Citation: ZHENG Zhuo, WU Zhen-Guo, XIANG Wei, YANG Xiu-Shan. Preparation and Electrochemical Performance of Porous Micro-Nano Structure Layered Li-Rich 0.6Li₂MnO₃·0.4LiNi_0.5Mn_0.5O₂ Cathode for Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(3): 479-486. doi: 10.11862/CJIC.2017.059 shu

Preparation and Electrochemical Performance of Porous Micro-Nano Structure Layered Li-Rich 0.6Li₂MnO₃·0.4LiNi_0.5Mn_0.5O₂ Cathode for Lithium-Ion Batteries

1.
Polymer Research Institute, Sichuan University, Chengdu 610065, China
2.
School of Chemical Engineering, Sichuan University, Chengdu 610065, China
3.
College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610065, China

Corresponding author: YANG Xiu-Shan, yangxs@scu.edu.cn
Received Date: 11 November 2016
Revised Date: 25 December 2016

Figures(7)

A Li-rich 0.6Li₂MnO₃·0.4LiNi_0.5Mn_0.5O₂ cathode material with porous micro-nano spherical structure is prepared using a combination of carbonate co-precipitation and combustion method. Powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N₂ adsorpation-desorpation and galvanostatic charge-discharge tests are employed to analyze the crystal structure, micro morphology and electrochemical properties of the as-prepared material. Results indicate that this cathode has a porous micro-nano spherical structure, which is composed of primary particles with a small size about 300 nm. Moreover, this cathode has a well-ordered layered α-NaFeO₂ structure (space group R3m) and a high BET specific surface area of 13 m²·g^-1. Electrochemical measurements confirm that this cathode has excellent high capacity, good cycling stability and outstanding rate performance. At 2.0~4.8 V, the discharge capacities of the material at 0.1C, 0.2C, 0.5C, 1C, 3C, 5C and 10C are 266, 254, 235, 205, 186, 149 and 107 mAh·g^-1, respectively. After 100 cycles at 0.5C, the cathode also exhibits a discharge capacity of 217 mAh·g^-1 with capacity retention of 94%.
- micro-nano structure,
- carbonate co-precipitation,
- Li-rich cathodes,
- electrochemical performance,
- Lithium-ion batteries
1. [1]
  Manthiram A, Murugan A V, Sarkar A, et al. Energy Environ. Sci., 2008, 1(6):621-638 doi: 10.1039/b811802g
2. [2]
  Goodenough J B, Kim Y. Chem. Mater., 2010, 22(3):587-603 doi: 10.1021/cm901452z
3. [3]
  Yu H C, Ling C, Bhattacharya J, et al. Energy Environ. Sci., 2014, 7(5):1760-1768 doi: 10.1039/c3ee43154a
4. [4]
  Xu G, Li J, Xue Q, et al. J. Power Sources, 2014, 248:894-899 doi: 10.1016/j.jpowsour.2013.10.002
5. [5]
  Fu F, Deng Y P, Shen C H, et al. Electrochem. Commun., 2014, 44:54-58 doi: 10.1016/j.elecom.2014.04.013
6. [6]
  Lin J, Mu D, Jin Y, et al. J. Power Sources, 2013, 230(10): 76-80
7. [7]
  Mohanty D, Kalnaus S, Meisner R A, et al. J. Power Sources, 2013, 229(9):239-248
8. [8]
  Xu B, Fell C R, Chi M, et al. Energy Environ. Sci., 2011, 4(6):2223-2233 doi: 10.1039/c1ee01131f
