Citation: WANG Hao, YANG Xi-Yun, YIN Zhou-Lan, CAO Gai-Fang, XU Hui. Synthesis and Adsorption Properties of ZrO₂-Coated Lithium Ion-Sieve from Salt Lake Brine[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1775-1781. doi: 10.11862/CJIC.2017.217 shu

Synthesis and Adsorption Properties of ZrO₂-Coated Lithium Ion-Sieve from Salt Lake Brine

WANG Hao ¹ ,
YANG Xi-Yun ^1,2,, ,
YIN Zhou-Lan ² ,
CAO Gai-Fang ¹ ,
XU Hui ¹

1.
School of Metallurgy and Environment, Central South University, Changsha 410083, China
2.
College of Chemistry and Chemical Engineering, Central South Universiyt, Changsha 410083, China

Corresponding author: YANG Xi-Yun, yxy7412@csu.edu.cn
Received Date: 8 May 2017
Revised Date: 22 August 2017

Figures(9)

ZrO₂-coated H_1.6Mn_1.6O₄ was synthesized from Li_1.6Mn_1.6O₄ precursor prepared by a hydrothermal method. The liquid precipitation process followed by acid washing was utilized to coat ZrO₂ on the precursor. The structure, morphology and composition of the ZrO₂-coated precursor were investigated by SEM, XRD, EDS and HRTEM analysis. The influences of coating content and roasting temperature on Mn dissolution loss ratio and Li adsorption capacity were discussed. The results indicate that a layer of ZrO₂ with 15 nm in thickness is coated on the precursor when ZrO₂ content is 3% and roasting temperature is 450℃. The Mn dissolution loss ratio decreases from 3.14% to 2.65% and Li adsorption capacity of the resulting ion sieve in the salt lake brine maintains 29.4 mg·g^-1. After 10 cycles of adsorption and desorption, the corresponding Mn dissolution loss ratio and Li adsorption capacity is 0.34% and 24.4 mg·g^-1, respectively. The adsorption capacity is higher than the bare lithium ion-sieve (22.9 mg·g^-1). The results suggest that the structure and cycle stability of H_1.6Mn_1.6O₄ are improved by a ZrO₂ coating layer.
- lithium ion-sieve,
- surface coating,
- Mn dissolution loss,
- Li adsorption capacity
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Synthesis and Adsorption Properties of ZrO₂-Coated Lithium Ion-Sieve from Salt Lake Brine