Citation: LIU Lu, XU Chun-Ying, LI Ying, WANG Ji-Chao, ZHANG Yu-Ping, WANG Jian-Ji. Two Cd(Ⅱ) Coordination Polymers Based on Flexible Tetracarboxylic Acid Ligands:Crystal Structures and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1817-1824. doi: 10.11862/CJIC.2017.233 shu

Two Cd(Ⅱ) Coordination Polymers Based on Flexible Tetracarboxylic Acid Ligands:Crystal Structures and Fluorescent Properties

LIU Lu ^1,, ,
XU Chun-Ying ² ,
LI Ying ¹ ,
WANG Ji-Chao ¹ ,
ZHANG Yu-Ping ^1,, ,
WANG Jian-Ji ³

1.
Postdoctoral Research Base, School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China
2.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan 471934, China
3.
Henan Normal University, Xinxiang, Henan 453007, China

Corresponding author: LIU Lu, liululiulu2012@126.com ZHANG Yu-Ping, beijing2008zyp@163.com
Received Date: 19 December 2016
Revised Date: 7 September 2017

Figures(8)

Two coordination polymers, [Cd₂(L)(DMF)_1.5(H₂O)₂]_n (1) and {[Cd(L)_0.5(4, 4'-bpy)(H₂O)]·2H₂O}_n (2), have been designed and synthesized by solvothermal or hydrothermal reactions of 5, 5'-(hexane-1, 6-diyl)-bis(oxy)diisophthalic acid ligand (H₄L) with Cd(Ⅱ) metal ions in the presence/absence of N-donor ligands. The structures of 1~2 have been determined by single-crystal X-ray diffraction analyses and further characterized via infrared spectra (IR), powder X-ray diffraction (PXRD), elemental analyses and thermogravimetric (TG) analyses. Complex 1 features a (4, 4)-connected sql topology net with point symbol of {4⁴·6²}₂. Complex 2 presents a trinodal (4, 4, 4)-connected 3D 3-fold interpenetrating bbf network with a Schläfli symbol of (6⁶)(6⁴·8²). Additionally, complexes 1 and 2 present better thermal stabilities, and show different photoluminescence behaviors in the solid state.
- Cd(Ⅱ),
- crystal structure,
- topology,
- fluorescence
1. [1]
  Zheng A X, Si J, Tang X Y, et al. Inorg. Chem., 2012, 51:10262-10273 doi: 10.1021/ic301191n
2. [2]
  Jiang H, Feng D, Liu T, et al. J. Am. Chem. Soc., 2012, 134:14690-14693 doi: 10.1021/ja3063919
3. [3]
  Suh M. P, Park H. J, Prasad T. K, et al. Chem. Rev., 2012, 112:782-835
4. [4]
  Li J, Sculley R J, Zhou H C. Chem. Rev., 2012, 112:869-932 doi: 10.1021/cr200190s
5. [5]
  Liu Y, Xuan W, Cui Y. Adv. Mater., 2010, 22:4112-4135 doi: 10.1002/adma.v22:37
6. [6]
  Nugent P S, Rhodus V L, Pham T, et al. J. Am. Chem. Soc., 2013, 135:10950-10953 doi: 10.1021/ja4054948
7. [7]
  Bauer C A, Timofeeva T V, Settersten T B, et al. J. Am. Chem. Soc., 2007, 129:7136-7144 doi: 10.1021/ja0700395
8. [8]
  Zhang C L, Zhang M D, Qin L, et al. Cryst. Growth Des., 2014, 14:491-499 doi: 10.1021/cg401149h
9. [9]
  Cui Y, Yue Y, Qian G, et al. Chem. Rev., 2012, 112:1126-1162 doi: 10.1021/cr200101d
10. [10]
  Cook T R, Zheng Y R, Stang P J. Chem. Rev., 2013, 113:734-777 doi: 10.1021/cr3002824
11. [11]
  Peng Y, Gong T, Cui Y. Chem. Commun., 2013, 49:8253-8255 doi: 10.1039/c3cc43549k
12. [12]
  Wang Y L, Fu J H, Wei J J, et al. Cryst. Growth Des., 2012, 12:4663-4668 doi: 10.1021/cg300889x
13. [13]
  Kanoo P, Gurunatha K L, Maji T K. Cryst. Growth Des., 2009, 9:4147-4156 doi: 10.1021/cg900386q
14. [14]
  Hagrman P J, Hagrman D, Zubieta J. Angew. Chem., Int. Ed., 1999, 38:2638-2684 doi: 10.1002/(ISSN)1521-3773
15. [15]
  Zhang X P, Zhou J M, Shi W, et al. CrystEngComm, 2013, 15:9738-9744 doi: 10.1039/c3ce41073k
16. [16]
  Liu W L, Yu J H, Jiang J X, et al. CrystEngComm, 2011, 13:2764-2773 doi: 10.1039/c0ce00950d
17. [17]
  Ordonez C, Fonari M, Lindline J, et al. Cryst. Growth Des., 2014, 14:5452-5465 doi: 10.1021/cg5006133
18. [18]
  Eddaoudi M, Moler D B, Li H, et al. Acc. Chem. Res., 2001, 34:319-330 doi: 10.1021/ar000034b
19. [19]
  Karmakar A, Goldberg I. CrystEngComm, 2011, 13:339-349 doi: 10.1039/C0CE00474J
20. [20]
  Hawxwell S M, Espallargas G M, Bradshaw D, et al. Chem. Commun., 2007:1532-1534
21. [21]
  Perry J J, Kravtsov V C, McManus G J, et al. J. Am. Chem. Soc., 2007, 129:10076-10077 doi: 10.1021/ja0734952
22. [22]
  Qu L L, Zhu Y L, Li Y Z, et al. Cryst. Growth Des., 2011, 11:2444-2452 doi: 10.1021/cg200229h
23. [23]
  Berl V, Schmutz M, Krische M J, et al. Chem. Eur. J., 2002, 8:1227-1244 doi: 10.1002/1521-3765(20020301)8:5<1227::AID-CHEM1227>3.0.CO;2-0
24. [24]
  Sheldrick G M. Acta Crystallogr., Sect. A:Found. Crystallogr., 2008, A64:112-122
25. [25]
  He Y H, Feng Y L, Lan Y Z, et al. Cryst. Growth Des., 2008, 8:3586-3594 doi: 10.1021/cg8000398
26. [26]
  Zhang L Y, Zhang J P, Lin Y Y, et al. Cryst. Growth Des., 2006, 6:1684-1689 doi: 10.1021/cg060194f
27. [27]
  Zhang R B, Li Z J, Qin Y Y, et al. Inorg. Chem., 2008, 47:4861-4876 doi: 10.1021/ic8001042
28. [28]
  Ohkoshi S, Tokoro H, Hozumi T, et al. J. Am. Chem. Soc., 2006, 128:270-277 doi: 10.1021/ja0559092
29. [29]
  Censo D D, Fantacci S, Angelis F D, et al. Inorg. Chem., 2008, 47:980-989 doi: 10.1021/ic701814h
30. [30]
  Stadler M, Puntoriero F, Campagna S, et al. Chem. Eur. J., 2005, 11:3997-4009 doi: 10.1002/(ISSN)1521-3765
31. [31]
  Fang S M, Chen M, Yang X G, et al. CrystEngComm, 2012, 14:5299-5304 doi: 10.1039/c2ce25194a
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