Citation: WANG Qiang, XU Rui, WANG Xu-Sheng, LIU Si-De, HUANG Yuan-Biao, CAO Rong. Platinum Nanoparticle-Decorated Porous Porphyrin-Based Metal-Organic Framework for Photocatalytic Hydrogen Production[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2038-2044. doi: 10.11862/CJIC.2017.240 shu

Platinum Nanoparticle-Decorated Porous Porphyrin-Based Metal-Organic Framework for Photocatalytic Hydrogen Production

WANG Qiang ^1,2 ,
XU Rui ¹ ,
WANG Xu-Sheng ¹ ,
LIU Si-De ² ,
HUANG Yuan-Biao ^1,, ,
CAO Rong ^1,,

1.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
2.
Fujian Normal University, Fuzhou, Fujian 350007, China

Corresponding author: HUANG Yuan-Biao, rcao@fjirsm.ac.cn CAO Rong, ybhuang@fjirsm.ac.cn
Received Date: 30 July 2017
Revised Date: 7 September 2017

Figures(8)

Herein, Pt NPs of ca. 2.5 nm incorporated inside the mesopores of porphyrin-based MOF PCN-222, denoted as Pt@PCN-222, were prepared using double-solvent method followed by visible-light reduction. The obtained mesoporous MOF composite Pt@PCN-222 can effectively adsorb visible-light to promote the water splitting for hydrogen production, which gives a H₂ yield of 253 μmol·g^-1·h^-1.
- metal-organic framework,
- mesopore,
- PCN-222,
- platinum nanoparticles,
- water splitting for hydrogen production 0 Introduction
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