Citation: XIA Liang-Min, CHEN Hao, WU Qing-An, WANG Xiao-Jing, LOU Wen-Ya, XU Bin, LUO Shu-Ping. Aza-Isocyanide Heteroleptic Copper Complexes: Synthesis and Application in Photocatalytic Hydrogen Evolution From Water[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 560-568. doi: 10.11862/CJIC.2017.075 shu

Aza-Isocyanide Heteroleptic Copper Complexes: Synthesis and Application in Photocatalytic Hydrogen Evolution From Water

XIA Liang-Min ¹ ,
CHEN Hao ¹ ,
WU Qing-An ¹ ,
WANG Xiao-Jing ² ,
LOU Wen-Ya ² ,
XU Bin ^2,*,, ,
LUO Shu-Ping ^1,2,*,,

1.
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, China
2.
Yiwu Science and Technology Research Institute, Zhejiang University of Technology, Yiwu, Zhejiang 322001, China

Corresponding author: XU Bin, xubin@zjut.edu.cn LUO Shu-Ping, Luoshuping@zjut.edu
Received Date: 6 September 2016
Revised Date: 25 February 2017

Figures(11)

A electron-donating bidentate ligands of isocyano-compounds were designed and synthesized, which could formed a series of aza-isocyanide heteroleptic copper photosensitizers 4a~4h with 1, 10-phenanthroline derivatives as N ligands. The photosensitive activities of this copper complexes were studied in water reduction system, and the turnover number (TON) of hydrogen evolution was up to 168 with bis (2-isocyanophenyl) sulfane as isocyanide ligand and 1, 10-phenanthroline with 2, 9-disubstitutes as N ligand. After the photophysical and photoelectric properties of these copper complexes were studied, a preliminary explanation and discussion of the structure-activity relationship and the mechanism of photocatalytic hydrogen evolution from water were carried out.
- isocyanide,
- heteroleptic copper complexes,
- photosensitizer,
- water splitting,
- hydrogen evolution
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