Citation: WU Guo-Guo, JIN Rong, PU Yong, LI Jun-Jun, YAN Heng-Qing, ZHANG Yun-Wang, ZHANG Lin. Electrodepositing Double Au-Cu Shells on Hollow Polystyrene Miscorsphere[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(6): 1030-1034. doi: 10.11862/CJIC.2017.120 shu

Electrodepositing Double Au-Cu Shells on Hollow Polystyrene Miscorsphere

WU Guo-Guo ¹ ,
JIN Rong ^2,*,, ,
PU Yong ² ,
LI Jun-Jun ² ,
YAN Heng-Qing ² ,
ZHANG Yun-Wang ³ ,
ZHANG Lin ^3,*,,

1.
School of Mechatronics Engineering, Chongqing University of Arts and Sciences, Chongqing 402160, China
2.
Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing 402160, China
3.
Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang, Sichuan 621900, China

Corresponding author: JIN Rong, rong516112@sina.cn ZHANG Lin, zlmy@sina.com
Received Date: 8 September 2016
Revised Date: 28 February 2017

Figures(5)

Double core-shells composite miscorsphere of PS/Au/Cu have been prepared by electrodepositing Cu on the PS-Au composite miscorsphere which is electrodeposited Au on the template of hollow polystyrene microsphere in the self-designed electrodepositing setup. Firstly, PS-Au miscorsphere keep a good spherical symmetric. And the Au electrodeposit is fine with thickness of 5.6 μm. Secondly, Cu is electrodeposited on integral PS-Au miscorsphere selected. Cu grow along crystal structure of Au because of the same face-centered cubic structure. Then the section of Au-Cu is compact. Finally, the thickness of Cu is 8.62 μm, the Au is 4.04 μm. The morphology, thickness, composition and roughness of PS/Au/Cu microsphere and double core-shells are studied by 3D-Video microscope, SEM, EDS and XRD. The results show that the complete shells of uniform deposit, good smoothness and low roughness of PS/Au/Cu microsphere and Au-Cu are synthesized on the surface of hollow polystyrene microsphere.
- double core-shells,
- composite microsphere,
- electrodeposited
1. [1]
  LI Bin, NIU Gao, YI Yong, et al. Spectrosc. Spect. Anal., 2016, 36(9):2812-2817
2. [2]
  WU Xuan-Rong, YANG Qiao-Zhen, ZHAO Yong-Xiang. J. Inorg. Mater., 2016, 31(5):473-478
3. [3]
  MAO Qian-Jin, YU Cai-Xia, WANG Qun. Journal of Beijing University of Technology, 2003, 29(1):108-111
4. [4]
  QI Xiao-Bo, TANG Yong-Jian, LI Bo, et al. High Power Laser and Particle Beams, 2006, 18(1):55-60
5. [5]
  Nikroo A, Baugh W, Steinman D A. Fusion Sci. Technol., 45(2004):202-205
6. [6]
  Rogach A, Susha A, Caruso F. Adv. Mater., 2000, 12:333-337 doi: 10.1002/(SICI)1521-4095(200003)12:5<333::AID-ADMA333>3.0.CO;2-X
7. [7]
  Kato N, Caruso F. J. Phys. Chem. B, 2004, 109(42):19604-19612
8. [8]
  Ou J L, Chang C P, Sung Y, et al. Colloids Surf. A, 2007, 304(123):36-41
9. [9]
  LIU Hui-Yu, CHEN Dong, TANG Fang-Qiong, et al. Acta Phys.-Chim. Sin., 2006, 22(4):644-648
10. [10]
  WANG Yu, ZHANG Xiao-Yong, MAO Li, et al. J. Mater. Sci. Eng., 2004, 22(5):753-756
11. [11]
  ZHANG Jian-Hua, LU Zhong-Yuan, SONG Li-Xian, et al. New Chemical Materials, 2007, 34(6):30-31
12. [12]
  ZHANG Bin-Gjie, YANG Wen-Bin, ZHOU Yuan-Lin, et al. High Power Laser and Particle Beams, 2007, 19(4):744-748
13. [13]
  Jin R, Zhang Y W, Zhang L, et al. Appl. Surf. Sci., 264(2013):464-469
14. [14]
  SUN Jing-Yuan, ZHANG Yun-Wang, DU Kai, et al. High Power Laser and Particle Beams, 2010, 22(12):2889-2892
15. [15]
  Peter A, Cerjan C, Hamza A, et al. Phys. Plasmas, 2007, 14:056312 doi: 10.1063/1.2716406
16. [16]
  Jackson J B, Halas N J. J. Phys. Chem. B, 2001, 104(14):2743-2746
17. [17]
  Yong K T, Sahoo Y, Swihart M T, et al. Colloids Surf. A, 2006, 290(1/2/3):89-105
18. [18]
  WANG Ying, MI Kan, XIONG Sheng-Lin. Chinese J. Inorg. Chem., 2017, 33(2):243-248 doi: 10.11862/CJIC.2017.048
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沈阳化工大学材料科学与工程学院沈阳 110142