9. [9]
  Deng H, Belharouak I, Sun Y K, et al. J. Mater. Chem., 2009, 19(26):4510-4516 doi: 10.1039/b904098f
10. [10]
  GAO Yuan, LAI Qiong-Yu, WEI Ni-Ni, et al. Chinese J. Inorg. Chem., 2005, 21(5):778-782
11. [11]
  Park J H, Lim J, Yoon J, et al. Dalton Trans., 2012, 41(10): 3053-3059 doi: 10.1039/c2dt11833e
12. [12]
  Dianat A, Seriani N, Bobeth M, et al. J. Mater. Chem. A, 2013, 1(32):9273-9280 doi: 10.1039/c3ta11598d
13. [13]
  Song B, Lai M O, Lu L. Electrochim. Acta, 2012, 80:187-195 doi: 10.1016/j.electacta.2012.06.118
14. [14]
  Jung Y S, Cavanagh A S, Yan Y, et al. J. Electrochem. Soc., 2011, 158(12):A1298-A1302 doi: 10.1149/2.030112jes
15. [15]
  Gallagher K G, Kang S H, Park S U, et al. J. Power Sources, 2011, 196(22):9702-9707 doi: 10.1016/j.jpowsour.2011.07.054
16. [16]
  WANG Xu-Yang, YE Xue-Hai, ZHI Xiao-Ke, et al. Chinese J. Inorg. Chem., 2013, 29(4):774-778
17. [17]
  YIN Yan-Ping, LU Hua-Quan, WANG Zhong, et al. Chinese J. Inorg. Chem., 2015, 31(10):1966-1970
18. [18]
  Bai J, Li X, Liu G, et al. Adv. Funct. Mater., 2014, 24(20): 3012-3020 doi: 10.1002/adfm.v24.20
19. [19]
  Thackeray M M, Kang S H, Johnson C S, et al. J. Mater. Chem., 2007, 17(30):3112-3125 doi: 10.1039/b702425h
20. [20]
  Kang K, Meng Y S, Bre'ger J, et al. Science, 2006, 311(5763):977-980 doi: 10.1126/science.1122152
21. [21]
  Huang Z D, Liu X M, Oh S W, et al. J. Mater. Chem., 2011, 21(29):10777-10784 doi: 10.1039/c1jm00059d
22. [22]
  Zhang X Y, Jiang W J, Mauger A, et al. J. Power Sources, 2010, 195:1292-1301 doi: 10.1016/j.jpowsour.2009.09.029
23. [23]
  Fu Q, Du F, Bian X, et al. J. Mater. Chem. A, 2014, 2(20): 7555-7562 doi: 10.1039/c4ta00189c
24. [24]
  Noh H J, Chen Z, Yoon C S, et al. Chem. Mater., 2013, 25(10):2109-2115 doi: 10.1021/cm4006772
25. [25]
  Li J, Xiong S, Li X, et al. Nanoscale, 2013, 5(5):2045-2054 doi: 10.1039/c2nr33576j
26. [26]
  Li J, Xiong S, Liu Y, et al. Nano Energy, 2013, 2(6):1249-1260 doi: 10.1016/j.nanoen.2013.06.003
27. [27]
  Shen C H, Wang Q, Fu F, et al. ACS Appl. Mater. Interfaces, 2014, 6(8):5516-5524 doi: 10.1021/am405844b
28. [28]
  Wang F X, Xiao S Y, Chang Z. Chem. Commun., 2013, 49(80):9209-9211 doi: 10.1039/c3cc44360d
29. [29]
  Zhang X J, Shi W H, Zhu J X, et al. Nano Res., 2010, 3(9): 643-652 doi: 10.1007/s12274-010-0024-6
30. [30]
  Li Q, Li G, Fu C, et al. ACS Appl. Mater. Interfaces, 2014, 6(13):10330-10341 doi: 10.1021/am5017649
31. [31]
  Wang S, Wu Y, Li Y, et al. Electrochim. Acta, 2014, 133(7): 100-106
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrochemical Performance of Porous Micro-Nano Structure Layered Li-Rich 0.6Li2MnO3·0.4LiNi0.5Mn0.5O2 Cathode for Lithium-Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Performance of Porous Micro-Nano Structure Layered Li-Rich 0.6Li₂MnO₃·0.4LiNi_0.5Mn_0.5O₂ Cathode for Lithium-Ion Batteries