Citation: XIE Qing-Fan, YAO Yong-Gang, JIANG Yan, HONG Si-Yu, CHEN Yan-Min. Syntheses, Structures and Characterization of Cu (Ⅱ) and Co (Ⅲ) Complexes Formed by a Tripodal Tetradentate Schiff Base[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 867-873. doi: 10.11862/CJIC.2017.101 shu

Syntheses, Structures and Characterization of Cu (Ⅱ) and Co (Ⅲ) Complexes Formed by a Tripodal Tetradentate Schiff Base

College of Chemical Engineerng and Material, Quanzhou Normal University, Quanzhou, Fujian 362000, China

Corresponding author: CHEN Yan-Min, qzucym@163.com
Received Date: 3 January 2017
Revised Date: 16 March 2017

Figures(7)

A multidentate Schiff base ligand (H₃Lds, 1) with[NO₃] donor set, derived from the condensation of salicylaldehyde and 2-Amino-2-methyl-1, 3-propanediol, reacted with copper (Ⅱ) chloride or cobalt (Ⅱ) acetate to yield two complexes[CuCl (H₂Lds)]·H₂O (2) and[Co₂(H₂O)₂(Lds)₂]·5H₂O (3). The ligand and complexes were characterized by elemental analysis, IR, UV spectra and X-ray diffraction analysis. The results reveal that 1 crystallizes in orthorhombic space group P2₁2₁2₁, 2 with Cu (Ⅱ) in distorted square-planar coordination in orthorhombic space group Pbca, 3 with Co (Ⅲ) in distorted coordination octahedron in monoclinic space group P2₁/c, respectively. The H₃Lds is linked by intermolecular H-bonds to form two-dimension supramolecular network, while both complexes are connected by intermolecular hydrogen-bonding interactions to form a supramolecular chains, respectively.
- schiff base,
- complexes,
- crystal structure,
- hydroxyl-rich ligand
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