Citation: SONG Heng-Xu, NIU Yong-Qiang, HOU Hua, WU Zhu, ZHAO Yu-Hong. Development and Prospect of Oxide Cathode Materials for High Temperature Lithium Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2155-2168. doi: 10.11862/CJIC.2017.263 shu

Development and Prospect of Oxide Cathode Materials for High Temperature Lithium Batteries

1.
Laboratory of Materials for High Temperature Lithium Batteries, School of Materials Science and Engineering, North University of China, Taiyuan 030051, China
2.
Energy Science and Technology Laboratory, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China

Corresponding author: ZHAO Yu-Hong, zhaoyuhong@nuc.edu.cn
Received Date: 24 July 2017
Revised Date: 10 September 2017

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High temperature lithium battery is the development of low temperature applications of thermal batteries, and has large potential development and utilization in the oil/gas and geothermal field. Compared with the lithium alloy anode materials with large specific capacity and close to the pure lithium electrode potential, the cathode materials are pivotal section of high temperature lithium battery and have large potential space. In the cathode materials, the oxide materials exhibit high voltage characteristics and high thermal stability, and the high-temperature lithium battery can be miniaturized to meet the current voltage supply under the specific conditions. However, there is no systematic overview about the oxide of high-temperature lithium battery currently. In order to make more development in this field and promote the optimal adjustment of energy structure, this paper introduces and summarizes the transition metal oxides used in high-temperature lithium battery, including physical properties, electrochemical properties and synthesis or preparation methods. We describe the excellent properties of various oxide materials in detail, and point out the shortcomings and the existing problems of the material. Moreover, this paper predicts the development of oxide cathode materials, and demonstrates the future direction of development and the work to be done. We hope that this work can provide some reference for the relevant researchers.
- high-temperature lithium battery,
- cathode material,
- oxide,
- electrochemical performance,
- preparation
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