Citation: SUN Ru, LI Dong-Lin, CHEN Guang-Qi, ZHANG Wei, FAN Xiao-Yong, GOU Lei, WANG Yan-Ru, CHENG Yi-Ni, ZHAO Zhen-Zhen. Synthesis and Electrochemical Performances of Three-Dimensionally Ordered Macroporous Fe₂SiO₄/SiO₂@C Nano-Glass-Ceramic Materials as an Anode for Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(3): 471-478. doi: 10.11862/CJIC.2017.058 shu

Synthesis and Electrochemical Performances of Three-Dimensionally Ordered Macroporous Fe₂SiO₄/SiO₂@C Nano-Glass-Ceramic Materials as an Anode for Lithium-Ion Batteries

New Energy Materials and Devices Laboratory, School of Materials Science and Engineering, Chang'an University, Xi'an 710064, China

Corresponding author: LI Dong-Lin, donglinli@hotmail.com
Received Date: 4 November 2016
Revised Date: 4 January 2017

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A three-dimensionally ordered macroporous (3DOM) Fe₂SiO₄/SiO₂@C nano-glass-ceramic as an anode material for lithium-ion battery is successfully synthesized using a polystyrene (PS) colloidal crystal nano-casting and post-calcination. After a gel is calcined at 650℃ under an argon atmosphere, Fe₂SiO₄ nanocrystals grow from iron-containing SiO₂-based glass, resulting in 3DOM nano-glass-ceramic consisted of Fe₂SiO₄ nanocrystals, Fe³⁺-doped glassy SiO₂ and amorphous carbon. The resultant 3DOM Fe₂SiO₄/SiO₂@C nano-glass-ceramic exhibits a highly reversible discharge capacity up to 450 mAh·g^-1 at a current density of 50 mA·g^-1, and 260 mAh·g^-1 at 250 mA·g^-1 in the voltage range of 0.05~3.0 V, while the 3DOM amorphous SiO₂@C composite with same porous structure only delivers 15 mAh·g^-1 at 50 mA·g^-1. Compared to the 3DOM amorphous SiO₂@C composite, the 3DOM Fe₂SiO₄/SiO₂@C nano-glass-ceramic anode exhibits a significantly improved capacity and high-rate performancse. These results mean that the Fe₂SiO₄ and Fe³⁺ can enhance reversible lithium storage capability and high-rate performances of SiO₂-based nano-glass-ceramics.
- lithium-ion battery,
- SiO₂,
- nano-glass-ceramic,
- three-dimensionally ordered macroporous
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Synthesis and Electrochemical Performances of Three-Dimensionally Ordered Macroporous Fe2SiO4/SiO2@C Nano-Glass-Ceramic Materials as an Anode for Lithium-Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Electrochemical Performances of Three-Dimensionally Ordered Macroporous Fe₂SiO₄/SiO₂@C Nano-Glass-Ceramic Materials as an Anode for Lithium-Ion Batteries