Citation: LIU Ji-Wei. Syntheses, Crystal Structures and Properties of Zinc(Ⅱ) and Co(Ⅱ) Complexes Constructed by 2, 2'-Dithiosalicylic Acid, Bis (2-carboxyphenyl) Sulfide and N-Donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 705-712. doi: 10.11862/CJIC.2017.068 shu

Syntheses, Crystal Structures and Properties of Zinc(Ⅱ) and Co(Ⅱ) Complexes Constructed by 2, 2'-Dithiosalicylic Acid, Bis (2-carboxyphenyl) Sulfide and N-Donor Ligands

LIU Ji-Wei ^*,,

Heilongjiang Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Technology, Northeast Petroleum University, Daqing, Heilongjiang 163318, China

Corresponding author: LIU Ji-Wei, liujiwei0706@163.com
Received Date: 20 December 2016
Revised Date: 6 January 2017

Figures(10)

The Zn(Ⅱ) complex, [Zn (C₁₄H₈O₄S)(ip)(H₂O)] (1) (C₁₄H₈O₄S=bis (2-carboxyphenyl) sulfide, ip=1H-imidazo[4, 5-f] [1, 10]phenanthroline) was prepared with 2, 2'-dithiosalicylic acid, ip and Zn (NO₃)₂·6H₂O by in situ hydro-thermal reaction; while {[Co (C₁₄H₈O₄S₂)(im)₂]·H₂O}_n (2) (C₁₄H₈O₄S₂=2, 2'-dithiosalicylate, im=imidazole) was synth-esized by mixing 2, 2'-dithiosalicylic acid, im and cobalt dinitrate; after that they were characterized by elemental analysis, thermal analysis, IR, fluorescent spectra analysis, XRD and X-ray single crystal diffraction. Complex 1 has a dinuclear structure, and the Zn(Ⅱ) ion is five-coordinated in a distorted trigonal bipyramidal geometry. Complex 2 has a one-dimensional chain structure, while the Co(Ⅱ) ion is six-coordinated to form a distorted octahedral configuration.
- 2, 2'-dithiosalicylic acid,
- bis (2-carboxyphenyl) sulfide,
- in situ reaction,
- crystal structure
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