Citation: WANG Hui, ZHANG Xiao-Dong, XIE Yi. Recent Progresses on the Photoexcitation Processes of Polymeric Carbon Nitride-Based Materials[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 1897-1913. doi: 10.11862/CJIC.2017.249 shu

Recent Progresses on the Photoexcitation Processes of Polymeric Carbon Nitride-Based Materials

Hefei National Laboratory for Physical Science at Microscale, University of Science and Technology of China, Hefei 230026, China

Corresponding author: ZHANG Xiao-Dong, zhxid@ustc.edu.cn XIE Yi, yxie@ustc.edu.cn
Received Date: 21 August 2017
Revised Date: 19 September 2017

Figures(16)

Recently, the metal-free polymeric carbon nitride has drawn tremendous attention by virtue of its unique material composition and electronic structure, holding great promise in optical excitation related applications, such as photocatalysis, photoluminescence, and photoelectrochemistry. The investigation of photoexcitation processes dominated by energy band structure, charge carrier behaviors and excitonic effects in polymeric carbon nitride are of great significance in understanding mechanisms, optimizing performance and expanding application. Focusing on this topic, we review recent advances in research on the photoexcitation processes of polymeric carbon nitride-based materials, by beginning with a brief introduction of the characterization techniques in these works. We then discuss the charge carrier and exciton aspects in the photoexcitation processes. The principles of universal modification strategies on photoexcitation processes are summarized. Also, the applications of the photoexcitation processes in this polymeric semiconductor are highlighted.
- polymeric carbon nitride,
- photoexcitation,
- charge carrier,
- excitonic effects
1. [1]
  Wang X, Maeda K, Thomas A, et al. Nat. Mater., 2009, 8:76-80 doi: 10.1038/nmat2317
2. [2]
  ZHANG Jin-Shui, WANG Bo, WANG Xin-Chen. Progress in Chemistry, 2014, 26 (1):19-29
3. [3]
  Wang X, Blechert S, Antonietti M. ACS Catal., 2012, 2:1596-1606 doi: 10.1021/cs300240x
4. [4]
  Ong W J, Tan L L, Ng Y H, et al. Chem. Rev., 2016, 116: 7159-7329 doi: 10.1021/acs.chemrev.6b00075
5. [5]
  Zhang J, Chen Y, Wang X. Energy Environ. Sci., 2015, 8: 3092-3108 doi: 10.1039/C5EE01895A
6. [6]
  Cao S, Yu J. J. Phys. Chem. Lett., 2014, 5:2101-2107 doi: 10.1021/jz500546b
7. [7]
  Cao S, Low J, Yu J, et al. Adv. Mater., 2015, 27:2150-2176 doi: 10.1002/adma.201500033
8. [8]
  Liu J, Wang H, Antonietti M. Chem. Soc. Rev., 2016, 45: 2308-2326 doi: 10.1039/C5CS00767D
9. [9]
  Thomas A, Fischer A, Goettmann F, et al. J. Mater. Chem., 2008, 18:4893-4908 doi: 10.1039/b800274f
10. [10]
  Kroke E, Schwarz M, Horath-Bordon E, et al. New J. Chem., 2002, 26:508-512 doi: 10.1039/b111062b
11. [11]
  Sattler A, Pagano S, Zeuner M, et al. Chem.-Eur. J., 2009, 15:13161-13170 doi: 10.1002/chem.v15:47
12. [12]
  Lotsch B V, Schnick W. Chem. Mater., 2006, 18:1891-1900 doi: 10.1021/cm052342f
13. [13]
  Redemann C E, Lucas H J. J. Am. Chem. Soc., 1940, 62: 842-846 doi: 10.1021/ja01861a038
14. [14]
  Ang T P, Chan Y M. J. Phys. Chem. C, 2011, 115:15965-15972 doi: 10.1021/jp200324v
15. [15]
  Wei W, Jacob T. Phys. Rev. B, 2013, 87:085202 doi: 10.1103/PhysRevB.87.085202
16. [16]
  Butchosa C, Guiglion P, Zwijnenburg M A. J. Phys. Chem. C, 2014, 118:24833-24842 doi: 10.1021/jp507372n
