Citation: GU Min, CHEN Ying-Long, WU Ya-Zhen. Preparation and Optical Properties of CuO-SiO₂ and Cu₂O-SiO₂ Films[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 576-582. doi: 10.11862/CJIC.2017.077 shu

Preparation and Optical Properties of CuO-SiO₂ and Cu₂O-SiO₂ Films

State Key Laboratory of Coal Mine Disaster Dynamics and Control, College of Resources and Environmental Science, Chongqing University, Chongqing 400044, China

Corresponding author: GU Min, mgu@cqu.edu.cn
Received Date: 4 August 2016
Revised Date: 3 January 2017

Figures(7)

The Cu-SiO₂ composite films were first prepared by electrochemical sol-gel method at-0.9 V from Cu²⁺-SiO₂ tranparent composite sol which was prepared by using CuSO₄·5H₂O and tetraethoxysilane as precursors. Then, Cu-SiO₂ composite films were transformed into Cu₂O-SiO₂ and CuO-SiO₂ composite films by thermal treatment at 250 and 450℃, respectively. The compostion, morphology and thickness of the two composited films were characterized by X-ray diffraction (XRD) and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDX) and step profiler, respectively. In addition, the linear and nonlinear optical properties were measured by using UV-Vis spectrum and Z-scan methods. It was found that the optical properties of these composite films were influenced by the Cu content, the forms of Cu element (i.e. CuO or Cu₂O) and particle size of CuO or Cu₂O in the films. The optical band gaps of Cu₂O-SiO₂ and CuO-SiO₂ composite films were respectively 2.67 and 2.54 eV, and the third-order nonlinear susceptibilities (χ⁽³⁾) were 2.31×10^-6 and 1.36×10^-6 esu, respectively.
- electrochemical-sol-gel,
- thermal treatment,
- copper oxide-silicon dioxide,
- cuprous oxide-silicon dioxide,
- composite film,
- optical band gap,
- third-order nonlinear optical property
1. [1]
  WU Ya-Zhen, GU Min. Chinese J. Inorg. Chem., 2016, 32(4):617-624
2. [2]
  Akhavan O, Tohidi H, Moshfegh A Z. Thin Solid Films, 2009, 517:6700-6707 doi: 10.1016/j.tsf.2009.05.016
3. [3]
  Zhang X J, Zhang D G, Ni X M, et al. Mater. Lett., 2007, 61:248-250 doi: 10.1016/j.matlet.2006.04.047
4. [4]
  Vives S, Meunier C. Mater. Lett., 2013, 91:165-169 doi: 10.1016/j.matlet.2012.09.081
5. [5]
  Armelao L, Barreca D, Bertapelle M, et al. Thin Solid Films, 2003, 442:48-52 doi: 10.1016/S0040-6090(03)00940-4
6. [6]
  GE Man-Zhen, YU Guang-Hui, YANG Hui, et al. J. Mater. Sci. Eng., 1996, 14(2):31-35
7. [7]
  Shmatko V A, Yalovega G E, Myasoedova T N, et al. Phys. Solid State, 2015, 57:399-406 doi: 10.1134/S1063783415020328
8. [8]
  Espinos J P, Morales J, Barranco A, et al. J. Phys. Chem. B, 2002, 106:6921-6929 doi: 10.1021/jp014618m
9. [9]
  Switzer J A, Liu R, Bohannan E W. J. Phys. Chem. B, 2002, 106:12369-12372 doi: 10.1021/jp0266188
10. [10]
11. [11]
  GAN Ping, GU Min, LI Qiang, et al. J. Inorg. Mater., 2011, 26(3):295-299 doi: 10.3724/SP.J.1077.2011.00295
12. [12]
  De G, Epifani M, Licciulli A. J. Non-Cryst. Solids, 1996, 201:250-255 doi: 10.1016/0022-3093(96)00409-7
13. [13]
  Toledano R, Shacham R, Avnir D, Mandler D. Chem. Mater., 2008, 20:4276-4283 doi: 10.1021/cm800002z
14. [14]
  Kuhn A T, Chan C Y. J. Appl. Electrochem., 1983, 13:189-207 doi: 10.1007/BF00612481
15. [15]
  Liu L, Mandler D. Electrochim. Acta, 2013, 102:212-218 doi: 10.1016/j.electacta.2013.03.188
16. [16]
  Sánchez M, Rams J, Ureňa A. Oxid. Met., 2008, 69:327-341 doi: 10.1007/s11085-008-9100-7
17. [17]
  DING Yu-Tian, LU Zhen-Hua, HU Yong, et al. J. Lanzhou Univ. Tech., 2010, 36(2):1-4
18. [18]
  Dubal D P, Gund G S, Lokhande C D, et al. Mater. Res. Bull., 2013, 48:923-928 doi: 10.1016/j.materresbull.2012.11.081
19. [19]
  Diaz-Droguett D E, Espinoza R, Fuenzalida V M. Appl. Surf. Sci., 2011, 257:4597-4602 doi: 10.1016/j.apsusc.2010.12.082
20. [20]
  Pierson J F, Thobor-Keck A, Billard A. Appl. Surf. Sci., 2003, 210:359-367 doi: 10.1016/S0169-4332(03)00108-9
21. [21]
  GAN Xin-Hui, LIAO Yuan-Bao, LIU Dong, et al. Chinese J. Lumin., 2008, 26(6):1076-1080
1. [1]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
2. [2]
  Ruifeng CHEN , Chao XU , Jianting JIANG , Tianshe YANG . Gold nanorod/zinc oxide/mesoporous silica nanoplatform: A triple-modal platform for synergistic anticancer therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2272-2282. doi: 10.11862/CJIC.20250117
3. [3]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
4. [4]
  Xiaohang JIN , Qi LIU , Jianping LANG . Room‑temperature solid‑state synthesis, structure, and third‑order nonlinear optical properties of phosphine‑ligand‑protected silver thiolate clusters. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1505-1512. doi: 10.11862/CJIC.20250125
5. [5]
  Yujie WANG , Laobang WANG , Zheng ZHANG , Qi LIU , Jianping LANG . Construction of W/Cu/S cluster-based supramolecular compounds via alkynyl/sulfur cycloaddition and their third-order nonlinear optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2069-2077. doi: 10.11862/CJIC.20250129
6. [6]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
7. [7]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008
8. [8]
  Jiayin Hu , Yafei Guo , Long Li , Tianlong Deng . Teaching Innovation of Salt-Water System Phase Diagrams under the “Dual Carbon” Background: Introducing the Pressurized CO₂ Carbonization Phase Equilibria. University Chemistry, 2025, 40(11): 31-36. doi: 10.12461/PKU.DXHX202412031
9. [9]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
10. [10]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
11. [11]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
12. [12]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-0. doi: 10.3866/PKU.WHXB202407020
13. [13]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
14. [14]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
15. [15]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
16. [16]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
17. [17]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
18. [18]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
19. [19]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
20. [20]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1624)
HTML views(327)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Optical Properties of CuO-SiO2 and Cu2O-SiO2 Films

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Optical Properties of CuO-SiO₂ and Cu₂O-SiO₂ Films