Citation: Susannah D. Banziger, Eileen C. Judkins, Matthias Zeller, Ren Tong. Diruthenium-DMBA Bis-Alkynyl Compounds with Hetero-and Extended-Aryl Appendant: Preparation and Electrochemical Property[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2103-2109. doi: 10.11862/CJIC.2017.238 shu

Diruthenium-DMBA Bis-Alkynyl Compounds with Hetero-and Extended-Aryl Appendant: Preparation and Electrochemical Property

Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, USA

Corresponding author: Ren Tong, tren@purdue.edu
Received Date: 14 June 2017
Revised Date: 23 August 2017

Figures(4)

Under weak base conditions, diruthenium(Ⅲ) tetrakis-N, N'-dimethylbenzamidinate (DMBA) nitrate Ru₂(DMBA)₄(NO₃)₂ was reacted with arylethyne ligands, where aryl=NAP^me (N-methyl-1, 8-naphthalimide), NAP^iso (N-isopropyl-1, 8-naphthalimide), Naphth (naphthalene) and Ant (anthracene), to afford four new compounds: trans-Ru₂(DMBA)₄(C₂Ar)₂ (Ar=NAP^me, 1; NAP^iso, 2; Naphth, 3; Ant, 4). Molecular structures of new compounds were determined using single crystal X-ray diffraction, and the Ru-Ru bond lengths (0.245 0~0.249 1 nm) are consis-tent with the existence of a Ru-Ru single bond. These compounds are diamagnetic and were further characterized with ¹H NMR and UV-Vis-NIR spectroscopic techniques. Cyclic voltammograms of compounds 1~4 consist of two reversible one-electron processes, an oxidation and a reduction, and their potentials depend on the nature of Ar.
- diruthenium,
- alkynyl,
- naphthalimide,
- naphthalene,
- anthracene
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