17. [17]
  Zhang H, Zuo X, Tang H, et al. Phys. Chem. Chem. Phys., 2015, 17:6280-6288 doi: 10.1039/C4CP05288A
18. [18]
  Dong G, Zhang Y, Pan Q, et al. J. Photochem. Photobiol. C, 2014, 20:33-50 doi: 10.1016/j.jphotochemrev.2014.04.002
19. [19]
  Du A, Sanvito S, Smith S C. Phys. Rev. Lett., 2012, 108: 197207 doi: 10.1103/PhysRevLett.108.197207
20. [20]
  Zhang X D, Xie X, Wang H, et al. J. Am. Chem. Soc., 2013, 135:18-21 doi: 10.1021/ja308249k
21. [21]
  Ma X G, Lü Y H, Xu J, et al. J. Phys. Chem. C, 2012, 116: 23485-23493 doi: 10.1021/jp308334x
22. [22]
  O'Connell M J, Bachilo S M, Huffman C B, et al. Science, 2002, 297:593-596 doi: 10.1126/science.1072631
23. [23]
  Hill H M, Rigosi A F, Roquelet C, et al. Nano Lett., 2015, 15:2992-2997 doi: 10.1021/nl504868p
24. [24]
  Liu K, Zhang L, Cao T, et al. Nat. Commun., 2014, 5:4966 doi: 10.1038/ncomms5966
25. [25]
  Sun L, Chen Z, Ren Q, et al. Phys. Rev. Lett., 2008, 100: 156403 doi: 10.1103/PhysRevLett.100.156403
26. [26]
  Wang H, Jiang S L, Chen S C, et al. Chem. Sci., 2017, 8: 4087-4092 doi: 10.1039/C7SC00307B
27. [27]
  Zhang Q, Zheng H, Geng Z, et al. J. Am. Chem. Soc., 2013, 135:12468-12474 doi: 10.1021/ja407110r
28. [28]
  Bi W, Li X, Zhang L, et al. Nat. Commun., 2015, 6:8647 doi: 10.1038/ncomms9647
29. [29]
  Wu K, Chen J, McBride J R, et al. Science, 2015, 349:632-635 doi: 10.1126/science.aac5443
30. [30]
  Sun X, Wang X, Li X, et al. Macromol. Rapid Commun., 2015, 36:298-303 doi: 10.1002/marc.201400529
31. [31]
  Zhang Q, Luo Y. High Power Laser Sci. Eng., 2016, 4:e22 doi: 10.1017/hpl.2016.23
32. [32]
  Chen Z W, Zhang Q, Luo Y. ChemPhotoChem, 2017, 1:350-354 doi: 10.1002/cptc.v1.8
33. [33]
  Wang H, Jiang S, Chen S, et al. Adv. Mater., 2016, 28:6940-6945 doi: 10.1002/adma.201601413
34. [34]
  Scholes G D, Rumbles G. Nat. Mater., 2006, 5:683-696 doi: 10.1038/nmat1710
35. [35]
  Goushi K, Yoshida K, Sato K, et al. Nat. Photonics, 2012, 6: 253-258 doi: 10.1038/nphoton.2012.31
36. [36]
  Huang M H, Mao S, Feick H, et al. Science, 2001, 292:1897-1899 doi: 10.1126/science.1060367
37. [37]
  Xie Y, Gong M, Shastry T A, et al. Adv. Mater., 2013, 25: 3433-3437 doi: 10.1002/adma.v25.25
38. [38]
  Nozik A J, Beard M C, Luther J M, et al. Chem. Rev., 2010, 110:6873-6890 doi: 10.1021/cr900289f
39. [39]
  Semonin O E, Luther J M, Choi S, et al. Science, 2011, 334: 1530-1533 doi: 10.1126/science.1209845
40. [40]
  Jares-Erijman E A, Jovin T M. Nat. Biotechnol., 2003, 21: 1387-1395 doi: 10.1038/nbt896
41. [41]
  Sekar R B, Periasamy A. J. Cell Biol., 2003, 160:629-633 doi: 10.1083/jcb.200210140
42. [42]
  Cao Y, Parker I D, Yu G, et al. Nature, 1999, 397:414-417 doi: 10.1038/17087
43. [43]
  Congreve D N, Lee J, Thompson N J, et al. Science, 2013, 340:334-337 doi: 10.1126/science.1232994
44. [44]
  Lee J, Jadhav P, Reusswig P D, et al. Acc. Chem. Res., 2013, 46:1300-1311 doi: 10.1021/ar300288e
45. [45]
  Wang X, Chen X, Thomas A, et al. Adv. Mater., 2009, 21: 1609-1612 doi: 10.1002/adma.v21:16
46. [46]
  Gao L F, Wen T, Xu J Y, et al. ACS Appl. Mater. Interfaces, 2016, 8:617-624 doi: 10.1021/acsami.5b09684
47. [47]
  Yue B, Li Q, Iwai H, et al. Sci. Technol. Adv. Mater., 2011, 12:034401 doi: 10.1088/1468-6996/12/3/034401
48. [48]
  Ding G, Wang W, Jiang T, et al. ChemCatChem, 2013, 5: 192-200 doi: 10.1002/cctc.201200502
