Citation: SUN Yuan-Xu, GUO Dan-Dan, ZHU Xiao-Qing, WANG Cheng, CHEN She-Yun, DAI Jing-Tao. Efficient Synthesis and Application in Heck Reaction of Pd/Fe₃O₄ Magnetic Nanoparticles(English)[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(6): 1081-1089. doi: 10.11862/CJIC.2017.132 shu

Efficient Synthesis and Application in Heck Reaction of Pd/Fe₃O₄ Magnetic Nanoparticles(English)

1.
College of Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
2.
College of Chemical and Environmental Engineering, Yancheng Teachers University, Yancheng, Jiangsu 224051, China

Corresponding author: DAI Jing-Tao, ycjtdai@163.com
Received Date: 16 February 2017
Revised Date: 26 April 2017

Figures(8)

Pd/Fe₃O₄ NPs have been successfully synthesized using polyvinyl pyrrolidone as a stabilizing agent. The resultant samples were characterized by X-ray diffraction, transmission electron microscopy, inductively coupled plasma, and magnetic studies. The Pd/Fe₃O₄ NPs catalyst was also applied in the Heck reaction to evaluate the catalytic performance. The results show that the cubic phase of Pd coexists with the cubic phase of Fe₃O₄, and the catalysts have size less 20 nm and the excellent catalytic activity of Pd/Fe₃O₄ NPs in the Heck reaction. In addition, the catalyst can be recovered via a magnet and reused several times without significant loss of its catalytic activity.
- Pd/Fe₃O₄,
- magnetic nanoparticles,
- polyvinyl pyrrolidone,
- Heck reaction
1. [1]
  Ibrahim H, Bala M D. J. Organomet. Chem., 2015, 794:301-310 doi: 10.1016/j.jorganchem.2015.07.015
2. [2]
  Majumder A, Gupta R, Mandal M, et al. J. Org. Chem., 2015, 781:23-34 doi: 10.1016/j.jorganchem.2014.11.018
3. [3]
  Moussa S, Siamaki A R, Gupton B F, et al. ACS Catal., 2012, 2(1):145-154 doi: 10.1021/cs200497e
4. [4]
  Lee Y, Hong M C, Ahn H, et al. J. Org. Chem., 2014, 769:, 80-93 doi: 10.1016/j.jorganchem.2014.07.013
5. [5]
  Kogan V, Aizenshtat Z, Popovitz B R, et al. Org. Lett., 2002, 4:3529-3532 doi: 10.1021/ol026689p
6. [6]
  Zhang Z, Zha Z, Gan C, et al. J. Org. Chem., 2006, 71:4339-4342 doi: 10.1021/jo060372b
7. [7]
  Chang Y C, Chang C H, Wang L W, et al. Polyhedron, 2015, 100:382-391 doi: 10.1016/j.poly.2015.08.041
8. [8]
  LI Xue-Ting, ZANG Peng-Yuan, YE Qiu-Ming, et al. Chinese J. Inorg. Chem., 2011, 27(8):1550-1554
9. [9]
  Nezhad A K, Panahi F. J. Organomet. Chem., 2013, 741-742:7-14 doi: 10.1016/j.jorganchem.2013.05.013
10. [10]
  Jhou Y M, Nandi D J, Lee Y, et al. Polyhedron, 2015, 100:28-35 doi: 10.1016/j.poly.2015.07.027
11. [11]
  Nowrouzi N, Zarei M. Tetrahedron, 2015, 71:7847-7852 doi: 10.1016/j.tet.2015.08.023
12. [12]
  Zhang J, Li T, Zhao X, et al. J. Colloid Interface Sci., 2016, 463:13-21 doi: 10.1016/j.jcis.2015.10.035
13. [13]
  Firouzabadi H, Iranpoor N, Kazemi F, et al. J. Mol. Catal. A:Chem., 2012, 357:154-161 doi: 10.1016/j.molcata.2012.02.006
14. [14]
  Astruc D. Inorg. Chem., 2007, 46:1884-1894 doi: 10.1021/ic062183h
15. [15]
  Fernández G L, Blanco M, Blanco C, et al. J. Mol. Catal. A:Chem., 2016, 416:140-146 doi: 10.1016/j.molcata.2016.02.023
16. [16]
  Andujar P, Lanone S, Brochard P, et al. Rev. Mal. Respir., 2011, 28:e66-e75 doi: 10.1016/j.rmr.2011.09.008
17. [17]
  Schmid G. Chem. Rev., 1992, 92:1709-1727 doi: 10.1021/cr00016a002
18. [18]
  Szucs A, Berger F, Dekany I. Colloids Surf. A, 2000, 174:387-402 doi: 10.1016/S0927-7757(00)00597-5
19. [19]
  Deraedt C, Astruc D. Acc. Chem. Res., 2014, 47:494-503 doi: 10.1021/ar400168s
20. [20]
  Khazaei A, Khazaei M, Rahmati S. J. Mol. Catal. A:Chem., 2015, 398:241-247 doi: 10.1016/j.molcata.2014.12.013
21. [21]
  Ojala J, SirviöJ A, Liimatainen H. Chem. Eng. J., 2016, 288:312-320 doi: 10.1016/j.cej.2015.10.113
