Citation: XIONG Jun, LÜ Shao-Fang, PENG Jun-Jun, LI Ming, LI Wei, YANG Shui-Bin. Two Inorganic-Organic Hybrid Crystals Based on Polyoxometallates and Supramolecular Cation:Syntheses and Crystal Structures[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1649-1655. doi: 10.11862/CJIC.2017.171 shu

Two Inorganic-Organic Hybrid Crystals Based on Polyoxometallates and Supramolecular Cation:Syntheses and Crystal Structures

XIONG Jun ^1,, ,
LÜ Shao-Fang ¹ ,
PENG Jun-Jun ¹ ,
LI Ming ¹ ,
LI Wei ¹ ,
YANG Shui-Bin ^2,,

1.
College of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan 430200, China
2.
College of Chemical Engineering, Huanggang Normal University, Huanggang, Hubei 438000, China

Corresponding author: XIONG Jun, jxiong@wtu.edu.cn; 2416975012@qq.com YANG Shui-Bin, 2416975012@qq.com
Received Date: 31 March 2017
Revised Date: 17 May 2017

Figures(5)

Two new inorganic-organic hybrids[(3-F-4-MeAnis)(DB[18]crown-6)]₂[Mo₆O₁₉]·2CH₃CN (1) and[(2-F-4-MeAnis)([18]crown-6)]₂[SMo₁₂O₄₀]·2CH₃CN (2) (3-F-4-MeAnis=3-fluoro-4-methylanilinium, DB[18]crown-6=dibenzo[18]crown-6, 2-F-4-MeAnis=2-fluoro-4-methylanilinium) have been synthesized and characterized by infrared spectrum (IR), elemental analysis (EA), thermosgravimetric analysis (TGA) and X-ray diffraction. Compounds 1 and 2 are constructed through noncovalent bonding interaction and the polyoxometalates (POMs) and supramolecular cation arrange alternately. Supramolecular cation forms through the N-H…O hydrogen bonding interaction between the nitrogen atom of anilinium and oxygen atoms of crown ether derivatives. In the crystals of 1 and 2, each polyoxoanion is surrounded by six supramolecular cations and forms hexagonal arrangement viewed along the a axis. Crystalline structure and TGA indicated that phenyl rings in DB[18]crown-6 plays an important role in maintaining the stability of compound 1.CCDC:1540103,1;1540105,2.
- inorganic-organic hybrids,
- supramolecular self-assembled,
- polyoxometallates,
- crown ether,
- supramolecular cation
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沈阳化工大学材料科学与工程学院沈阳 110142