Citation: NI Tian-Jun, YUAN Qiang-Tao, ZHANG Wei, YANG Zhi-Jun, YU Hai-Hong, CAI Hong-Rui. Influence of Solvents on the Formation of Silver(Ⅰ) Complexes with the Flexible 1, 3, 5-Tris(triazol-1-ylmethyl)-2, 4, 6-trimethylbenzene[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2177-2185. doi: 10.11862/CJIC.2017.269 shu

Influence of Solvents on the Formation of Silver(Ⅰ) Complexes with the Flexible 1, 3, 5-Tris(triazol-1-ylmethyl)-2, 4, 6-trimethylbenzene

1.
School of Basic Medicine, Xinxiang Medical University, Xinxiang, Henan 453003, China
2.
College of Pharmacy, Xinxiang Medical University, Xinxiang, Henan 453003, China

Corresponding author: YANG Zhi-Jun, zjyang@xxmu.edu.cn
Received Date: 17 April 2017
Revised Date: 19 September 2017

Figures(10)

Two novel silver complexes {[Ag(ttmb)(H₂O)]NO₃}_n (1) and {[Ag(ttmb)]NO₃·H₂O}_n (2) were synthesized by the reaction of AgNO₃ with 1, 3, 5-tri(1, 2, 4-triazol-1-ylmethyl)-2, 4, 6-trimethylbenzene (ttmb) in different solvents. The solid-state fluorescent properties of these two complexes and related ligand ttmb were then investigated at room temperature. Structural characterizations by elemental analysis, powder and single-crystal X-ray diffraction analysis and infrared spectra shows that complex 1 contains a highly undulated 2D network while complex 1 carries a 2D (6, 3) network.
- crystal structure,
- sliver complex,
- triazole ligand,
- coordination polymers
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1.
沈阳化工大学材料科学与工程学院沈阳 110142