Citation: SUN Meng-Ting, LU Si-Yu, SUN Jing, WANG Yuan, YU Wen-Sheng, CUI Si-Yuan. Preparation and Property of Temperature Sensitive Paints with Different Europium Complexes as Probe Molecules[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(7): 1217-1222. doi: 10.11862/CJIC.2017.136 shu

Preparation and Property of Temperature Sensitive Paints with Different Europium Complexes as Probe Molecules

College of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China

Corresponding author: SUN Jing, sj-cust@126.com
Received Date: 9 February 2017
Revised Date: 2 May 2017

Figures(5)

Probe molecules of Eu (MAA)₃Phen, Eu (Sal)₃Phen and Eu (CA)₃Phen were prepared by using europium oxide (Eu₂O₃), methacrylate (MAA), salicylic acid (HSal), cinnamic acid (HCA) and phenanthroline (Phen).A series of temperature sensitive paints (TSPs) were obtained by the polymerization of different probe molecules, methyl methacrylate (MMA) and the initiator of benzoyl peroxide (BPO).The structure, morphology, luminescence property of probe molecules and the temperature quenching property of TSPs were characterized by infrared spectrometer, fluorescence spectrometer and scanning electron microscopy.The effect of different ligands on the luminescence property of probe molecules and the temperature quenching property of TSPs were studied.It is indicated that the fluorescence intensity of Eu (MAA)₃Phen is obviously higher than that of Eu (Sal)₃Phen or Eu (CA)₃Phen, and the temperature quenching properties of the three TSPs are good.The temperature sensitivity of Eu (MAA)₃Phen/PMMA and Eu (CA)₃Phen/PMMA is higher in 55~65℃.However, the temperature sensitivity of Eu (Sal)₃Phen/PMMA is higher in 35~45℃.That is to say, different TSPs can be used in different temperature ranges.
- probe molecules,
- temperature sensitive paints,
- temperature quenching,
- phenanthroline
1. [1]
  Liu T, Campbell B, Sullivan J P, et al. J. Thermophys. Heat Transfer, 1995, 9(4):605-611 doi: 10.2514/3.714
2. [2]
  Liu T, Campbell B, Sullivan J P, et al. Exp. Therm. Fluid Sci., 1995, 10(3):101-102
3. [3]
  LIU Yan-Zhu, YI Chun, HUANG Li-Qun, et al. J. Nanchang Univ.:Nat. Sci., 2006, 30(4):360-364
4. [4]
  DU Chen-Xia, WANG Zhi-Qiang, XIN Qi, et al. Acta Chim. Sinica, 2004, 62(22):2265-2269 doi: 10.3321/j.issn:0567-7351.2004.22.011
5. [5]
  Wang J F, Zhang D H, Liu X, et al. J. Chem. Eng. Data, 2010, 55(12):5608-5613 doi: 10.1021/je1004565
6. [6]
  LIU Jian-Feng, CHEN Ji-Fei, ZHAO Guo-Liang. Chinese J. Inorg. Chem., 2011, 27(1):100-106
7. [7]
8. [8]
  HONG Guang-Yan. Rare Earth Luminescent Material-Basic and Applied. Beijing:Science Press, 2011.
9. [9]
  SUN Jing, JIN Guang-Yong, LI Chang-Li, et al. J. Chem. Eng. Chin. Univ., 2011, 25(2):361-364
10. [10]
  SONG Ya-Jiao, SUN Jing, ZHU Peng, et al. Chinese J. Inorg. Chem., 2013, 29(6):1171-1175
11. [11]
  SONG Ya-Jiao, SUN Jing, YAN Ling-Ling, et al. J. Chin. Rare Earth Soc., 2013, 31(1):55-59
12. [12]
  ZHANG Min, SUN Jing, LIU Hui-Min, et al. Chinese J. Inorg. Chem., 2016, 32(3):421-426 doi: 10.11862/CJIC.2016.058
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