 10.1016/j.apsusc.2016.04.123
43. [43]
  Morrow D R, Richardson G C, Kleinman L, et al. J. Polym. Sci. Part B:Polym. Phys., 1967, 5:493-494
44. [44]
  Muñoz-Escalona A, Hernandez J G, Gallardo J A. J. Appl. Polym. Sci., 1984, 29:1187-1202 doi: 10.1002/app.1984.070290415
45. [45]
  Small B L, Brookhart M, Bennett A M A. J. Am. Chem. Soc., 1998, 120:4049-4050 doi: 10.1021/ja9802100
46. [46]
  Slade R C T, Knowles J A, Jones D J, et al. Solid State Ionics, 1997, 96:9-19 doi: 10.1016/S0167-2738(97)00012-X
47. [47]
  Ortíz-Oliveros H B, Flores-Espinosa R M, Ordoez-Regil E, et al. Chem. Eng. J., 2014, 236:398-405 doi: 10.1016/j.cej.2013.09.103
48. [48]
  Kaminsky W. Pure Appl. Chem., 1998, 70:1229-1235
49. [49]
  Nicholas C P, Hongsang A H S, Marks T J. J. Am. Chem. Soc., 2003, 125:4325-4331 doi: 10.1021/ja0212213
1. [1]
  Min LUO , Xiaonan WANG , Yaqin ZHANG , Tian PANG , Fuzhi LI , Pu SHI . Porous spherical MnCo₂S₄ as high-performance electrode material for hybrid supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 413-424. doi: 10.11862/CJIC.20240205
2. [2]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
3. [3]
  Linping Li , Junhui Su , Yanping Qiu , Yangqin Gao , Ning Li , Lei Ge . Design and fabrication of ternary Au/Co3O4/ZnCdS spherical composite photocatalyst for facilitating efficient photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100472-100472. doi: 10.1016/j.cjsc.2024.100472
4. [4]
  Yu-Yao Li , Xiao-Hui Li , Zhi-Xuan An , Yang Chu , Xiu-Li Wang . Room-temperature olefin epoxidation reaction by two 2D cobalt metal-organic complexes under O₂ atmosphere: Coordination and structural regulation. Chinese Chemical Letters, 2025, 36(4): 109716-. doi: 10.1016/j.cclet.2024.109716
5. [5]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
6. [6]
  Yiwen Xu , Chaozheng He , Chenxu Zhao , Ling Fu . Single-atom Ti doping on S-vacancy two-dimensional CrS₂ as a catalyst for ammonia synthesis: A DFT study. Chinese Chemical Letters, 2025, 36(4): 109797-. doi: 10.1016/j.cclet.2024.109797
7. [7]
  Fei Yin , Erli Yang , Xue Ge , Qian Sun , Fan Mo , Guoqiu Wu , Yanfei Shen . Coupling WO₃₋_x dots-encapsulated metal-organic frameworks and template-free branched polymerization for dual signal-amplified electrochemiluminescence biosensing. Chinese Chemical Letters, 2024, 35(4): 108753-. doi: 10.1016/j.cclet.2023.108753
8. [8]
  Hailong He , Wenbing Wang , Wenmin Pang , Chen Zou , Dan Peng . Double stimulus-responsive palladium catalysts for ethylene polymerization and copolymerization. Chinese Chemical Letters, 2024, 35(7): 109534-. doi: 10.1016/j.cclet.2024.109534
9. [9]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
10. [10]
  Xinyu You , Xin Zhang , Shican Jiang , Yiru Ye , Lin Gu , Hexun Zhou , Pandong Ma , Jamal Ftouni , Abhishek Dutta Chowdhury . Efficacy of Ca/ZSM-5 zeolites derived from precipitated calcium carbonate in the methanol-to-olefin process. Chinese Journal of Structural Chemistry, 2024, 43(4): 100265-100265. doi: 10.1016/j.cjsc.2024.100265
11. [11]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
12. [12]
  Bing Niu , Honggao Huang , Liwei Luo , Li Zhang , Jianbo Tan . Coating colloidal particles with a well-defined polymer layer by surface-initiated photoinduced polymerization-induced self-assembly and the subsequent seeded polymerization. Chinese Chemical Letters, 2025, 36(2): 110431-. doi: 10.1016/j.cclet.2024.110431
13. [13]
  Shuo Li , Xinran Liu , Yongjie Zheng , Jun Ma , Shijie You , Heshan Zheng . Effective peroxydisulfate activation by CQDs-MnFe₂O₄@ZIF-8 catalyst for complementary degradation of bisphenol A by free radicals and non-radical pathways. Chinese Chemical Letters, 2024, 35(5): 108971-. doi: 10.1016/j.cclet.2023.108971
14. [14]
  Boqiang Wang , Yongzhuo Xu , Jiajia Wang , Muyang Yang , Guo-Jun Deng , Wen Shao . Transition-metal free trifluoromethylimination of alkenes enabled by direct activation of N-unprotected ketimines. Chinese Chemical Letters, 2024, 35(9): 109502-. doi: 10.1016/j.cclet.2024.109502
15. [15]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
16. [16]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
17. [17]
  Ying-Yu Zhang , Jia-Qi Luo , Yan Han , Wan-Ying Zhang , Yi Zhang , Hai-Feng Lu , Da-Wei Fu . Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature. Chinese Chemical Letters, 2025, 36(1): 109530-. doi: 10.1016/j.cclet.2024.109530
18. [18]
  Kexin Yin , Jingren Yang , Yanwei Li , Qian Li , Xing Xu . Metal-free diatomaceous carbon-based catalyst for ultrafast and anti-interference Fenton-like oxidation. Chinese Chemical Letters, 2024, 35(12): 109847-. doi: 10.1016/j.cclet.2024.109847
19. [19]
  Pengfei Zhang , Qingxue Ma , Zhiwei Jiang , Xiaohua Xu , Zhong Jin . Transition-metal-catalyzed remote meta-C—H alkylation and alkynylation of aryl sulfonic acids enabled by an indolyl template. Chinese Chemical Letters, 2024, 35(8): 109361-. doi: 10.1016/j.cclet.2023.109361
20. [20]
  Xue Zhao , Mengshan Chen , Dan Wang , Haoran Zhang , Guangzhi Hu , Yingtang Zhou . Ultrafine nano-copper derived from dopamine polymerization & synchronous adsorption achieve electrochemical purification of nitrate to ammonia in complex water environments. Chinese Chemical Letters, 2024, 35(8): 109327-. doi: 10.1016/j.cclet.2023.109327

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1280)
HTML views(44)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Spherical α-Ti(HPO4)2 Supported Catalysts:Synthesis and Catalytic Properties in Olefin Polymerizations

Metrics

通讯作者: 陈斌, bchen63@163.com

Spherical α-Ti(HPO₄)₂ Supported Catalysts:Synthesis and Catalytic Properties in Olefin Polymerizations