49. [49]
  Wang Y, Wang Y, Chen Y, et al. Mater. Lett., 2015, 139:70-72 doi: 10.1016/j.matlet.2014.10.008
50. [50]
  Li X, Bi W, Zhang L, et al. Adv. Mater., 2016, 28:2427-2431 doi: 10.1002/adma.201505281
51. [51]
  Fang J, Fan H, Li M, et al. J. Mater. Chem. A, 2015, 3:13819-13826 doi: 10.1039/C5TA02257F
52. [52]
  Zhang G, Zhang M, Ye X, et al. Adv. Mater., 2014, 26:805-809 doi: 10.1002/adma.201303611
53. [53]
  Wang Y, Li H, Yao J, et al. Chem. Sci., 2011, 2:446-450 doi: 10.1039/C0SC00475H
54. [54]
  Wang Y, Di Y, Antonietti M, et al. Chem. Mater., 2010, 22: 5119-5121 doi: 10.1021/cm1019102
55. [55]
  Liu G, Niu P, Sun C, et al. J. Am. Chem. Soc., 2010, 132: 11642-11648 doi: 10.1021/ja103798k
56. [56]
  Zhang Y J, Mori T, Ye J H, et al. J. Am. Chem. Soc., 2010, 132:6294-6295 doi: 10.1021/ja101749y
57. [57]
  Li Y, Wang Z, Xia T, et al. Adv. Mater., 2016, 28:6959-6965 doi: 10.1002/adma.201601960
58. [58]
  Chen Y, Wang B, Lin S, et al. J. Phys. Chem. C, 2014, 118: 29981-29989 doi: 10.1021/jp510187c
59. [59]
  Wang H, Zhang X D, Xie J, et al. Nanoscale, 2015, 7:5152-5156 doi: 10.1039/C4NR07645A
60. [60]
  Zhang X, Wang H, Wang H, et al. Adv. Mater., 2014, 26: 4438-4443 doi: 10.1002/adma.v26.26
61. [61]
  Yang S, Gong Y, Zhang J, et al. Adv. Mater., 2013, 25:2452-2456 doi: 10.1002/adma.v25.17
62. [62]
  Niu P, Zhang L, Liu G, et al. Adv. Funct. Mater., 2012, 22: 4763-4770 doi: 10.1002/adfm.v22.22
63. [63]
  Zhao Y, Zhang J, Qu L. ChemNanoMat, 2015, 1:298-318 doi: 10.1002/cnma.v1.5
64. [64]
  Dong F, Zhao Z, Xiong T, et al. ACS Appl. Mater. Interfaces, 2013, 5:11392-11401 doi: 10.1021/am403653a
65. [65]
  Samanta S, Martha S, Parida K. ChemCatChem, 2014, 6:1453-1462
66. [66]
  Bi L, Xu D, Zhang L, et al. Phys. Chem. Chem. Phys., 2015, 17:29899-29905 doi: 10.1039/C5CP05158D
67. [67]
  Zhao Z, Sun Y, Dong F. Nanoscale, 2015, 7:15-37 doi: 10.1039/C4NR03008G
68. [68]
  Wang H, Sun X, Li D, et al. J. Am. Chem. Soc., 2017, 139: 2468-2473 doi: 10.1021/jacs.6b12878
69. [69]
  Li X H, Chen J S, Wang X, et al. J. Am. Chem. Soc., 2011, 133:8074-8077 doi: 10.1021/ja200997a
70. [70]
  Li X H, Antonietti M. Chem. Soc. Rev., 2013, 42:6593-6604 doi: 10.1039/c3cs60067j
71. [71]
  Li X H, Wang X, Antonietti M. Chem. Sci., 2012, 3:2170-2174 doi: 10.1039/c2sc20289a
72. [72]
  Lu X, Xu K, Tao S, et al. Chem. Sci., 2016, 7:1462-1467 doi: 10.1039/C5SC03551A
73. [73]
  Jorge A B, Martin D J, Dhanoa M T S, et al. J. Phys. Chem. C, 2013, 117:7178-7185 doi: 10.1021/jp4009338
74. [74]
  Liu J, Liu Y, Liu N, et al. Science, 2015, 347:970-974 doi: 10.1126/science.aaa3145
75. [75]
  Tian J Q, Liu Q, Asiri A M, et al. Anal. Chem., 2013, 85: 5595-5599 doi: 10.1021/ac400924j
76. [76]
  Zhang X L, Zheng C, Guo S S, et al. Anal. Chem., 2014, 86: 3426-3434 doi: 10.1021/ac500336f
77. [77]
  Wang Q B, Wang W, Lei J P, et al. Anal. Chem., 2013, 85: 12182-12188 doi: 10.1021/ac403646n
78. [78]
  Zhang S, Li J, Zeng M, et al. Nanoscale, 2014, 6:4157-4162 doi: 10.1039/c3nr06744k
79. [79]
  Bian J, Li Q, Huang C, et al. Nano Energy, 2015, 15:353-361 doi: 10.1016/j.nanoen.2015.04.012
80. [80]
  Li G, Lian Z, Wang W, et al. Nano Energy, 2016, 19:446-454 doi: 10.1016/j.nanoen.2015.10.011
81. [81]
  Jayaraman T, Arumugam Raja S, Priya A, et al. New J. Chem., 2015, 39:1367-1374 doi: 10.1039/C4NJ01807A
