Citation: NI Tian-Jun, YUAN Qiang-Tao, ZHANG Wei, YANG Zhi-Jun, YU Hai-Hong, CAI Hong-Rui. Influence of Solvents on the Formation of Silver(Ⅰ) Complexes with the Flexible 1, 3, 5-Tris(triazol-1-ylmethyl)-2, 4, 6-trimethylbenzene[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2177-2185. doi: 10.11862/CJIC.2017.269 shu

Influence of Solvents on the Formation of Silver(Ⅰ) Complexes with the Flexible 1, 3, 5-Tris(triazol-1-ylmethyl)-2, 4, 6-trimethylbenzene

1.
School of Basic Medicine, Xinxiang Medical University, Xinxiang, Henan 453003, China
2.
College of Pharmacy, Xinxiang Medical University, Xinxiang, Henan 453003, China

Corresponding author: YANG Zhi-Jun, zjyang@xxmu.edu.cn
Received Date: 17 April 2017
Revised Date: 19 September 2017

Figures(10)

Two novel silver complexes {[Ag(ttmb)(H₂O)]NO₃}_n (1) and {[Ag(ttmb)]NO₃·H₂O}_n (2) were synthesized by the reaction of AgNO₃ with 1, 3, 5-tri(1, 2, 4-triazol-1-ylmethyl)-2, 4, 6-trimethylbenzene (ttmb) in different solvents. The solid-state fluorescent properties of these two complexes and related ligand ttmb were then investigated at room temperature. Structural characterizations by elemental analysis, powder and single-crystal X-ray diffraction analysis and infrared spectra shows that complex 1 contains a highly undulated 2D network while complex 1 carries a 2D (6, 3) network.
- crystal structure,
- sliver complex,
- triazole ligand,
- coordination polymers
1. [1]
  Li Q, Xu P, Gao W, et al. Adv. Mater., 2014, 26:1378-1386 doi: 10.1002/adma.201304218
2. [2]
  Chen L, Chen Q, Wu M, et al. Acc. Chem. Res., 2015, 48:201-210 doi: 10.1021/ar5003076
3. [3]
  LIANG Rui, WANG Yu-Ting, GUO Yong-Kang, et al. Chinese J. Inorg. Chem., 2017, 33(8):1465-1473 doi: 10.11862/CJIC.2017.154
4. [4]
  Zhang M D, Zheng B H, Chen L, et al. Dalton Trans., 2016, 45:3334-3339 doi: 10.1039/C5DT04462F
5. [5]
  Park I H, Medishetty R, Kim J Y, et al. Angew. Chem. Int. Ed., 2014, 53:5591-5595 doi: 10.1002/anie.v53.22
6. [6]
  Huang X F, Ma J X, Liu W S. Inorg. Chem., 2014, 53:5922-5930 doi: 10.1021/ic403080n
7. [7]
  Zhang L, Yang W, Wu X Y, et al. Chemistry, 2016, 22:11283-11290 doi: 10.1002/chem.201600705
8. [8]
  Shen X, Yan B. J. Colloid Interface Sci., 2016, 468:220-226 doi: 10.1016/j.jcis.2016.01.055
9. [9]
  Bai L, Wang P, Bose P, et al. ACS Appl. Mater. Interfaces, 2015, 7:5056-60 doi: 10.1021/am5089549
10. [10]
  Wang Y, Tan C, Sun Z, et al. Chemistry, 2014, 20:1341-1348 doi: 10.1002/chem.v20.5
11. [11]
  Han M L, Duan Y P, Li D S, et al. Dalton Trans., 2014, 43:15450-15456 doi: 10.1039/C4DT01086H
12. [12]
  Weisser F, Hohloch S, Plebst S, et al. Chemistry, 2014, 20:781-793 doi: 10.1002/chem.v20.3
13. [13]
  Szorcsik A, Matyuska F, Benyei A, et al. Dalton Trans., 2016, 45:14998-15012 doi: 10.1039/C6DT01228K
14. [14]
  Stewart C D, Pedraza M, Arman H, et al. J. Inorg. Biochem., 2015, 149:25-38 doi: 10.1016/j.jinorgbio.2015.04.012
15. [15]
  Brown J L, Jones M B, Gaunt A J, et al. Inorg. Chem., 2015, 54:4064-75 doi: 10.1021/acs.inorgchem.5b00299
16. [16]
  Haldon E, Delgado-Rebollo M, Prieto A, et al. Inorg. Chem., 2014, 53:4192-4201 doi: 10.1021/ic500311y
17. [17]
  Martinez-Alanis P R, Sanchez Eguia B N, Ugalde-Saldivar V M, et al. Chemistry, 2013, 19:6067-6079 doi: 10.1002/chem.201203498
18. [18]
  Arcis-Castillo Z, Munoz M C, Molnar G, et al. Chemistry, 2013, 19:6851-6861 doi: 10.1002/chem.v19.21
19. [19]
  Li M X, Miao Z X, Shao M, et al. Inorg. Chem., 2008, 47:4481-4489 doi: 10.1021/ic701346x
20. [20]
  Zhang L, Kuang X, Wu X, et al. Dalton Trans., 2014, 43:7146-7152 doi: 10.1039/c3dt53580k
