Citation: YU Qin, WANG Da-Peng, MA Jian-Ping, YU Fei, CAO Zi-Heng, HU Tian-Hao, WANG Peng, WANG Hai-Ying. Syntheses and Crystal Structures of Co(Ⅱ) and Cu(Ⅱ) Complexes Based on 3, 5-Bis(3-pyridyl)-4-amino-1, 2, 4-triazole Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2345-2350. doi: 10.11862/CJIC.2017.261 shu

Syntheses and Crystal Structures of Co(Ⅱ) and Cu(Ⅱ) Complexes Based on 3, 5-Bis(3-pyridyl)-4-amino-1, 2, 4-triazole Ligand

YU Qin ¹ ,
WANG Da-Peng ¹ ,
MA Jian-Ping ² ,
YU Fei ¹ ,
CAO Zi-Heng ¹ ,
HU Tian-Hao ¹ ,
WANG Peng ³ ,
WANG Hai-Ying ^1,,

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing 210023, China
2.
School of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China
3.
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China

Corresponding author: WANG Hai-Ying, haiyingqd@163.com
Received Date: 16 August 2017
Revised Date: 12 October 2017

Figures(7)

Two new metal complexes of {[CoL(H₂O)₄]SO₄·H₂O}_n (1) and [Cu(hfac)₂L₂] (2, hfac=hexafluoroa-cetylacetonate) based on 3, 5-bis(3-pyridyl)-4-amino-1, 2, 4-triazole (L) have been synthesized and characterized by infrared spectrum (IR), elemental analysis (EA), and X-ray single crystal diffraction. For 1, ligand L adopts a cis-conformation and acts as a bidentate spacer to bind Co(Ⅱ) centers to form a one-dimensional (1D) sinusoidal chain. These sinusoidal chains are linked with each other and give a three-dimensional (3D) framework through O-H…O and O-H…N hydrogen bonds of neighboring chains. H₂O guest molecules and SO₄^2- anions are bound on the framework through hydrogen bonding system. For 2, while the ligand L also adopts a cis-conformaation, it acts as a monodentate spacer to bind Cu(Ⅱ) centers to form a discrete mononuclear complex, which is also linked into a three-dimensional (3D) framework through hydrogen bonds.
- triazole,
- complex,
- hydrogen bond,
- crystal structure
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