Citation: ZHANG Qing-Rui, DENG Rui-Ping, LIU Ying-Bo, ZHOU Liang, ZHANG Hong-Jie. Near Infrared Luminescence Properties of the Complexes of Er_xYb_1-x(TPB)₃Bath (x=0, 0.218, 0.799, 0.896, 0.987, 1)[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2011-2016. doi: 10.11862/CJIC.2017.254 shu

Near Infrared Luminescence Properties of the Complexes of Er_xYb_1-x(TPB)₃Bath (x=0, 0.218, 0.799, 0.896, 0.987, 1)

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: DENG Rui-Ping, dengrp@ciac.ac.cn ZHANG Hong-Jie, hongjie@ciac.ac.cn
Received Date: 18 August 2017
Revised Date: 22 September 2017

Figures(5)

A series of near infrared (NIR) luminescent complexes based on Er_xYb_1-x(TPB)₃Bath (where TPB=4, 4, 4-tri-fluoro-1-phenyl-1, 3-butanedione, Bath=4, 7-diphenyl-1, 10-phenanthroline, x=0, 0.218, 0.799, 0.896, 0.987, 1, respectively) were prepared by selecting TPB and Bath as the first and second ligands, respectively. Luminescence properties of these complexes were investigated in detail. All these complexes exhibit the characteristic emission of the Yb³⁺ and/or Er³⁺ ion in the NIR region, and the emission intensity of Er³⁺ ion can be enhanced by modulating the n_Er/n_Yb, which is related to the energy transfer from Yb³⁺ to Er³⁺ ions.
- rare earth complex,
- near infrared luminescence,
- energy transfer
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Near Infrared Luminescence Properties of the Complexes of ErxYb1-x(TPB)3Bath (x=0, 0.218, 0.799, 0.896, 0.987, 1)

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通讯作者: 陈斌, bchen63@163.com

Near Infrared Luminescence Properties of the Complexes of Er_xYb_1-x(TPB)₃Bath (x=0, 0.218, 0.799, 0.896, 0.987, 1)