22. [22]
  Magdesieva T V, Nikitin O M, Zolotukhina E V, et al. Electrochim. Acta, 2014, 122:289-295 doi: 10.1016/j.electacta.2013.09.157
23. [23]
  Petrucci C, Cappelletti M, Piermatti O, et al. J. Mol. Catal. A:Chem., 2015, 401:27-34 doi: 10.1016/j.molcata.2015.02.012
24. [24]
  Gulcan M, Zahmakiran M, Özkar S. Appl. Catal. B:Environ., 2014, 147:394-401 doi: 10.1016/j.apcatb.2013.09.007
25. [25]
  Yuan D, Huang B. Catal. Commun., 2012, 18:126-131 doi: 10.1016/j.catcom.2011.11.032
26. [26]
  Carosio M G A, Bernardes D F, Andrade F D, et al. J. Food Eng., 2016, 173:143-149 doi: 10.1016/j.jfoodeng.2015.11.004
27. [27]
  Petrov A. Y, Chase J G, Sellier M, et al. Math. Biosci., 2013, 246:191-201 doi: 10.1016/j.mbs.2013.08.012
28. [28]
  XIAO Wang-Chuan, WANG Ye-Min, WANG Ren-Zhang, et al. Chinese J. Inorg. Chem., 2014, 30(11):2559-2563
29. [29]
  Li S. Z, Zhang W, Chen F X, et al. Mater. Res. Bull., 2015, 66:186-191 doi: 10.1016/j.materresbull.2015.02.042
30. [30]
  Li H, Lu Z, Cheng G, et al. RSC Adv., 2015, 5:5059-5067 doi: 10.1039/C4RA12536C
31. [31]
  Agiotis L, Theodorakos I, Samothrakitis S, et al. J. Magn. Magn. Mater., 2016, 401:956-964 doi: 10.1016/j.jmmm.2015.10.111
32. [32]
  Haracz S, Hilgendorff M, Rybka J D, et al. Nucl. Instrum. Methods Phys. Res., Sect. B, 2015, 364:120-126 doi: 10.1016/j.nimb.2015.08.035
33. [33]
  Feng J, Cai C. J. Fluorine Chem., 2013, 146, 6-10 doi: 10.1016/j.jfluchem.2012.12.009
34. [34]
  Liu E T, Zhao H P, Li H, et al. New J. Chem., 2014, 38:2911-2916 doi: 10.1039/c3nj01659e
35. [35]
  NIU Yi-Fan, YANG Ying, YANG Wen-Tao. Chinese J. Inorg. Chem., 2016, 32(12):2129-2135
36. [36]
  Li S Z, Zhang W, So M H, et al. J. Mol. Catal. A:Chem., 2012, 359:81-87 doi: 10.1016/j.molcata.2012.03.025
37. [37]
  Sanchez-Padilla N M, Montemayor S M, Torres L A, et al. Int. J. Hydrogen Energ, 2013, 38:12681-12688 doi: 10.1016/j.ijhydene.2012.11.026
38. [38]
  Bhowmik R N, Poddar A, Saravanan A. J. Magn. Magn. Mater., 2010, 322:2340-2349 doi: 10.1016/j.jmmm.2010.02.035
39. [39]
  Cuenú F, Abonia R, Bolaños A, et al. J. Organomet. Chem., 2011, 696:1834-1839 doi: 10.1016/j.jorganchem.2011.02.016
40. [40]
  Martins D D L, Alvarez H M, Aguiar L C S, et al. Appl. Catal. A:Gen., 2011, 408:47-53 doi: 10.1016/j.apcata.2011.09.014
41. [41]
  Karthikeyan P, Muskawar P N, Aswar S A, et al. J. Mol. Catal. A:Chem., 2012, 358:112-120 doi: 10.1016/j.molcata.2012.03.004
42. [42]
  Fortea-Pérez F R, Schlegel I, Julve M. J. Organomet. Chem., 2013, 743:102-108 doi: 10.1016/j.jorganchem.2013.06.041
43. [43]
  Karami K, Moghadam Z K, Hosseini-Kharat M. Catal. Commun., 2014, 43:25-28 doi: 10.1016/j.catcom.2013.08.027
1. [1]
  Xuhui Fan , Fan Wang , Mengjiao Li , Faiza Meharban , Yaying Li , Yuanyuan Cui , Xiaopeng Li , Jingsan Xu , Qi Xiao , Wei Luo . Visible light excitation on CuPd/TiN with enhanced chemisorption for catalyzing Heck reaction. Chinese Chemical Letters, 2025, 36(1): 110299-. doi: 10.1016/j.cclet.2024.110299
2. [2]
  Yuan CONG , Yunhao WANG , Wanping LI , Zhicheng ZHANG , Shuo LIU , Huiyuan GUO , Hongyu YUAN , Zhiping ZHOU . Construction and photocatalytic properties toward rhodamine B of CdS/Fe₃O₄ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2241-2249. doi: 10.11862/CJIC.20240219
3. [3]
  Qinwen Zheng , Xin Liu , Lintao Tian , Yi Zhou , Libing Liao , Guocheng Lv . Mechanism of Fenton catalytic degradation of Rhodamine B induced by microwave and Fe₃O₄. Chinese Chemical Letters, 2025, 36(4): 109771-. doi: 10.1016/j.cclet.2024.109771
4. [4]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198
5. [5]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
6. [6]