82. [82]
  Zhou X, Jin B, Li L, et al. J. Mater. Chem., 2012, 22:17900-17905 doi: 10.1039/c2jm32686h
83. [83]
  Su J, Geng P, Li X, et al. Nanoscale, 2015, 7:16282-16289 doi: 10.1039/C5NR04562B
84. [84]
  Hou Y, Zuo F, Dagg A P, et al. Adv. Mater., 2014, 26:5043-5049 doi: 10.1002/adma.201401032
85. [85]
  Yin H S, Zhou Y L, Li B C, et al. Sens. Actuators B, 2016, 222:1119-1126 doi: 10.1016/j.snb.2015.08.019
86. [86]
  Liu Y, Yan K, Zhang J. ACS Appl. Mater. Interfaces, 2016, 8:28255-28264 doi: 10.1021/acsami.5b08275
87. [87]
  Li R Y, Zhang Y, Tu W W, et al. ACS Appl. Mater. Interfaces, 2017, 9:22289-22297 doi: 10.1021/acsami.7b06107
88. [88]
  Li X, Zhu L, Zhou Y, et al. Anal. Chem., 2017, 89:2369-2376 doi: 10.1021/acs.analchem.6b04184
89. [89]
  Zhuang J, Lai W, Xu M, et al. ACS Appl. Mater. Interfaces, 2015, 7:8330-8338 doi: 10.1021/acsami.5b01923
1. [1]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
2. [2]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
3. [3]
  Dongdong Yao , JunweiGu , Yi Yan , Junliang Zhang , Yaping Zheng . Teaching Phase Separation Mechanism in Polymer Blends Using Process Representation Teaching Method: A Teaching Design for Challenging Theoretical Concepts in “Polymer Structure and Properties” Course. University Chemistry, 2025, 40(4): 131-137. doi: 10.12461/PKU.DXHX202408125
4. [4]
  Qingjun PAN , Zhongliang GONG , Yuwu ZHONG . Advances in modulation of the excited states of photofunctional iron complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 45-58. doi: 10.11862/CJIC.20240365
5. [5]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001
6. [6]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
7. [7]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
8. [8]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
9. [9]
  Xuefei Leng , Yanshai Wang , Hai Wang , Shengyang Tao . The In-Depth integration of “Industry-University-Research” in the Exploration and Practice of “Comprehensive Training in Polymer Engineering”. University Chemistry, 2025, 40(4): 66-71. doi: 10.12461/PKU.DXHX202405105
10. [10]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
11. [11]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
12. [12]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-. doi: 10.3866/PKU.WHXB202309027
13. [13]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
14. [14]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
15. [15]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
16. [16]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
17. [17]
  Jiajia Li , Xiangyu Zhang , Zhihan Yuan , Zhengyang Qian , Jian Zhu . 3D Printing Based on Photo-Induced Reversible Addition-Fragmentation Chain Transfer Polymerization. University Chemistry, 2024, 39(5): 11-19. doi: 10.3866/PKU.DXHX202309073
18. [18]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
19. [19]
  .
  CCS Chemistry 综述推荐│绿色氧化新思路：光/电催化助力有机物高效升级
  . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.
20. [20]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094

Get Citation

PDF

XML

Metrics

PDF Downloads(114)
Abstract views(7497)
HTML views(2069)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Recent Progresses on the Photoexcitation Processes of Polymeric Carbon Nitride-Based Materials

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com