Citation: DONG Yi-Tian, TU Bo, XU Hong, HUANG Ya-Li, ZHANG Qi-Long, HU Zong-Chao, ZHU Bi-Xue. Syntheses and Crystal Structures of Cd(Ⅱ), Zn(Ⅱ) and Hg(Ⅱ) Complexes Based on Bis (pyridylurea) Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 651-658. doi: 10.11862/CJIC.2017.088 shu

Syntheses and Crystal Structures of Cd(Ⅱ), Zn(Ⅱ) and Hg(Ⅱ) Complexes Based on Bis (pyridylurea) Ligand

DONG Yi-Tian ¹ ,
TU Bo ² ,
XU Hong ² ,
HUANG Ya-Li ² ,
ZHANG Qi-Long ^2,*,, ,
HU Zong-Chao ^1,3,*,, ,
ZHU Bi-Xue ¹

1.
College of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China
2.
Department of Chemistry, Guizhou Medical University, Guizhou, Guiyang 550025, China
3.
Guizhou Industry Polytechnic College, Guizhou, Guiyang 550008, China

Corresponding author: ZHANG Qi-Long, gzuqlzhang@126.com HU Zong-Chao, zchu@gzu.edu.cn
Received Date: 1 January 2017
Revised Date: 11 March 2017

Figures(14)

The urea-based pyridyl ligand L was synthesized from the reaction of 1, 3-Benzenediamine with 3-isocyanatopyridine in toluene heating to reflux. CdSO₄·8H₂O, ZnI₂, HgI₂ and HgCl₂ reacted with L to give the complexes {[Cd (L)(SO₄)(H₂O)₃]·H₂O}_n (1), {[Zn (L) I₂]·2C₂H₅OH}_n (2), {[Hg (L) I₂]·2C₂H₅OH}_n (3), [Hg (L) Cl₂]·H₂O (4), which were characterized by elemental analysis, FT-IR, single crystal X-ray diffraction and powder X-ray diffraction. Complex 1 forms a one-dimensional helix chain structure, complex 2 and complex 3 show a one-dimensional zigzag chain structure and complex 4 shows a 32-membered ring.
- bis (pyridylurea) ligand,
- Cd(Ⅱ) complex,
- Zn(Ⅱ) complex,
- Hg(Ⅱ) complex,
- crystal structure
1. [1]
  Pandurangan K, Kitchen J A, Blasco S, et al. Angew. Chem. Int. Ed., 2015, 54:4566-4570 doi: 10.1002/anie.201411857
2. [2]
  Duke R M, McCabe T, Schmitt W, et al. J. Org. Chem., 2012, 77:3115-3126 doi: 10.1021/jo202332h
3. [3]
  Zhang Z G, Schreiner P R. Chem. Soc. Rev., 2009, 38:1187-1198 doi: 10.1039/b801793j
4. [4]
  Amendola V, Fabbrizzi L, Mosca L. Chem. Soc. Rev., 2010, 39:3889-3915 doi: 10.1039/b822552b
5. [5]
  Jie Z, Yang D, Zhao Y X, et al. Angew. Chem. Int. Ed., 2014, 53:6632-6636 doi: 10.1002/anie.201402169
6. [6]
  Custelcean R, Williams N J, Seipp C A. Angew. Chem. Int. Ed., 2015, 54:10525-10529 doi: 10.1002/anie.201506314
7. [7]
  Wu B, Liang J J, Zhao Y X, et al. CrystEngComm, 2010, 12:2129-2134 doi: 10.1039/b920777e
8. [8]
  Liang J J, Wu B, Jia C D, et al. CrystEngComm, 2009, 11:975-977 doi: 10.1039/b820640f
9. [9]
  Li S G, Wu B, Hao Y G, et al. CrystEngComm, 2010, 12:2001-2004 doi: 10.1039/b922566h
10. [10]
  Manna U, Nayak B, Das G. Cryst. Growth Des., 2016, 16(12):7163-7174 doi: 10.1021/acs.cgd.6b01370
11. [11]
  Custelcean R, Sellin V, Moyer B A. Chem. Commun., 2007:1541-1543
12. [12]
  Custelcean R, Bonnesen P A, Duncan N C, et al. J. Am. Chem. Soc., 2012, 134:8525-8534 doi: 10.1021/ja300677w
13. [13]
  Zhang Q L, Huang Y L, Xu H, et al. J. Coord. Chem., 2016, 70(1):156-167
14. [14]
  ZHANG Hui-Qin, YUAN Zhi-Ze, LAI Xiao-Qing, et al. Chinese J. Inorg. Chem., 2016, 32(11):2058-2062
15. [15]
  ZHANG Qi-Long, FENG Guang-Wei, HU Peng, et al. Chinese J. Inorg. Chem., 2014, 30(10):2433-2439
16. [16]
  Liu J, Wang F, Ding Q R, et al. Inorg. Chem., 2016, 55(24):12520-12522 doi: 10.1021/acs.inorgchem.6b02514
17. [17]
  Li Y L, Zhao Y, Kang Y S, et al. Cryst. Growth Des., 2016, 16(12):7112-7123 doi: 10.1021/acs.cgd.6b01352
18. [18]
  Paul M, Adarsh N N, Dastidar P. Cryst. Growth Des., 2012, 12:4135-4143 doi: 10.1021/cg300649e
19. [19]
  Sheldrick G M. SHELX-97, University of Göttingen, Germany, 1997.
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