Citation: HUANG Ji-Chun, MEI Lin, MA Zheng, ZHU Xian-Yu, QUAN Jing-Bin, LI De-Cheng. Electrochemical Performance of Li-rich Layered Cathode Material 0.6Li[Li_1/3Mn_2/3]O₂·0.4LiNi_5/12Mn_5/12Co_1/6O₂ by ZrO₂ Coating[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(7): 1236-1242. doi: 10.11862/CJIC.2017.173 shu

Electrochemical Performance of Li-rich Layered Cathode Material 0.6Li[Li_1/3Mn_2/3]O₂·0.4LiNi_5/12Mn_5/12Co_1/6O₂ by ZrO₂ Coating

College of Physics, Optoelectronics and Energy & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215006, China

Received Date: 18 February 2017
Revised Date: 21 May 2017

Figures(9)

Lithium-rich layered oxide materials 0.6Li[Li_1/3Mn_2/3]O₂·0.4LiNi_5/12Mn_5/12Co_1/6O₂(named as LNMCO) have been prepared by spray-drying method and followed by high temperature annealed and surface coated with ZrO₂.The TEM results show that the ZrO₂ layer with nano size particles is located on the surface of the particles.The initial coulombic efficiencies and discharge capacities of the 0.6Li[Li_1/3Mn_2/3]O₂·0.4LiNi_5/12Mn_5/12Co_1/6O₂ lithium-rich layered oxide material are largely improved by ZrO₂ coating, and the value is 87.2%, 279.3 mAh·g^-1, compared to 75.1%, 224.1 mAh·g^-1, respectively, for the bare sample at the room temperature and at a current density of 20 mA·g^-1 in the voltage range of 2.0 to 4.8 V when the content of ZrO₂ is 1.5%.After 100 cycles, the 1.5% ZrO_2^-coated sample shows a high discharge capacity of 248.3 mAh·g^-1 with a capacity retention of 88.9%, while the bare LNMCO presents a lower discharge capacity of 195.9 mAh·g^-1 with a capacity retention of 87.4%.
- lithium-ion batteries,
- cathode material,
- lithium-rich layered oxide cathode,
- Zirconium oxide coating
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Electrochemical Performance of Li-rich Layered Cathode Material 0.6Li[Li1/3Mn2/3]O2·0.4LiNi5/12Mn5/12Co1/6O2 by ZrO2 Coating

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通讯作者: 陈斌, bchen63@163.com

Electrochemical Performance of Li-rich Layered Cathode Material 0.6Li[Li_1/3Mn_2/3]O₂·0.4LiNi_5/12Mn_5/12Co_1/6O₂ by ZrO₂ Coating