Citation: XIE Jia-Ze, WANG Da-Peng, MA Jian-Ping, WANG Hai-Ying, ZUO Jing-Lin. Iron(Ⅱ) Complex Based on π-Conjugated 4-Tetrathiafulvalene-2, 6-di(pyrazin-2-yl)pyridine Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2045-2050. doi: 10.11862/CJIC.2017.246 shu

Iron(Ⅱ) Complex Based on π-Conjugated 4-Tetrathiafulvalene-2, 6-di(pyrazin-2-yl)pyridine Ligand

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China
2.
School of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China
3.
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China

Corresponding author: WANG Hai-Ying, haiyingqd@163.com
Received Date: 1 August 2017
Revised Date: 18 September 2017

Figures(6)

The tetrathiafulvalene (TTF) functionalized 2, 6-di(pyrazin-2-yl)pyridine derivative, 4-tetrathiafulvalene-2, 6-di(pyrazin-2-yl)pyridine (L), was designed and synthesized. Based on L, one electrochemically active TTF-containing Fe(Ⅱ) complex, namely, [Fe(Ⅱ)(L)₂](BF₄)₂·2.75CH₃CN·0.25CH₂Cl₂ (1), was synthesized and characterized by IR, elemental analysis, and X-ray single crystal diffraction. The complex 1 is formed by ligands and iron(Ⅱ) in a tridentate fashion. Complex 1 exhibits a discrete structure and features diverse nonclassical hydrogen bonding interactions, π…π and S…S interactions. In addition, magnetic, electrochemical, and spectroelectrochemistry properties for complex 1 have been studied.
- tetrathiafulvalene,
- Fe(Ⅱ) complex,
- multifunctional materials,
- crystal structure
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142