21. [21]
  Kim H M, Cho B R. J. Mater. Chem., 2009, 19:7402-7409 doi: 10.1039/b906361g
22. [22]
  Chepelin O, Ujma J, Wu X, et al. J. Am. Chem. Soc., 2012, 134:19334-19337 doi: 10.1021/ja309031h
23. [23]
  Fu H R, Wang F, Zhang J. Dalton Trans., 2014, 43:4668-4673 doi: 10.1039/c3dt52940a
24. [24]
  Herm Z R, Swisher J A, Smit B, et al. J. Am. Chem. Soc., 2011, 133:5664-5667 doi: 10.1021/ja111411q
25. [25]
  Zhang M, Chen Y P, Bosch M, et al. Angew. Chem. Int. Ed., 2014, 53:815-818 doi: 10.1002/anie.201307340
26. [26]
  Lin Z J, Lu J, Hong M, et al. Chem. Soc. Rev., 2014, 43:5867-5895 doi: 10.1039/C3CS60483G
27. [27]
  Wang Y T, Li S T, Wu S Q, et al. J. Am. Chem. Soc., 2013, 135:5942-5945 doi: 10.1021/ja312622c
28. [28]
  Ni T, Xing F, Shao M, et al. Cryst. Growth Des., 2011, 11:2999-3012 doi: 10.1021/cg2002749
29. [29]
  Ni T, Zhao Y, Shao M, et al. Z. Anorg. Allg. Chem., 2011, 637:689-697 doi: 10.1002/zaac.201000433
30. [30]
  Stephenson A, Argent S P, Riis-Johannessen T, et al. J. Am. Chem. Soc., 2011, 133:858-870 doi: 10.1021/ja107403p
31. [31]
  Blessing R H. Acta Crystallogr. Sect. A:Found. Crystallogr., 1995, A51:33-38
32. [32]
  Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structure, University of Göttingen, Germany, 1997.
33. [33]
  Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
34. [34]
  Connell T U, Schieber C, Silvestri I P, et al. Inorg. Chem., 2014, 53:6503-6511 doi: 10.1021/ic5008999
35. [35]
  Guo X G, Yang W B, Wu X Y, et al. Dalton Trans., 2013, 42:15106-15112 doi: 10.1039/c3dt51574e
36. [36]
  Dutta S, Bucar D K, Elacqua E, et al. Chem. Commun., 2013, 49:1064-1066 doi: 10.1039/C2CC36458A
37. [37]
  Saha D, Maity T, Das S, et al. Dalton Trans., 2013, 42:13912-13922 doi: 10.1039/c3dt51509e
38. [38]
  Yao L, Zhang S, Wang R, et al. Angew. Chem. Int. Ed., 2014, 53:2119-2123 doi: 10.1002/anie.201308486
39. [39]
  Luo Y H, Wang Y, Zhao J, et al. Spectrochim. Acta, Part A, 2014, 122:246-251 doi: 10.1016/j.saa.2013.11.090
40. [40]
  CHEN Man-Sheng, HUANG Xiu-Yu, CHEN Xiao-Li, et al. Chinese J. Inorg. Chem., 2017, 33(6):1090-1096 doi: 10.11862/CJIC.2017.128
1. [1]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
2. [2]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
3. [3]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
4. [4]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
5. [5]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
6. [6]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
7. [7]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
8. [8]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
9. [9]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
10. [10]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
11. [11]
  Shuwen SUN , Gaofeng WANG . Design and synthesis of a Zn(Ⅱ)-based coordination polymer as a fluorescent probe for trace monitoring 2, 4, 6-trinitrophenol. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 753-760. doi: 10.11862/CJIC.20240399
12. [12]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
13. [13]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
14. [14]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
15. [15]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
16. [16]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
17. [17]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
18. [18]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
19. [19]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
20. [20]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1046)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142