  Xun Zhu , Chenchen Zhang , Yingying Li , Yin Lu , Na Huang , Dawei Wang . Degradation of perfluorooctanoic acid by inductively heated Fenton-like process over the Fe₃O₄/MIL-101 composite. Chinese Chemical Letters, 2024, 35(12): 109753-. doi: 10.1016/j.cclet.2024.109753
7. [7]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
8. [8]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
9. [9]
  Xiao-Fang Lv , Xiao-Yun Ran , Yu Zhao , Rui-Rui Zhang , Li-Na Zhang , Jing Shi , Ji-Xuan Xu , Qing-Quan Kong , Xiao-Qi Yu , Kun Li . Combing NIR-Ⅱ molecular dye with magnetic nanoparticles for enhanced photothermal theranostics with a 95.6% photothermal conversion efficiency. Chinese Chemical Letters, 2025, 36(4): 110027-. doi: 10.1016/j.cclet.2024.110027
10. [10]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083
11. [11]
  Ke Zhang , Sheng Zuo , Pengyuan You , Tong Ru , Fen-Er Chen . Palladium-catalyzed stereoselective decarboxylative [4 + 2] cyclization of 2-methylidenetrimethylene carbonates with pyrrolidone-derived enones: Straightforward access to chiral tetrahydropyran-fused spiro-pyrrolidine-2,3-diones. Chinese Chemical Letters, 2024, 35(6): 109157-. doi: 10.1016/j.cclet.2023.109157
12. [12]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
13. [13]
  Yi Zhang , Biao Wang , Chao Hu , Muhammad Humayun , Yaping Huang , Yulin Cao , Mosaad Negem , Yigang Ding , Chundong Wang . Fe–Ni–F electrocatalyst for enhancing reaction kinetics of water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100243-100243. doi: 10.1016/j.cjsc.2024.100243
14. [14]
  Guan-Nan Xing , Di-Ye Wei , Hua Zhang , Zhong-Qun Tian , Jian-Feng Li . Pd-based nanocatalysts for oxygen reduction reaction: Preparation, performance, and in-situ characterization. Chinese Journal of Structural Chemistry, 2023, 42(11): 100021-100021. doi: 10.1016/j.cjsc.2023.100021
15. [15]
  Mengli Xu , Zhenmin Xu , Zhenfeng Bian . Achieving Ullmann coupling reaction via photothermal synergy with ultrafine Pd nanoclusters supported on mesoporous TiO2. Chinese Journal of Structural Chemistry, 2024, 43(7): 100305-100305. doi: 10.1016/j.cjsc.2024.100305
16. [16]
  Jiaxu Wang , Jinxie Zhang , Xiuping Wang , Jingying Wang , Lina Chen , Jiahui Cao , Wei Cao , Siyu Liang , Ping Luan , Ke Zheng , Xiao-Kun Ouyang , Li Gao , Xiaowen Ou , Fan Zhang , Meitong Ou , Lin Mei . CaCO₃-coated hollow mesoporous silica nanoparticles for pH-responsive fungicides release. Chinese Chemical Letters, 2024, 35(12): 109697-. doi: 10.1016/j.cclet.2024.109697
17. [17]
  Li Li , Zhi-Xin Yan , Chuan-Kun Ran , Yi Liu , Shuo Zhang , Tian-Yu Gao , Long-Fei Dai , Li-Li Liao , Jian-Heng Ye , Da-Gang Yu . Electro-reductive carboxylation of CCl bonds in unactivated alkyl chlorides and polyvinyl chloride with CO₂. Chinese Chemical Letters, 2024, 35(12): 110104-. doi: 10.1016/j.cclet.2024.110104
18. [18]
  Manman Ou , Yunjian Zhu , Jiahao Liu , Zhaoxuan Liu , Jianjun Wang , Jun Sun , Chuanxiang Qin , Lixing Dai . Polyvinyl alcohol fiber with enhanced strength and modulus and intense cyan fluorescence based on covalently functionalized graphene quantum dots. Chinese Chemical Letters, 2025, 36(2): 110510-. doi: 10.1016/j.cclet.2024.110510
19. [19]
  Gregorio F. Ortiz . Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery. Chinese Chemical Letters, 2024, 35(10): 109391-. doi: 10.1016/j.cclet.2023.109391
20. [20]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(870)
HTML views(137)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Efficient Synthesis and Application in Heck Reaction of Pd/Fe3O4 Magnetic Nanoparticles(English)

Metrics

通讯作者: 陈斌, bchen63@163.com

Efficient Synthesis and Application in Heck Reaction of Pd/Fe₃O₄ Magnetic Nanoparticles(English)