Citation: LI Zhi-Hua, WANG Yu-Xia, QIU Dan, LI Zai-Jun, GU Zhi-Guo. AAO Assisted 1D Confined Assembly and 2D Surface Filming of Iron(Ⅱ) Triazole Nanomaterial and Spin-Crossover Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2311-2321. doi: 10.11862/CJIC.2017.200 shu

AAO Assisted 1D Confined Assembly and 2D Surface Filming of Iron(Ⅱ) Triazole Nanomaterial and Spin-Crossover Properties

LI Zhi-Hua ¹ ,
WANG Yu-Xia ¹ ,
QIU Dan ¹ ,
LI Zai-Jun ¹ ,
GU Zhi-Guo ^1,2,,

1.
School of Chemistry and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China
2.
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, Wuxi, Jiangsu 214122, China

Corresponding author: GU Zhi-Guo, zhiguogu@jiangnan.edu.cn
Received Date: 28 May 2017
Revised Date: 16 July 2017

Figures(7)

Iron(Ⅱ) triazole (SCO1) and iron(Ⅱ) 4-amino-triazole (SCO2) spin-crossover (SCO) nanomaterials were assembled in the channel and on the surface of anodic aluminum oxide (AAO) templates simultaneously by a facile sequential multistep assembly method. The obtained SCO1-1D+2D and SCO2-1D+2D nanomaterials have been characterized by SEM, FT-IR, PXRD, and Raman spectra. SEM images show that spherical SCO NPs growing in the channel of AAO templates aggregate with time going on, and assemble as 1D nanostructure. While those growing on the surface of AAO substrates assemble as uniform and dense 2D SCO film. It is interesting that both SCO-1D+2D nanostructures present a special two-step spin-crossover behaviour with hysteresis loops (SCO1-1D+2D:T_c1↑=319 K, T_c1↓=313 K, T_c2↑=381 K, T_c2↓=340 K; SCO2-1D+2D:T_c1↑=181 K, T_c1↓=155 K, T_c2↑=246 K, T_c2↓=233 K). The magnetic measuring of SCO-1D and SCO-2D indicates that the two-step SCO behaviour results from the different assembly morphologies of SCO. The first step spin transition at lower temperature is ascribed to the properties of 2D SCO films growing on the surface of AAO templates, while the transition in the second step at higher temperature can be attributed to the 1D SCO confined assembly growing in the channel of AAO membranes.
- nanomaterials,
- anodic aluminum oxide (AAO) templates,
- self-assembly,
- two-step spin-crossover behavior
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