Citation: LIAO Bei-Ling, YANG Ge-Ge, LI Shi-Xiong, JIANG Yi-Min, YIN Xiu-Ju. Syntheses, Structures and Magnetic Analysis of Co(Ⅱ) Coordination Polymer Based on N-(Pyridine-3-sulfonyl amino) Acetate[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1843-1848. doi: 10.11862/CJIC.2017.189 shu

Syntheses, Structures and Magnetic Analysis of Co(Ⅱ) Coordination Polymer Based on N-(Pyridine-3-sulfonyl amino) Acetate

LIAO Bei-Ling ^1,2 ,
YANG Ge-Ge ² ,
LI Shi-Xiong ^1,2,3,, ,
JIANG Yi-Min ^2,, ,
YIN Xiu-Ju ^1,2

1.
College of Chemistry and Biological Engineering, Hechi University, Yizhou, Guangxi 546300, China
2.
School of Chemistry and Pharmacy, Guangxi Normal University, Guilin, Guangxi 541004, China
3.
School of Environment and Energy, South China University of Technology, Guangzhou 510006, China

Corresponding author: LI Shi-Xiong, lsx1324@163.com JIANG Yi-Min, 790223684@qq.com
Received Date: 1 April 2017
Revised Date: 26 May 2017

Figures(4)

The reaction of Co(OAc)₂·2H₂O, 4, 4'-azopyridine(4, 4'-azpy) with N-(pyridine-3-sulfonyl amino) acetate (H₂L) in ethanol and water leads to the formation of one mononuclear cobalt polymer {[Co(L)(4, 4'-azpy)(H₂O)]·2H₂O}_n (1). The structure of 1 was analyzed by elemental analysis, IR, TG and single crystal X-ray diffraction. The results show that complex 1 belongs to monoclinic system and P2₁/n space groups. The TGA shows that the structure of 1 remains unchanged during the loss of coordination water molecules and free water molecules, and begins to decompose at 238℃, indicating 1 has good stability. The magnetic investigation shows that there is antiferromagnetic interactions between Co(Ⅱ) ions in polymer 1.
- polymer,
- N-(pyridine-3-sulfonyl amino) acetate,
- structure,
- magnetic
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