Citation: LI Shi-Long, LÜ Chao, MIN Xin, FANG Ming-Hao, HUANG Zhao-Hui, LIU Yan-Gai. Preparation and Luminescence Properties of La₇O₆(BO₃)(PO₄)₂: Tb³⁺/Eu³⁺ Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 761-768. doi: 10.11862/CJIC.2017.086 shu

Preparation and Luminescence Properties of La₇O₆(BO₃)(PO₄)₂: Tb³⁺/Eu³⁺ Phosphors

Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences (Beijing), Beijing 100083, China

Corresponding author: MIN Xin, minx@cugb.edu.cn
Received Date: 22 December 2016
Revised Date: 13 March 2017

Figures(10)

La₇O₆(BO₃)(PO₄)₂:Tb³⁺ and La₇O₆(BO₃)(PO₄)₂:Eu³⁺ phosphors were prepared by a high-temperature solid state reaction, and the phase behavior, crystal structure, luminescence properties and thermal stability were investigated. The La₇O₆(BO₃)(PO₄)₂:Eu³⁺ phosphors emitted a red light under the ultraviolet excitation. The emission maximum was at 616 nm, corresponding to the ⁵D₀-⁷F₂ transition of Eu³⁺. The concentration quenching pheno-menon was observed when the doping concentration of Eu³⁺ ion was beyond 0.08. The corresponding CIE coordinates were calculated to be (0.610 2, 0.382 3). The La₇O₆(BO₃)(PO₄)₂:Tb³⁺ phosphors emitted a green light under the ultraviolet excitation. The emission maximum was at 544 nm, corresponding to the ⁵D₄-⁷F₅ transition of Tb³⁺. Concentration quenching phenomenon was observed when the concentration of Tb³⁺ ion was beyond 0.15, and its CIE coordinates are calculated to be (0.317 7, 0.535 2). Based on the analysis of temperature-dependent emission spectra of La₇O₆(BO₃)(PO₄)₂:Tb³⁺ and La₇O₆(BO₃)(PO₄)₂:Eu³⁺ phosphors, it can be found that both phosphors possess good thermal stability.
- phosphors,
- photoluminescence properties,
- Eu³⁺,
- Tb³⁺,
- La₇O₆(BO₃)(PO₄)₂
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Preparation and Luminescence Properties of La₇O₆(BO₃)(PO₄)₂: Tb³⁺/Eu³⁺ Phosphors