Citation: YANG Yong-Sheng, CHEN Bo-Yong, JU Hai-Yan, ZUO Fen, WANG Shi-Wei, LI Yu-Guang, YAN Shi-Ping. Two Binuclear Copper(Ⅱ) Complexes Containing 1, 4, 7-Trisbenzyl-1, 4, 7-triazacyclononane (Bn₃tacn) Ligand:Syntheses, Characterization and Binding with DNA[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2338-2344. doi: 10.11862/CJIC.2017.262 shu

Two Binuclear Copper(Ⅱ) Complexes Containing 1, 4, 7-Trisbenzyl-1, 4, 7-triazacyclononane (Bn₃tacn) Ligand:Syntheses, Characterization and Binding with DNA

1.
Hubei Key Laboratory of Biomass Fiber and Ecological Dyeing and Finishing, School of Chemistry and Engineering, Wuhan Textile University, Wuhan 430073, China
2.
School of Chemical Engineering, Changchun University of Technology, Changchun 130012, China
3.
Department of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: YANG Yong-Sheng, ysyang@wtu.edu.cn WANG Shi-Wei, wswjldx2004@163.com
Received Date: 21 November 2016
Revised Date: 15 October 2017

Figures(5)

Two binuclear copper(Ⅱ) complexes were prepared with ligand 1, 4, 7-tribenzyl-1, 4, 7-triazacyclononane (Bn₃tacn):[Cu₂(Bn₃tacn)₂(m-bdc)(CH₃CN)₃(H₂O)₂]ClO₄ (1) and[Cu₂(Bn₃tacn)₂(OH)₂](ClO₄)₂ (2). The copper(Ⅱ) ion in complex 1 is bridged by the m-benedicarboxylic acid (m-bdc) adopting bis(bidentate/monodentate) coordination type and is bridged by the μ-OH in complex 2. Complexes 1 and 2 crystalize in the monoclinic system, space group P2₁/c and C2/c, respectively. IR, UV-Vis, element analysis, binding with DNA properties of the complex 1 and cyclic voltammogram of complex 2 have been studied.
- binuclear copper(Ⅱ),
- 1, 4, 7-triazacyclonoane,
- binding with DNA
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沈阳化工大学材料科学与工程学院沈阳 110142

Two Binuclear Copper(Ⅱ) Complexes Containing 1, 4, 7-Trisbenzyl-1, 4, 7-triazacyclononane (Bn3tacn) Ligand:Syntheses, Characterization and Binding with DNA

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通讯作者: 陈斌, bchen63@163.com

Two Binuclear Copper(Ⅱ) Complexes Containing 1, 4, 7-Trisbenzyl-1, 4, 7-triazacyclononane (Bn₃tacn) Ligand:Syntheses, Characterization and Binding with DNA